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The First Oxovanadium(V)-Thiolate Complex, [VO(SCH2CH2)3N] Kausik K. Nanda, Ekkehard Sinn, and Anthony W. Addison pp 1 - 2; DOI: 10.1021/ic9512486 |
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Benzimidazol-2-ylcarbinols and Benzimidazol-2-yl Ketones: Novel Bifunctional Chelating Ligands for Copper Sergiu M. Gorun, Robert T. Stibrany, Alan R. Katritzky, Jaroslaw J. Slawinski, Hassan Faid-Allah, and Frédéric Brunner pp 3 - 4; DOI: 10.1021/ic950698v |
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Alkali Metal Bis(o-anisyl)phosphides: Characterization of MP(C6H4OMe-o)2 (M = Li, Na) and Crystal Structure of a Sodium Secondary Organophosphide Helen C. Aspinall and Martin R. Tillotson pp 5 - 8; DOI: 10.1021/ic950789s |
Preparation, Crystal Structures, and Isomerization of the Tellurium Diimide Dimers RNTe( -NR')2TeNR (R = R' = tBu; R = PPh2NSiMe3, R' = tBu, tOct): X-ray Structure of the Telluradiazole Dimer [tBu2C6H2N2Te]2Tristram Chivers, Xiaoliang Gao, and Masood Parvez pp 9 - 15; DOI: 10.1021/ic950154t |
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Syntheses and Structural Characterization of Tetrahedral Four-Coordinate Gold(I) Complexes of 1,3,5-Triaza-7-phosphaadamantane. An Example of a Hydrogen-Bond-Directed Supramolecular Assembly Jennifer M. Forward, Zerihun Assefa, Richard J. Staples, and John P. Fackler, Jr. pp 16 - 22; DOI: 10.1021/ic950560c |
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First Mixed Fluoro-Chloro Group 4 Organometallics: Synthesis and Spectroscopic and Structural Characterization of [{(C5Me5)ZrF2Cl}4], [{(C5Me5)HfF2Cl}4], [(C5Me5)4Zr4(-F)2(-F2)2(-Cl)2Cl4], [(C5Me5)4Hf4(-F)2(-F2)2(-Cl)2Cl4], [(C5Me4Et)2ZrClF], and [(C5Me5)2HfClF] Eamonn F. Murphy, Thomas Lübben, Axel Herzog, Herbert W. Roesky, Alojz Demsar, Mathias Noltemeyer, and Hans-Georg Schmidt pp 23 - 29; DOI: 10.1021/ic950822a |
High-Valent Manganese in Polyoxotungstates. 3. Dimanganese Complexes of  -Keggin AnionsXiao-Yan Zhang, Charles J. O'Connor, Geoffrey B. Jameson, and Michael T. Pope pp 30 - 34; DOI: 10.1021/ic950770p |
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Synthesis and Characterization of nido-[1,1,2,2-(CO)4-1,2-(PPh3)2-1,2-FeIrB2H5]: A Heterobimetallaborane Analogue of nido-[B4H7]- Jonathan Bould, Nigam P. Rath, and Lawrence Barton pp 35 - 39; DOI: 10.1021/ic950696a |
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Synthesis, X-ray Crystal Structure Determination, and NMR Spectroscopic Investigation of Two Homoleptic Four-Coordinate Lanthanide Complexes: Trivalent (tBu2P)2La[(-PtBu2)2Li(thf)] and Divalent Yb[(-PtBu2)2Li(thf)]2 Gerd W. Rabe, Jürgen Riede, and Annette Schier pp 40 - 45; DOI: 10.1021/ic950643t |
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Synthesis of Stable Multifunctional C-Phosphonio Phosphorus Vinyl Ylides Philip Dyer, Antoine Baceiredo, and Guy Bertrand pp 46 - 50; DOI: 10.1021/ic950628o |
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Synthesis and Structural Studies of Metal Complexes of the Biological Ligand 2-Quinaldic Acid: Utilization of the Polymer Pendant Analog PS-2-QA for Selective Aluminum Ion Removal from Aqueous Solution Wei Li, Marilyn M. Olmstead, Dana Miggins, and Richard H. Fish pp 51 - 55; DOI: 10.1021/ic950503j |
Syntheses and Structures of the Complexes cis-[M(C6F5)2(N X)] (M = Pd, Pt; NX = 2-Iodoaniline, 2-Benzoylpyridine) Containing NX Acting as a Didentate Chelating Ligand and Displaying I M or OM InteractionsJosé María Casas, Larry R. Falvello, Juan Forniés, and Antonio Martín pp 56 - 62; DOI: 10.1021/ic950283+ |
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A New Class of Aluminum Cations Based upon Tetradentate (N2O2) Chelating Ligands David A. Atwood, Jolin A. Jegier, and Drew Rutherford pp 63 - 70; DOI: 10.1021/ic950574i |
Reactions of Elemental Indium and Indium(I) Bromide with Nickel-Bromine Bonds: Structure of ( 5-C5H5)(Ph3P)Ni-InBr2(O=PPh3)Jurij Weiss, Thomas Priermeier, and Roland A. Fischer pp 71 - 75; DOI: 10.1021/ic950614i |
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Synthesis and Molecular Structures of Hydrotris(dimethylpyrazolyl)borate Complexes of the Lanthanides Sung-Ying Liu, Graham H. Maunder, Andrea Sella, Maya Stevenson, and Derek A. Tocher pp 76 - 81; DOI: 10.1021/ic941469w |
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Syntheses and Vibrational and 13C MAS-NMR Spectra of Bis(carbonyl)mercury(II) Undecafluorodiantimonate(V) ([Hg(CO)2][Sb2F11]2) and of Bis(carbonyl)dimercury(I) Undecafluorodiantimonate ([Hg2(CO)2][Sb2F11]2) and the Molecular Structure of [Hg(CO)2][Sb2F11]2 M. Bodenbinder, G. Balzer-Jöllenbeck, H. Willner, R. J. Batchelor, F. W. B. Einstein, C. Wang, and F. Aubke pp 82 - 92; DOI: 10.1021/ic9507171 |
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Synthesis of Arenethiolate Complexes of Divalent and Trivalent Lanthanides from Metallic Lanthanides and Diaryl Disulfides: Crystal Structures of [{Yb(hmpa)3}2(-SPh)3][SPh] and Ln(SPh)3(hmpa)3 (Ln = Sm, Yb; hmpa = Hexamethylphosphoric Triamide) Kazushi Mashima, Yuushou Nakayama, Tetsuya Shibahara, Hiroki Fukumoto, and Akira Nakamura pp 93 - 99; DOI: 10.1021/ic950050i |
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Electronic Structure and Properties of Trihalogen Cations X3+ and XY2+ (X, Y = F, Cl, Br, I) Jun Li, Stephan Irle, and W. H. Eugen Schwarz pp 100 - 109; DOI: 10.1021/ic950305s |
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[FeII(TRIM)2]F2, the First Example of Spin Conversion Monitored by Molecular Vibrations Azzedine Bousseksou, Marc Verelst, Hector Constant-Machado, Gilles Lemercier, Jean-Pierre Tuchagues, and François Varret pp 110 - 115; DOI: 10.1021/ic9506567 |
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Crystal Structures and Luminescence Properties of Platinum(II) Complexes Containing 3,3'-Biisoquinoline Masako Kato, Kumiko Sasano, Chizuko Kosuge, Mikio Yamazaki, Shigenobu Yano, and Masaru Kimura pp 116 - 123; DOI: 10.1021/ic9507124 |
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Study of the Reactions of Platinum Macrocyclic Complex Ions with Free Radicals Formed by Pulse Radiolysis of Aqueous Media W. L. Waltz, J. Lilie, S. Chandrasekhar, D. Woo, and K. Brown pp 124 - 130; DOI: 10.1021/ic950744r |
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Ab Initio/IGLO/NMR Investigation of nido-C4B7H11 Configurations: Structural Assignment of the Three Known Isomers and Reconfirmation of Empirical Carbon Placement Patterns Joseph W. Bausch, Robert C. Rizzo, Larry G. Sneddon, Andrew E. Wille, and Robert E. Williams pp 131 - 135; DOI: 10.1021/ic9506724 |
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Energy Transfer in Rigid Ru(II)/Os(II) Dinuclear Complexes with Biscyclometalating Bridging Ligands Containing a Variable Number of Phenylene Units Francesco Barigelletti, Lucia Flamigni, Massimo Guardigli, Alberto Juris, Marc Beley, Sandrine Chodorowski-Kimmes, Jean-Paul Collin, and Jean-Pierre Sauvage pp 136 - 142; DOI: 10.1021/ic9503085 |
Facile Dehydrogenation of  -Amino Acids Chelated to a Ruthenium(II) Ion: (-Imino acidato)ruthenium(II) ComplexesMotowo Yamaguchi, Kazuhiro Machiguchi, Tomonori Mori, Koichi Kikuchi, Isao Ikemoto, and Takamichi Yamagishi pp 143 - 148; DOI: 10.1021/ic941264n |
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Relationship between Solid State NMR Parameters and X-ray Structural Data in Tricadmium Phosphates S. Aime, G. Digilio, R. Gobetto, A. Bigi, A. Ripamonti, N. Roveri, and M. Gazzano pp 149 - 154; DOI: 10.1021/ic950462r |
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Thermal and Light-Induced Spin Transition in the High- and Low-Temperature Structure of [Fe0.35Ni0.65(mtz)6](ClO4)2 Th. Buchen, D. Schollmeyer, and P. Gütlich pp 155 - 161; DOI: 10.1021/ic9504405 |
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Kinetics of the Formation of Macrocyclic Polyaminocarboxylate Ligand Complexes: A Laser-Excited Luminescence Study of the Eu3+-dtpa-dien System Shu Ling Wu, Sonya J. Franklin, Kenneth N. Raymond, and William DeW. Horrocks, Jr. pp 162 - 167; DOI: 10.1021/ic950800o |
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Crystal Structure and Magnetic Behavior of [(C2H5)4N]2Cu5Cl12. A Novel Two-Dimensional Copper(II) Halide Network Derived from the CuCl2 Structure José A. Ayllón, Isabel C. Santos, Rui T. Henriques, Manuel Almeida, Luís Alcácer, and Maria T. Duarte pp 168 - 172; DOI: 10.1021/ic9505864 |
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Ligand Substitution Reactions at the Nickel of [Mo3NiS4(H2O)10]4+ with Two Water Soluble Phosphines, CO, Br-, I-, and NCS- and the Inertness of the 1,4,7-Triazacyclononane (L) Complex [Mo3(NiL)S4(H2O)9]4+ David M. Saysell, Christopher D. Borman, Chee-Hun Kwak, and A. Geoffrey Sykes pp 173 - 178; DOI: 10.1021/ic950562x |
Determination of the 17O Quadrupolar Coupling Constant and of the 13C Chemical Shielding Tensor Anisotropy of the CO Groups of Pentane-2,4-dione and  -Diketonate Complexes in Solution. NMR Relaxation StudyD. Champmartin and P. Rubini pp 179 - 183; DOI: 10.1021/ic950635c |
Electrochemical and Spectral Characterization of Iron Corroles in High and Low Oxidation States: First Structural Characterization of an Iron(IV) Tetrapyrrole  Cation RadicalEric Van Caemelbecke, Stefan Will, Marie Autret, Victor A. Adamian, Johann Lex, Jean-Paul Gisselbrecht, Maurice Gross, Emanuel Vogel, and Karl M. Kadish pp 184 - 192; DOI: 10.1021/ic9509037 |
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Crystal Structure and Magnetic Properties of [Cu(4-Me-3-Nit-trz)4](ClO4)2, with 4-Me-3-Nit-trz = 2-(3-[4-Methyl-1,2,4-triazolyl])-4,4,5,5-tetramethylimidazoline-1-oxyl 3-Oxide. Intra- and Intermolecular Spin Interactions Yu Pei, Andreas Lang, Pierre Bergerat, Olivier Kahn, Mohammed Fettouhi, and Lahcène Ouahab pp 193 - 198; DOI: 10.1021/ic950530+ |
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Fingerprinting Petroporphyrin Structures with Vibrational Spectroscopy. 4. Resonance Raman Spectra of Nickel(II) Cycloalkanoporphyrins: Structural Effects Due To Exocyclic Ring Size Roman S. Czernuszewicz, J. Graham Rankin, and Timothy D. Lash pp 199 - 209; DOI: 10.1021/ic950749o |
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First Synthesis of a Binuclear [MnII(bipy)-FeIII(porphyrin)] Complex: Spectroscopic Characterization and First Evidence of Reversible Formation of Manganese(III) as Manganese Peroxidase Clotilde Policar, Isabelle Artaud, and Daniel Mansuy pp 210 - 216; DOI: 10.1021/ic9506771 |
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Thermolysis of Neopentylcobalamin Analogs Complexed to Haptocorrin: Side Chain Entropy and Activation of Organocobalamins for Carbon-Cobalt Bond Homolysis Kenneth L. Brown, Daniel R. Evans, Shifa Cheng, and Donald W. Jacobsen pp 217 - 222; DOI: 10.1021/ic9506466 |
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Structural and Quantum Chemical Study of Bi53+ and Isoelectronic Main-Group Metal Clusters. The Crystal Structure of Pentabismuth(3+) Tetrachlorogallate(III) Refined from X-ray Powder Diffraction Data and Synthetic Attempts on Its Antimony Analogue Stefan Ulvenlund, Kenny Ståhl, and Lars Bengtsson-Kloo pp 223 - 230; DOI: 10.1021/ic9413981 |
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Mechanisms of the Cycloaddition Reaction of Methylenecyclopropane-Palladium and Oxa- and Azatrimethylenemethane-Palladium Complexes with Olefins Yasuo Oishi, Eigo Sakamoto, and Hiroshi Fujimoto pp 231 - 238; DOI: 10.1021/ic9504607 |
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Extension of the Unified Solvation Model to Organometallic and Polycyclic Aromatic Probes James E. George and Russell S. Drago pp 239 - 241; DOI: 10.1021/ic9505099 |
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Synthesis of the Organotitanoxane Complexes [(5-C5Me5)4Ti4X2](-O)5. X-ray Structure of [(5-C5Me5)4Ti4Me2](-O)5 Pilar Gómez-Sal, Avelino Martín, Miguel Mena, and Carlos Yélamos pp 242 - 243; DOI: 10.1021/ic950069l |
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Syntheses and Structures of Raft-Type Hexanuclear Molybdenum Chloro Chalcogenido Cluster Complexes [Mo6E8Cl6(PEt3)6] (E = S, Se) Jun Mizutani, S  ichiro Yamada, Hideo Imoto, and Taro Saitopp 244 - 247; DOI: 10.1021/ic9502180 |
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Synthesis, Crystal Structure, and Magnetic Behavior of (3-CO3)[Cu3(Medpt)3(ClO4)3](ClO4): A New Copper(II) Carbonato-Bridged Complex with a Triangular Array Albert Escuer, Ramon Vicente, Evaristo Peñalba, Xavier Solans, and Mercé Font-Bardía pp 248 - 251; DOI: 10.1021/ic950331q |
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Synthesis, Characterization, and Catalytic Behavior of a Ruthenium(II) Tetraazaannulene Complex Lubin Luo, Edwin D. Stevens, and Steven P. Nolan pp 252 - 254; DOI: 10.1021/ic9510876 |
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Convenient Preparation of Lanthanide Aryloxides from Lanthanide Nitrate Polyether Complexes and the Crystal Structure of [La(OC6H3Me2-2,6)3(MeO(CH2CH2O)4Me)] Helen C. Aspinall and and Mark Williams pp 255 - 257; DOI: 10.1021/ic9507629 |
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Synthesis of the First Poly(pyrazolyl)borate Complex of Germanium(II): Solid State Structure of [HB(3,5-Me2pz)3Ge]I·1/2CH2Cl2 Daniel L. Reger and and Paul S. Coan pp 258 - 260; DOI: 10.1021/ic950920w |
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A One-Step Method for the Synthesis of a Vinyl-Containing Silsesquioxane and Other Organolithic Macromolecular Precursors Steven E. Yuchs and and Kathleen A. Carrado pp 261 - 262; DOI: 10.1021/ic950356p |
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Quantum Chemical Calculations of the Structures and Electronic Properties of N,N'- Bis(3,5-dibromosalicylidene)-1,2-diaminobenzene and Its Cobalt(II) Complex. Origin of the Redox Activity of the Cobalt Complex G. L. Estiú, A. H. Jubert, J. Costamagna, and J. Vargas pp 263 - 266; DOI: 10.1021/ic950219s |
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Monomeric Indium(I) and Silver(I) Complexes of a Polyfluorinated Tris(pyrazolyl)borate H. V. Rasika Dias and and Wiechang Jin pp 267 - 268; DOI: 10.1021/ic950901m |
Issue 2
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Platinum Cluster Cryptates: Trapping of Mercury(0) and Thallium(I) Leijun Hao, Jagadese J. Vittal, and Richard J. Puddephatt pp 269 - 270; DOI: 10.1021/ic9509903 |
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[CpAlN(2,6-i-Pr2C6H3)]2: A Dimeric Iminoalane Obtained by Alkane Elimination James D. Fisher, Pamela J. Shapiro, Glenn P. A. Yap, and Arnold L. Rheingold pp 271 - 272; DOI: 10.1021/ic951201k |
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Application of Time-Resolved, Step-Scan Fourier Transform Infrared Spectroscopy to Excited-State Electronic Structure in Polypyridyl Complexes of Rhenium(I) Jon R. Schoonover, Geoffrey F. Strouse, R. Brian Dyer, W. Douglas Bates, Pingyun Chen, and Thomas J. Meyer pp 273 - 274; DOI: 10.1021/ic950905r |
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Polymorphism of ((Tosylimino)iodo)-o-toluene: Two New Modes of Polymeric Association for ArINTs Ronald L. Cicero, Dong Zhao, and John D. Protasiewicz pp 275 - 276; DOI: 10.1021/ic951031b |
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[Cu(CO)n]+ Complex Ions in the Solid State (n = 1, 2, 3) Jeffrey J. Rack, John D. Webb, and Steven H. Strauss pp 277 - 278; DOI: 10.1021/ic951388f |
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The S6 Point Group Conformers of the Hexamethylchalcogens: Me6S, Me6Se, Me6Te Joseph E. Fowler, Henry F. Schaefer, III, and Kenneth N. Raymond pp 279 - 281; DOI: 10.1021/ic940240d |
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Electrochemical Properties and ESR Characterization of Mixed Valence -[XMo3-xVxW9O40]n- Heteropolyanions with X = PV and SiIV, x = 1, 2, or 3 Emmanuel Cadot, Michel Fournier, André Tézé, and Gilbert Hervé pp 282 - 288; DOI: 10.1021/ic940908o |
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Solvatochromism of Mono- and Dimolybdenum Coordination Compounds of Dipyridyloctatetraene and Linear Solvation Energy Relationship Models Based on the Kamlet-Taft and Drago Scales of Solvent Polarity James A. Thomas, Michael G. Hutchings, Christopher J. Jones, and Jon A. McCleverty pp 289 - 296; DOI: 10.1021/ic950357h |
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Analysis of the Vibronic Structure in the Emission and Absorption Spectra of (-1,1-Dicyanoethylene-2,2-dithiolato-S,S')bis(triphenylphosphine)digold(I) and Assignment of the Emissive State Stephen D. Hanna and Jeffrey I. Zink pp 297 - 302; DOI: 10.1021/ic950210q |
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Photoinduced Electron and Energy Transfer in Rigidly Bridged Ru(II)-Rh(III) Binuclear Complexes Maria Teresa Indelli, Franco Scandola, Jean-Paul Collin, Jean-Pierre Sauvage, and Angelique Sour pp 303 - 312; DOI: 10.1021/ic950745j |
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Electron-Transfer Reactions of Re(CO)5: Atom-Transfer-Concerted Mechanism vs Bimetallic Intermediate Formation M. Sarakha and G. Ferraudi pp 313 - 317; DOI: 10.1021/ic950846h |
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Synthesis and Characterization of Copper(II), Zinc(II), and Potassium Complexes of a Highly Fluorinated Bis(pyrazolyl)borate Ligand H. V. Rasika Dias and and John D. Gorden pp 318 - 324; DOI: 10.1021/ic951101e |
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Hexacoordinate Phosphorus. 7. Synthesis and Characterization of Neutral Phosphorus(V) Compounds Containing Divalent Tridentate Diphenol Imine, Azo, and Thio Ligands Chih Y. Wong, Robert McDonald, and Ronald G. Cavell pp 325 - 334; DOI: 10.1021/ic9507530 |
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Technetium(III), Technetium(II), and Technetium(I) Complexes with Pyridine Ligands. Can Pyridine Coordination Stabilize the Low Oxidation States of Technetium? Joseph Barrera, Anthony K. Burrell, and Jeffrey C. Bryan pp 335 - 341; DOI: 10.1021/ic950291q |
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Pyridineselenolate Complexes of Tin and Lead: Sn(2-SeNC5H4)2, Sn(2-SeNC5H4)4, Pb(2-SeNC5H4)2, and Pb(3-Me3Si-2-SeNC5H3)2. Volatile CVD Precursors to Group IV-Group VI Semiconductors Yifeng Cheng, T. J. Emge, and J. G. Brennan pp 342 - 346; DOI: 10.1021/ic9507326 |
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Vanadium(IV) Complexes with Mixed O,S Donor Ligands. Syntheses, Structures, and Properties of the Anions Tris(2-mercapto-4-methylphenolato)vanadate(IV) and Bis(2-mercaptophenolato)oxovanadate(IV) Paul R. Klich, Andrew T. Daniher, Paul R. Challen, David B. McConville, and Wiley J. Youngs pp 347 - 356; DOI: 10.1021/ic950792b |
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Model Investigations for Vanadium-Protein Interactions. Synthetic, Structural, and Physical Studies of Vanadium(III) and Oxovanadium(IV/V) Complexes with Amidate Ligands Anastasios D. Keramidas, Aggelos B. Papaioannou, Antonis Vlahos, Themistoklis A. Kabanos, George Bonas, Alexandros Makriyannis, Cathrin P. Rapropoulou, and Aris Terzis pp 357 - 367; DOI: 10.1021/ic9503803 |
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Bis(ligand) Rhenium(V) and Technetium(V) Complexes of Two Naturally Occurring Binding Moieties (Oxazoline and Thiazoline) Ed Shuter, H. R. Hoveyda, Veranja Karunaratne, Steven J. Rettig, and Chris Orvig pp 368 - 372; DOI: 10.1021/ic9507528 |
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Chromium(VI) Forms Thiolate Complexes with -Glutamylcysteine, N-Acetylcysteine, Cysteine, and the Methyl Ester of N-Acetylcysteine Samuel L. Brauer, Azzam S. Hneihen, John S. McBride, and Karen E. Wetterhahn pp 373 - 381; DOI: 10.1021/ic941452d |
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Synthesis, Structure, and Properties of a Model for Galactose Oxidase Mei M. Whittaker, Walter R. Duncan, and James W. Whittaker pp 382 - 386; DOI: 10.1021/ic951116c |
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Synthesis and Characterization of New Chiral Schiff Base Complexes with Diiminobinaphthyl or Diiminocyclohexyl Moieties as Potential Enantioselective Epoxidation Catalysts Katia Bernardo, Simon Leppard, Anne Robert, Gérard Commenges, Françoise Dahan, and Bernard Meunier pp 387 - 396; DOI: 10.1021/ic950700i |
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The Uracil C(5) Position as a Metal Binding Site: Solution and X-ray Crystal Structure Studies of PtII and HgII Compounds Markus Höpp, Andrea Erxleben, Ingo Rombeck, and Bernhard Lippert pp 397 - 403; DOI: 10.1021/ic950842c |
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N,N'-Ethylenedi-L-cysteine (EC) and Its Metal Complexes: Synthesis, Characterization, Crystal Structures, and Equilibrium Constants Yuejin Li, Arthur E. Martell, Robert D. Hancock, Joseph H. Reibenspies, Carolyn J. Anderson, and Michael J. Welch pp 404 - 414; DOI: 10.1021/ic941330l |
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Heteronuclear NMR Studies of Cobalt Corrinoids. 18. Correlation of Structure and Magnetic Resonance Parameters in Base-On Cobalamins Kenneth L. Brown, Daniel R. Evans, Jeffrey D. Zubkowski, and Edward J. Valente pp 415 - 423; DOI: 10.1021/ic950951r |
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Kinetics and Mechanism of the Reaction between Serum Albumin and Auranofin (and Its Isopropyl Analogue) in Vitro Jacqueline R. Roberts, Jun Xiao, Brian Schliesman, David J. Parsons, and C. Frank Shaw, III pp 424 - 433; DOI: 10.1021/ic9414280 |
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Electron Paramagnetic Resonance Spectroscopy of the Iron-Molybdenum Cofactor of Clostridium pasteurianum Nitrogenase Graham N. George, Roger C. Prince, and Richard E. Bare pp 434 - 438; DOI: 10.1021/ic950740m |
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Axial Imidazole Distortion Effects on the Catalytic and Binding Properties of Chelated Deuterohemin Complexes Luigi Casella and, Enrico Monzani, Piercarlo Fantucci, Michele Gullotti, Luca De Gioia, Alberto Strini, and Francesco Chillemi pp 439 - 444; DOI: 10.1021/ic950148x |
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{H(3-tBupz)B(3-tBupz)2-2}AlEt2 and {H(3-tBupz)B(3-tBupz)(5-tBupz)-2}AlEt2. Structure, Dynamic Solution Behavior, and the 1,2-Borotropic Shift Malcolm H. Chisholm, Nancy W. Eilerts, and John C. Huffman pp 445 - 450; DOI: 10.1021/ic950582z |
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Compounds Containing Copper-Sulfur Layers: Electronic Structure, Conductivity, and Stability Grigori V. Vajenine and Roald Hoffmann pp 451 - 457; DOI: 10.1021/ic951046+ |
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Developing Reagents To Orient Fullerene Derivatives. Formation and Structural Characterization of (2-C60O)Ir(CO)Cl(As(C6H5)3)2 Alan L. Balch, David A. Costa, Bruce C. Noll, and Marilyn M. Olmstead pp 458 - 462; DOI: 10.1021/ic950484d |
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New Layered Polyborates Cs2M2B10O17 (M = Na, K) Jun-Ming Tu and Douglas A. Keszler pp 463 - 466; DOI: 10.1021/ic950306k |
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Dipicolylamine Complexes of Copper(II): Two Different Coordination Geometries in the Same Unit Cell of Cu(Dipica)2(BF4)2 Mallayan Palaniandavar, Raymond J. Butcher, and Anthony W. Addison pp 467 - 471; DOI: 10.1021/ic941396g |
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Intermolecular Ferromagnetic and Antiferromagnetic Interactions in Halogen-Bridged Copper(I) Imino Nitroxides: Crystal Structures and Magnetic Properties of [CuI(-X)(imino nitroxide)]2 (X = I or Br) Hiroki Oshio, Takashi Watanabe, Akihiro Ohto, Tasuku Ito, and Hideki Masuda pp 472 - 479; DOI: 10.1021/ic950663v |
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Crystal Structure and Spectroscopic Characterization of K6(VO)4(SO4)8 Containing Mixed-Valent Vanadium(IV)-Vanadium(V) Kim Michael Eriksen, Kurt Nielsen, and Rasmus Fehrmann pp 480 - 484; DOI: 10.1021/ic9504304 |
Unusual 180 P-O-P Bond Angles in ZrP2O7N. Khosrovani, V. Korthuis, A. W. Sleight, and T. Vogt pp 485 - 489; DOI: 10.1021/ic950844x |
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Hinge Distortion in Platinum(II) Dimers with a Pt2S2 Ring. An ab Initio Molecular Orbital Study Mercè Capdevila, William Clegg, Pilar González-Duarte, Abdellah Jarid, and Agustí Lledós pp 490 - 497; DOI: 10.1021/ic950341r |
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Synthesis and Structural Studies of Platinum Complexes Containing Monodentate, Bridging, and Chelating Formamidine Ligands F. Albert Cotton, John H. Matonic, and Carlos A. Murillo pp 498 - 503; DOI: 10.1021/ic950741e |
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Synthesis of Lower Valent Molybdenum Oxides by an Ambient Temperature Reduction of Aqueous K2MoO4 by KBH4 C. Tsang, A. Dananjay, J. Kim, and A. Manthiram pp 504 - 509; DOI: 10.1021/ic950955w |
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Unusual Reactivity Mode of Coordinated Oximes: Platinum(IV)-Assisted Ring Closure by Reaction with Acetone Vadim Yu. Kukushkin, Vitaly K. Belsky, and David Tudela pp 510 - 513; DOI: 10.1021/ic950351s |
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Synthesis of Polysiloxane-Bound (Ether-phosphine)palladium Complexes. Stoichiometric and Catalytic Reactions in Interphases Ekkehard Lindner, Rudolf Schreiber, Theodor Schneller, Peter Wegner, Hermann A. Mayer, Wolfgang Göpel, and Christiane Ziegler pp 514 - 525; DOI: 10.1021/ic950412m |
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Chemistry of Bis(aryloxo)palladium(II) Complexes with N-Donor Ligands: Structural Features of the Palladium-to-Oxygen Bond and Formation of O-H···O Bonds Gerardus M. Kapteijn, David M. Grove, Huub Kooijman, Wilberth J. J. Smeets, Anthony L. Spek, and Gerard van Koten pp 526 - 533; DOI: 10.1021/ic950563p |
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Palladium(II) Arenethiolates with Chelating Diamines: Formation of N-H···S Hydrogen Bonds with Protonated N,N,N',N'-Tetramethylethylenediamine Gerardus M. Kapteijn, David M. Grove, Wilberth J. J. Smeets, Huub Kooijman, Anthony L. Spek, and Gerard van Koten pp 534 - 536; DOI: 10.1021/ic950701a |
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Uranium-Mediated Ring Opening of Tetrahydrofuran. Crystal Structure of UI2(OCH2CH2CH2CH2I)2(Ph3P=O)2 Larry R. Avens, David M. Barnhart, Carol J. Burns, and Steven D. McKee pp 537 - 539; DOI: 10.1021/ic9505211 |
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Synthesis and Crystal Structure of a Cationic Oxo-Bridged Nitridoruthenium(VI) Complex with a Chelating Diamine Ligand Having No -CH Group Wing-Hong Chiu, Chun-Xiao Guo, Kung-Kai Cheung, and Chi-Ming Che pp 540 - 541; DOI: 10.1021/ic950498j |
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Synthesis, Crystal Structure, and Solution Properties of a Hexacopper(II) Complex with Bridging Hydroxides, Pyrazolates, and Nitrates Ken Sakai, Yasutaka Yamada, Taro Tsubomura, Masayuki Yabuki, and Motowo Yamaguchi pp 542 - 544; DOI: 10.1021/ic950181j |
Issue 3
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Powder Neutron Diffraction in an Applied Magnetic Field: A Novel Tool for Transition Metal Chemistry Philip A. Reynolds, Elliot P. Gilbert, and Brian N. Figgis pp 545 - 546; DOI: 10.1021/ic9509589 |
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Phosphatovanadium Chemistry: Behavior of Phosphato Groups Covalently Bound to Only One Vanadyl Center David L. Thorn, Richard L. Harlow, and Norman Herron pp 547 - 548; DOI: 10.1021/ic950790r |
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Structures of [M2(dimen)4](Y)2 (M = Rh, Ir; dimen = 1,8-Diisocyanomenthane; Y = PF6, Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate, B(C6H5)4) Crystals Featuring an Exceptionally Wide Range of Metal-Metal Distances and Dihedral Twist Angles Christopher L. Exstrom, Doyle Britton, Kent R. Mann, Michael G. Hill, Vincent M. Miskowski, William P. Schaefer, Harry B. Gray, and William M. Lamanna pp 549 - 550; DOI: 10.1021/ic9508637 |
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A Hydrolysis-Resistant Terminal ME Bond (M = Nb; E = S, Se: M = Ta; E = S) in a Chalcogenido-Substituted Mixed-Metal Polyoxoanion Emil Radkov, Ying-Jie Lu, and Robert H. Beer pp 551 - 552; DOI: 10.1021/ic951053y |
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Pyramidal Tellurite Ions Te(NtBu)2(EtBu)- (E = O, NH): Syntheses and Structures of [K(THF)Te(NtBu)2(OtBu)]2 and {[LiTe(NtBu)2(NHtBu)]2LiCl}2 Tristram Chivers, Xiaoliang Gao, and Masood Parvez pp 553 - 554; DOI: 10.1021/ic951500+ |
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Synthesis and Structure of Cadmium Chalcogenide Beryllosilicate Sodalites S. E. Dann and M. T. Weller pp 555 - 558; DOI: 10.1021/ic950760o |
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First Example of a CuII Polymeric Complex Having a Tetranuclear Repeating Unit with a S = 2 Ground State. Crystal Structure of [Cu4(dpk·CH3O)2Cl6]n (dpk·CH3OH = Unimethylated Diol of Di-2-pyridyl Ketone) Athanassios N. Papadopoulos, Vasilis Tangoulis, Catherine P. Raptopoulou, Aris Terzis, and Dimitris P. Kessissoglou pp 559 - 565; DOI: 10.1021/ic950659j |
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5,20-Diphenyl-10,15-bis(p-tolyl)-21-selenaporphyrin and Its Nickel(II) Complexes Lechos  aw Latos-Gra y ski, Ewa Pacholska, Piotr J. Chmielewski, Marilyn M. Olmstead, and Alan L. Balchpp 566 - 573; DOI: 10.1021/ic950329z |
Pressure-Induced Spin-State Crossovers in Six-Coordinate FeIILnL'm(NCS)2 Complexes with L = L' and L  L': A XANES InvestigationCécile Roux, Jacqueline Zarembowitch, Jean-Paul Itié, Alain Polian, and Michel Verdaguer pp 574 - 580; DOI: 10.1021/ic9507023 |
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Synthesis and Structure of Two New Ternary Nitrides: FeWN2 and MnMoN2 David S. Bem, Christina M. Lampe-Önnerud, Hans P. Olsen, and Hans-Conrad zur Loye pp 581 - 585; DOI: 10.1021/ic9512338 |
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Proton and Metal Ion Interactions with Glycylglycylhistamine, a Serum Albumin Mimicking Pseudopeptide Tamás Gajda, Bernard Henry, André Aubry, and Jean-Jacques Delpuech pp 586 - 593; DOI: 10.1021/ic950373e |
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Stereochemistry of Seven-Coordinate Main Group and d0 Transition Metal Molecules Zhenyang Lin and and Ian Bytheway pp 594 - 603; DOI: 10.1021/ic950271o |
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Phosphine-Based Platinum(II) Hydroxo and Oxo Complexes Jian Jun Li, Wei Li, and Paul R. Sharp pp 604 - 613; DOI: 10.1021/ic950593s |
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Mechanistic Studies on the Reactions of Molybdenum(VI), Tungsten(VI), Vanadium(V), and Arsenic(V) Tetraoxo Anions with the FeIIFeIII Form of Purple Acid Phosphatase from Porcine Uteri (Uteroferrin) Joo-Sang Lim, Manuel A. S. Aquino, and A. Geoffrey Sykes pp 614 - 618; DOI: 10.1021/ic950139o |
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Synthesis, Crystal Structure, Antitumor Activity, and DNA-Binding Properties of the New Active Platinum Compound (Bis(N-methylimidazol-2-yl)carbinol)dichloroplatinum(II), Lacking a NH Moiety, and of the Inactive Analog Dichloro(N1,N1'-dimethyl-2,2'-biimidazole)platinum(II) Marieke J. Bloemink, Holger Engelking, Stefan Karentzopoulos, Bernt Krebs, and Jan Reedijk pp 619 - 627; DOI: 10.1021/ic950584j |
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Novel Building Blocks for Biomimetic Assemblies. Synthesis, Characterization, and Spectroscopic and Electrochemical Properties of New Bidentate Ligands Derived from Lysine and Cysteine and Their Complexes with Bis(2,2'-bipyridine)ruthenium(II) Ralf Alsfasser and and Rudi van Eldik pp 628 - 636; DOI: 10.1021/ic951176i |
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Dendrimer-Based Multinuclear Gold(I) Complexes Peter Lange, Annette Schier, and Hubert Schmidbaur pp 637 - 642; DOI: 10.1021/ic950644l |
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Trans Influence of Oxo and Dithiolene Coordination in Oxidized Models of Molybdenum Oxidoreductase: Synthesis, Structures, and Properties of Q2[MoVIO2(1,2-benzenedithiolato)2] (Q = NEt4, PPh4) and Related Complexes Norikazu Ueyama, Hiroyuki Oku, Mitsuru Kondo, Taka-aki Okamura, Naoto Yoshinaga, and Akira Nakamura pp 643 - 650; DOI: 10.1021/ic950204u |
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Reaction of Chromium(V) with the EPR Spin Traps 5,5-Dimethylpyrroline N-Oxide and Phenyl-N-tert-butylnitrone Resulting in Direct Oxidation Kent D. Sugden and Karen E. Wetterhahn pp 651 - 657; DOI: 10.1021/ic9506318 |
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Platinum-Rhenium-Mercury and Related Cluster Chemistry Leijun Hao, Jianliang Xiao, Jagadese J. Vittal, Richard J. Puddephatt, Ljubica Manojlovi  -Muir, Kenneth W. Muir, and Ali Ashgar Torabipp 658 - 666; DOI: 10.1021/ic950825n |
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Alkali Metal Induced Structural Changes in Complexes Containing Anionic Lanthanum Aryloxide Moieties. X-ray Crystal Structures of (THF)La(OAr)2(-OAr)2Li(THF), (THF)La(OAr)2(-OAr)2Na(THF)2, and CsLa(OAr)4 (Ar = 2,6-i-Pr2C6H3) David L. Clark, Rebecca V. Hollis, Brian L. Scott, and John G. Watkin pp 667 - 674; DOI: 10.1021/ic9510472 |
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Photochemical C-H Bond Activation Reactivity of (HBPz'3)Rh(CO)2 (Pz' = 3,5-Dimethylpyrazolyl) in Alkane Solutions Agus A. Purwoko and Alistair J. Lees pp 675 - 682; DOI: 10.1021/ic951199x |
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Syntheses and Characterization of (Diamine-N,N'-dicarboxylato)chromate(III) Dinuclear Complexes Bridged by Pyrazole-3,5-dicarboxylate: X-ray Structures of Na[Cr2(edda)2(-pzdc)]·5H2O and Na[Cr2(trdda)2(-pzdc)]·3H2O Narumi Sakagami, Manabu Nakahanada, Kazuhito Ino, Ayako Hioki, and Sumio Kaizaki pp 683 - 688; DOI: 10.1021/ic9503693 |
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Cluster Chemistry on Surfaces: Characterization and Catalytic Studies of Phosphine-Stabilized Platinum-Gold Clusters on Silica and Alumina Supports Irina V. G. Graf, Jeffrey W. Bacon, Mark B. Consugar, Michael E. Curley, Larry N. Ito, and Louis H. Pignolet pp 689 - 694; DOI: 10.1021/ic9504147 |
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Fluxionality in [ReH5(PPh3)2(pyridine)] Jesse C. Lee, Jr., Wenbin Yao, Robert H. Crabtree, and Heinz Rüegger pp 695 - 699; DOI: 10.1021/ic950929y |
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Crystal Structure and Spectroscopic Characterization of a Luminescent Europium Chelate Paul R. Selvin, Jaru Jancarik, Min Li, and Li-Wei Hung pp 700 - 705; DOI: 10.1021/ic950840s |
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Multinuclear NMR Study of Fluoroaluminate Complexes in Aqueous Solution Eric J. Martinez, Jean-Luc Girardet, and Claude Morat pp 706 - 710; DOI: 10.1021/ic9507575 |
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Electron Transfer through Norbornadiene and Quadricyclane Moieties as a Model for Molecular Switching Philippe Lainé, Valérie Marvaud, André Gourdon, Jean-Pierre Launay, Roberto Argazzi, and Carlo-Alberto Bignozzi pp 711 - 714; DOI: 10.1021/ic9507225 |
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Selectivity of Potentially Hexadentate Amine Phenols for Ga3+ and In3+ in Aqueous Solution Ernest Wong, P. Caravan, Shuang Liu, Steven J. Rettig, and Chris Orvig pp 715 - 724; DOI: 10.1021/ic951019j |
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Electrochemistry and Spectroelectrochemistry of Chloro(phthalocyaninato)Rhodium(III) Species in Solution Phase A. B. P. Lever, Yuhong Tse, V. Manivannan, Penny Seymour, Vladimir V. Strelets, and Lalchan S. Persaud pp 725 - 734; DOI: 10.1021/ic950618n |
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Equilibrium and High-Pressure Kinetic Study of Formation and Proton-Assisted Aquation of Monodentate Acetate, Propionate, and Glycolate Complexes of Palladium(II) in Aqueous Solution Tiesheng Shi and Lars I. Elding pp 735 - 740; DOI: 10.1021/ic950935u |
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Syntheses and Properties of Cyclopentadienyl-Substituted Imidotitanium Fluorides Feng-Quan Liu, Axel Herzog, Herbert W. Roesky, and Isabel Usón pp 741 - 744; DOI: 10.1021/ic950778z |
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Anionic Cadmium Complexes Containing the Bulky Tris(trimethylsilyl)germyl and Tris(trimethylsilyl)silyl Ligands Siva P. Mallela, Frank Schwan, and R. A. Geanangel pp 745 - 748; DOI: 10.1021/ic951061e |
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Synthesis, Molecular Structure, and Physical Properties of [tetrakis((methylthio)methyl)borate]2M (M = Fe, Co, Ni) Carl Ohrenberg, Pinghua Ge, Peter Schebler, Charles G. Riordan, Glenn P. A. Yap, and Arnold L. Rheingold pp 749 - 754; DOI: 10.1021/ic9511377 |
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Kinetic Studies on Reactions of Activated Triruthenium Carbonyl Clusters with Phosphorus Ligands Jian-Kun Shen, Fred Basolo, Paul Nombel, Noël Lugan, and Guy Lavigne pp 755 - 759; DOI: 10.1021/ic950947f |
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Mono- and Bimetallic Bipyridyl Polyene Complexes Containing 17-Electron Molybdenum Mononitrosyl Centers: Electrochemical, Spectroscopic, and Magnetic Studies Sean L. W. McWhinnie, James A. Thomas, Thomas A. Hamor, Christopher J. Jones, Jon A. McCleverty, David Collison, Frank E. Mabbs, Charlie J. Harding, Lesley J. Yellowlees, and Michael G. Hutchings pp 760 - 774; DOI: 10.1021/ic950358+ |
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Transition Metal Fischer-Type Complexes. Density Functional Analysis of the Systems (CO)5Cr=EH2 (E = C, Si, Ge, Sn) and (CO)5M=CH2 (M = Mo, W, Mn+) Heiko Jacobsen and Tom Ziegler pp 775 - 783; DOI: 10.1021/ic941006q |
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EXAFS Determinations of Uranium Structures: The Uranyl Ion Complexed with Tartaric, Citric, and Malic Acids P. G. Allen, D. K. Shuh, J. J. Bucher, N. M. Edelstein, T. Reich, M. A. Denecke, and H. Nitsche pp 784 - 787; DOI: 10.1021/ic9508536 |
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Metal Hydroperoxides as Oxygen Atom Transfer Reagents A. Bakac, B. Assink, J. H. Espenson, and W.-D. Wang pp 788 - 790; DOI: 10.1021/ic951166h |
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Preparation of [(5-C5H5)2TiB6H9]2: A Metallo Derivative of Hexaborane(10) Douglas L. Denton, Robert A. Godfroid, Lawrence Barton, and Sheldon G. Shore pp 791 - 792; DOI: 10.1021/ic9513292 |
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Preparation, Structure, and Properties of an Anionic Tetrameric Copper Complex Containing a Planar, Eight-Membered Ring Core Anthony E. Pullen, Jens Piotraschke, Khalil A. Abboud, and John R. Reynolds pp 793 - 796; DOI: 10.1021/ic950879x |
Issue 4
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Solid-State 109Ag NMR: A Sensitive Environmental Probe for Silver Thiolates Hilary G. Fijolek, Tracy A. Oriskovich, Alan J. Benesi, Pilar González-Duarte, and Michael J. Natan pp 797 - 799; DOI: 10.1021/ic950824v |
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Magnetic Properties of Metal-Intercalated Layered Vanadyl Phosphates Dimitris Papoutsakis, James E. Jackson, and Daniel G. Nocera pp 800 - 801; DOI: 10.1021/ic950931p |
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Synthesis and Characterization of the First Neutral Zinc-Sulfur Cluster: Zn10S4(SEt)12L4 May D. Nyman, Mark J. Hampden-Smith, and Eileen N. Duesler pp 802 - 803; DOI: 10.1021/ic951470a |
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Copper(I)/Dioxygen Reactivity with Dinuclear Compounds: Catalytic Oxygenation and Oxo-Transfer to a Ketone Dong-Heon Lee, Narasimha N. Murthy, and Kenneth D. Karlin pp 804 - 805; DOI: 10.1021/ic951490c |
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Molecular Structures of Sulfur Cyanide Trifluoride, SF3CN, and Sulfinyl Cyanide Fluoride, FS(O)CN Hans-Georg Mack, Heinz Oberhammer, Jürgen Jacobs, Marc Kronberg, and Helge Willner pp 806 - 810; DOI: 10.1021/ic9511940 |
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Molecular Structures and Photophysical Properties of Dirhodium Fluorophosphine Complexes Janice Kadis, Yeung-gyo K. Shin, Joel I. Dulebohn, Donald L. Ward, and Daniel G. Nocera pp 811 - 817; DOI: 10.1021/ic9505615 |
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Building Block Approach to the Construction of Long-Lived Osmium(II) and Ruthenium(II) Multimetallic Complexes Incorporating the Tridentate Bridging Ligand 2,3,5,6-Tetrakis(2-pyridyl)pyrazine Lisa M. Vogler and Karen J. Brewer pp 818 - 824; DOI: 10.1021/ic950709k |
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Three-Dimensional Hückel Theory for closo-Carboranes Benjamin M. Gimarc and Ming Zhao pp 825 - 834; DOI: 10.1021/ic9506668 |
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Nature of Transients in the Laser Flash Photolysis of the Tribromocuprate(I) Complex Kenneth L. Stevenson, David W. Knorr, and Attila Horváth pp 835 - 839; DOI: 10.1021/ic950383f |
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Chemistry in Molten Alkali Metal Polyselenophosphate Fluxes. Influence of Flux Composition on Dimensionality. Layers and Chains in APbPSe4, A4Pb(PSe4)2 (A = Rb, Cs), and K4Eu(PSe4)2 Konstantinos Chondroudis, Timothy J. McCarthy, and Mercouri G. Kanatzidis pp 840 - 844; DOI: 10.1021/ic950479+ |
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Crystal Structure, Electrical Transport, and Magnetic Properties of Niobium Monophosphide J. Xu, M. Greenblatt, T. Emge, P. Höhn, T. Hughbanks and, and Y. Tian pp 845 - 849; DOI: 10.1021/ic950826f |
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Non-Template-Centered, Closed Tetravanadium Phosphate and Phosphonate Clusters Tom Otieno, Ladd M. Mokry, Marcus R. Bond, Carl J. Carrano, and Norman S. Dean pp 850 - 856; DOI: 10.1021/ic951017z |
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Effect of K+ on the Stoichiometry of Carbonated Hydroxyapatite Obtained by the Hydrolysis of Monetite Erna A. P. De Maeyer, Ronald M. H. Verbeeck, and Ilse Y. Pieters pp 857 - 863; DOI: 10.1021/ic950916k |
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Two New Antiferromagnetic Nickel(II) Complexes Bridged by Azido Ligands in the Cis Position. Effect of the Counteranion on the Crystal Structure and Magnetic Properties Joan Ribas, Montserrat Monfort, Barindra Kumar Ghosh, Roberto Cortés, Xavier Solans, and Mercé Font-Bardía pp 864 - 868; DOI: 10.1021/ic9510573 |
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Surface Organometallic Chemistry on Oxides: Reaction of Trimethylphosphine with Bis(allyl)rhodium Grafted onto Silica Susannah L. Scott, Pascal Dufour, Catherine C. Santini, and Jean-Marie Basset pp 869 - 875; DOI: 10.1021/ic9405790 |
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Coordination and peri-Carbon Metalation of 1-Nitro-9-[(2-aminoethyl)amino]acridines toward Platinum(II). Evidences for Hydrogen Bonding between Endocyclic N(10)H and Chloride Ion Edmondo Ceci, Renzo Cini, Jerzy Konopa, Luciana Maresca, and Giovanni Natile pp 876 - 882; DOI: 10.1021/ic950804t |
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Comparison of the Properties of SnCl3- and SnBr3- Complexes of Platinum(II) John H. Nelson, William L. Wilson, Lewis W. Cary, Nathaniel W. Alcock, Howard J. Clase, Gouri S. Jas, Lori Ramsey-Tassin, and John W. Kenney, III pp 883 - 892; DOI: 10.1021/ic9507878 |
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Heterobimetallic Clusters of Copper(I) with Trithiotungstate and Trithiomolybdate. Synthesis and Characterization of the Octanuclear Clusters [Et4N]4[M4Cu4S12O4] (M = Mo, W) and the Dodecanuclear Clusters [M4Cu4S12O4(CuTMEN)4] (M = Mo, W; TMEN = N,N,N',N'-Tetramethylethylenediamine) Qun Huang, Xintao Wu, Quanming Wang, Tianlu Sheng, and Jiaxi Lu pp 893 - 897; DOI: 10.1021/ic950113x |
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Synthesis and Chemical and Electrochemical Characterization of Fe-S Carbonyl Clusters. X-ray Crystal Structures of [N(PPh3)2]2[Fe5S2(CO)14] and [N(PPh3)2]2[Fe6S6(CO)12] Francesca Calderoni, Francesco Demartin, Maria Carmela Iapalucci, Franco Laschi, Giuliano Longoni, and Piero Zanello pp 898 - 905; DOI: 10.1021/ic950482t |
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Synthesis and Characterization of Six-Coordinate Nitrido Complexes of Vanadium(V), Chromium(V), and Manganese(V). Isolation of a Dinuclear, Mixed-Valent -Nitrido Chromium(III)/Chromium(V) Species Andrea Niemann, Ursula Bossek, Gabriele Haselhorst, Karl Wieghardt, and Bernhard Nuber pp 906 - 915; DOI: 10.1021/ic9508031 |
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Synthesis and Electrochemistry of Heterobimetallic Ruthenium/Platinum and Molybdenum/Platinum Complexes Stephen D. Orth, Michael R. Terry, Khalil A. Abboud, Brian Dodson, and Lisa McElwee-White pp 916 - 922; DOI: 10.1021/ic9510977 |
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Synthesis, Characterization, and Comparative Properties of [PPN]2[Re6C(CO)18Mo(CO)4] and [PPN]2[Re6C(CO)18Ru(CO)3] Gishun Hsu, Scott R. Wilson, and John R. Shapley pp 923 - 928; DOI: 10.1021/ic950887d |
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Tetrachloro- and Tetrabromostibonium(V) Cations: Raman and 19F, 121Sb, and 123Sb NMR Spectroscopic Characterization and X-ray Crystal Structures of SbCl4+Sb(OTeF5)6- and SbBr4+Sb(OTeF5)6- William J. Casteel, Jr., Peter Kolb, Nicolas LeBlond, Hélène P. A. Mercier, and Gary J. Schrobilgen pp 929 - 942; DOI: 10.1021/ic950818z |
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Synthesis and Structure of [TpBut2]In, a Highly Twisted [Tris(3,5-di-tert-butylpyrazolyl)hydroborato]indium(I) Complex: Comparison with the Re-Evaluated Ordered Structure of [TpBut]In Matthew C. Kuchta, H. V. Rasika Dias, Simon G. Bott, and Gerard Parkin pp 943 - 948; DOI: 10.1021/ic9509948 |
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Atomic Proximity Due to Molecular Congestion: Rational Design of Bis(phosphite) Ligands by Restriction of Molecular Motion Stephen D. Pastor, Sai P. Shum, Anthony D. DeBellis, Lilibeth P. Burke, Ronald K. Rodebaugh, Frank H. Clarke, and Grety Rihs pp 949 - 958; DOI: 10.1021/ic9509286 |
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Dithiacrown Ether Substituted Porphyrazines: Synthesis, Single-Crystal Structure, and Control of Aggregation in Solution by Complexation of Transition-Metal Ions Cornelus F. van Nostrum, Franciscus B. G. Benneker, Hugo Brussaard, Huub Kooijman, Nora Veldman, Anthony L. Spek, Joop Schoonman, Martinus C. Feiters, and Roeland J. M. Nolte pp 959 - 969; DOI: 10.1021/ic950704n |
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Primitive Molecular Recognition Effects in Electron Transfer Processes: Modulation of ((Trimethylammonio)methyl)ferrocenium/ferrocene Self-Exchange Kinetics via Hydrophobic Encapsulation Roger M. Nielson, L. Andrew Lyon, and Joseph T. Hupp pp 970 - 973; DOI: 10.1021/ic950569e |
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(Pyridine)pentaamminechromium(III). Synthesis, Characterization, and Photochemistry Pietro Riccieri and Edoardo Zinato pp 974 - 980; DOI: 10.1021/ic950904z |
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Mechanism for Solvent Exchange on trans-[Os(en)2(2-H2)S]2+ Urban Frey, Zai-Wei Li, and Anne Matras pp 981 - 984; DOI: 10.1021/ic9510775 |
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Kinetics of Water Exchange on the Dihydroxo-Bridged Rhodium(III) Hydrolytic Dimer Alexander Drljaca, Leone Spiccia, H. Roy Krouse, and Thomas W. Swaddle pp 985 - 990; DOI: 10.1021/ic950423f |
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Volume Profile for Substitution in Labile Chromium(III) Complexes: Reactions of Aqueous [Cr(Hedta)OH2] and [Cr(edta)]- with Thiocyanate Ion Colin L. Beswick, Richard D. Shalders, and Thomas W. Swaddle pp 991 - 994; DOI: 10.1021/ic951110n |
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Equilibrium and Kinetics of Bromine Hydrolysis Richard C. Beckwith, Tian Xiang Wang, and Dale W. Margerum pp 995 - 1000; DOI: 10.1021/ic950909w |
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Synthesis, Structural Characterization, and Oxidation-Reduction Behavior of the -Isomer of the Dodecatungstosilicate Anion André Tézé, Jacqueline Canny, Lucian Gurban, René Thouvenot, and Gilbert Hervé pp 1001 - 1005; DOI: 10.1021/ic951004l |
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Imidotitanium Tris(pyrazolyl)hydroborates: Synthesis, Solution Dynamics, and Solid-State Structure Simon C. Dunn, Philip Mountford, and Oleg V. Shishkin pp 1006 - 1012; DOI: 10.1021/ic9510674 |
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Electrochemical Parametrization in Sandwich Complexes of the First Row Transition Metals Shuangxing Lu, Vladimir V. Strelets, Matthew F. Ryan, William J. Pietro, and A. B. P. Lever pp 1013 - 1023; DOI: 10.1021/ic950620e |
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A Nearly Linear Single Hydroxo Bridge. Synthesis, Structure, and Magnetic Susceptibility of (-Hydroxo)bis((tetraphenylporphinato)manganese(III)) Perchlorate Beisong Cheng, Pascal H. Fries, Jean-Claude Marchon, and W. Robert Scheidt pp 1024 - 1032; DOI: 10.1021/ic951041c |
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Iron-Semiquinone, Semiquinone-Semiquinone, and Iron-Iron Magnetic Exchange in Monomeric and Dimeric Ferric Complexes Containing the 3,6-Di-tert-butyl-1,2-semiquinonate Ligand Attia S. Attia, Brenda J. Conklin, Christopher W. Lange, and Cortlandt G. Pierpont pp 1033 - 1038; DOI: 10.1021/ic950595c |
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Synthetic, X-ray Structure, Electron Paramagnetic Resonance, and Magnetic Studies of the Manganese(II) Complex of 1-Thia-4,7-diazacyclononane ([9]aneN2S) Lawrence R. Gahan, Vincent A. Grillo, Trevor W. Hambley, Graeme R. Hanson, Clifford J. Hawkins, Emma M. Proudfoot, Boujemaa Moubaraki, Keith S. Murray, and Deming Wang pp 1039 - 1044; DOI: 10.1021/ic950549c |
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Metal Complex-Catalyzed Epoxidation of Olefins by Dioxygen with Co-Oxidation of Aldehydes. A Mechanistic Study Wonwoo Nam, Hyo Jin Kim, Seong Hoon Kim, Raymond Y. N. Ho, and Joan Selverstone Valentine pp 1045 - 1049; DOI: 10.1021/ic950782a |
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Oxygen Atom Transfer, Coupled Electron-Proton Transfer, and Correlated Electron-Nucleophile Transfer Reactions of Oxomolybdenum(IV) and Dioxomolybdenum(VI) Complexes Les J. Laughlin and Charles G. Young pp 1050 - 1058; DOI: 10.1021/ic950815m |
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Formation of Metallo-6A-((2-(bis(2-aminoethyl)amino)ethyl)amino)-6A-deoxy--cyclodextrins and Their Complexation of Tryptophan in Aqueous Solution Carolyn A. Haskard, Christopher J. Easton, Bruce L. May, and Stephen F. Lincoln pp 1059 - 1064; DOI: 10.1021/ic9510831 |
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Ring-Opened Adducts of the Anticancer Drug Carboplatin with Sulfur Amino Acids Kevin J. Barnham, Milos I. Djuran, Piedad del Socorro Murdoch, John D. Ranford, and Peter J. Sadler pp 1065 - 1072; DOI: 10.1021/ic950973d |
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Theoretical Study of the Oxidation of Nickel Thiolate Complexes by O2 Michael J. Maroney, Suranjan B. Choudhury, Peter A. Bryngelson, Shaukat A. Mirza, and Michael J. Sherrod pp 1073 - 1076; DOI: 10.1021/ic950162+ |
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Synthesis, Characterization, and Structural Determination of the Bimetallic Alkoxide ErAl3(OC3H7i)12 M. Wijk, R. Norrestam, M. Nygren, and G. Westin pp 1077 - 1079; DOI: 10.1021/ic9502685 |
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Synthesis and Characterization of (Et4N)4[MoS4Cu10Cl12]: A Polynuclear Molybdenum-Copper Cluster Containing a Central Tetrahedral MoS4 Encapsulated by Octahedral Cu6 and Tetrahedral Cu4 Arrays Daxu Wu, Maochun Hong, Rong Cao, and Hanqin Liu pp 1080 - 1082; DOI: 10.1021/ic9410304 |
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Design of Trigonal-Bipyramidal ZnN3S2 Complexes Udo Brand, Rainer Burth, and Heinrich Vahrenkamp pp 1083 - 1086; DOI: 10.1021/ic950731d |
Issue 5
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Organodiborate Ring Transformations Promoted by Zirconocene and Hafnocene Dichlorides. Preparation and Structure of (5-C5H5)2ZrCl{(-H)2BC4H8} Glenn T. Jordan IV and Sheldon G. Shore pp 1087 - 1088; DOI: 10.1021/ic951316o |
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Bis[(-chloro)copper(II)] Amethyrin: A Bimetallic Copper(II) Complex of an Expanded Porphyrin Steven J. Weghorn, Jonathan L. Sessler, Vincent Lynch, Theodore F. Baumann and, and John W. Sibert pp 1089 - 1090; DOI: 10.1021/ic9509692 |
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A Trinuclear Double-Helical Metal Complex of a Quinquepyridine Analog Anthony T. Baker, Donald C. Craig, and Gordon Dong pp 1091 - 1092; DOI: 10.1021/ic951372p |
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Role of Trans Ligands in the Reductive Cleavage of the -Oxo-Diiron Bridge Isak Vernik and Dennis V. Stynes pp 1093 - 1094; DOI: 10.1021/ic951478k |
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A Novel Potassium-Binding Hydrolysis Product of Ascidiacyclamide: A Cyclic Octapeptide Isolated from the Ascidian Lissoclinum patella Anna L. van den Brenk, David P. Fairlie, Lawrence R. Gahan, Graeme R. Hanson, and Trevor W. Hambley pp 1095 - 1100; DOI: 10.1021/ic9504755 |
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Synthesis, Structure, and Reactivity of Model Complexes of Copper Nitrite Reductase Luigi Casella and, Oliviero Carugo, Michele Gullotti, Sergio Doldi, and Massimiliano Frassoni pp 1101 - 1113; DOI: 10.1021/ic950392o |
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Effect of Nitrogen Methylation on Cation and Anion Coordination by Hexa- and Heptaazamacrocycles. Catalytic Properties of These Ligands in ATP Dephosphorylation Andrea Bencini, Antonio Bianchi, Claudia Giorgi, Piero Paoletti, Barbara Valtancoli, Vieri Fusi, Enrique García-España, José M. Llinares, and José Antonio Ramírez pp 1114 - 1120; DOI: 10.1021/ic9506926 |
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Evaluation of Solvent Accessibility to the [Fe4S4] Binding Pocket in Native and Tyr19 Mutant High Potential Iron Proteins by 1H-15N HMQC and 19F NMR Experiments Dawei Li, Anshu Agarwal, and J. A. Cowan pp 1121 - 1125; DOI: 10.1021/ic951160s |
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Oxidation of Cyclohexane by Molecular Oxygen Photoassisted by meso-Tetraarylporphyrin Iron(III)-Hydroxo Complexes A. Maldotti, C. Bartocci, G. Varani, A. Molinari, P. Battioni, and D. Mansuy pp 1126 - 1131; DOI: 10.1021/ic950386s |
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[Ni2(ppepO)(C6H5COO)2(CH3COOH)]ClO4·C4H10O: Synthesis and Characterization of an Asymmetric Dinuclear Nickel(II) Complex Showing Unusual Coordination Behavior with Relevance to the Active Site of Urease Dirk Volkmer, Andreas Hörstmann, Klaus Griesar, Wolfgang Haase, and Bernt Krebs pp 1132 - 1135; DOI: 10.1021/ic950368a |
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Disproportionation of Iron(III) Porphyrin -Cation Radicals in the Presence of Sterically Hindered Pyridines. Spectroscopic Detection of Asymmetric Highly Oxidized Intermediates Krystyna Rachlewicz and Lechos aw Latos-Grayskipp 1136 - 1147; DOI: 10.1021/ic950876k |
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Anisotropic Exchange Effects in Temperature and Pressure Dependences of EPR Zero-Field Splitting in [(C6H5)3(n-propyl)P]2Cu2Cl6 D. Gatteschi, J. Goslar, W. Hilczer, S. K. Hoffmann, and C. Zanchini pp 1148 - 1153; DOI: 10.1021/ic950811h |
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Synthesis and Characterization of Hydrotalcite-like Compounds Containing V3+ in the Layers and of Their Calcination Products F. M. Labajos, V. Rives, P. Malet, M. A. Centeno, and M. A. Ulibarri pp 1154 - 1160; DOI: 10.1021/ic950835o |
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AVSeO5 (A = Rb, Cs) and AV3Se2O12 (A = K, Rb, Cs, NH4): Hydrothermal Synthesis in the V2O5-SeO2-AOH System and Crystal Structure of CsVSeO5 Young-Uk Kwon, Kyu-Seok Lee, and Yoon Hyun Kim pp 1161 - 1167; DOI: 10.1021/ic9509488 |
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Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts Pierre Bonhôte, Ana-Paula Dias, Nicholas Papageorgiou, Kuppuswamy Kalyanasundaram, and Michael Grätzel pp 1168 - 1178; DOI: 10.1021/ic951325x |
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Electronic Structure of Layered Oxides Containing M2O7 (M = V, Nb) Double Octahedral Slabs Roger Rousseau, Maria Rosa Palacín, Pedro Gómez-Romero, and Enric Canadell pp 1179 - 1184; DOI: 10.1021/ic951048u |
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A Proposal for Positive Cooperativity in Anion-Cation Binding in Yttrium and Lutetium Complexes Based on o-Amino-Substituted Phenolate Ligands. On the Way to Coordination Polymers by Self-Assembly. Molecular Structures of [ClLu(OAr)3Na] (X-ray) and [ClY(OAr')3Y(OAr')3Na] (X-ray and 89Y-NMR) Marinus P. Hogerheide, Stéphanie N. Ringelberg, David M. Grove, Johann T. B. H. Jastrzebski, Jaap Boersma, Wilberth J. J. Smeets, Anthony L. Spek, and Gerard van Koten pp 1185 - 1194; DOI: 10.1021/ic950639h |
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Influence of Intramolecular Coordination on the Aggregation of Sodium Phenolate Complexes. X-ray Structures of [NaOC6H4(CH2NMe2)-2]6 and [Na(OC6H2(CH2NMe2)2-2,6-Me-4)(HOC6H2(CH2NMe2)2-2,6-Me-4)]2 Marinus P. Hogerheide, Stéphanie N. Ringelberg, Maurits D. Janssen, Jaap Boersma, Anthony L. Spek, and Gerard van Koten pp 1195 - 1200; DOI: 10.1021/ic950856i |
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Ferrimagnetic Mixed-Valency and Mixed-Metal Tris(oxalato)iron(III) Compounds: Synthesis, Structure, and Magnetism Corine Mathonière, Christopher J. Nuttall, Simon G. Carling, and Peter Day pp 1201 - 1206; DOI: 10.1021/ic950703v |
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Polyoxometalate Derivatives with Multiple Organic Groups. 2. Synthesis and Structures of Tris(organotin) , -Keggin Tungstosilicates Feibo Xin, Michael T. Pope, Gary J. Long, and Umberto Russo pp 1207 - 1213; DOI: 10.1021/ic951341u |
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Disordered CuN6 Jahn-Teller Centers in Hexakis(1-methyltetrazole)copper(II) Tetrafluoroborate: A Temperature-Dependent X-ray Diffraction and EPR Study Paul E. M. Wijnands, John S. Wood, Jan Reedijk, and Wim J. A. Maaskant pp 1214 - 1222; DOI: 10.1021/ic950315t |
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Synthetic, Structural, Spectroscopic, and Theoretical Studies of Structural Isomers of the Cluster Pt3(-PPh2)3Ph(PPh3)2. A Unique Example of Core Isomerism in Phosphine Phosphido-Rich Clusters Robert Bender, Pierre Braunstein, Alain Dedieu, Paul D. Ellis, Beth Huggins, Pierre D. Harvey, Enrico Sappa, and Antonio Tiripicchio pp 1223 - 1234; DOI: 10.1021/ic951164x |
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Hydrocarbon-Soluble Mercuracarborands: Syntheses, Halide Complexes, and Supramolecular Chemistry Zhiping Zheng, Carolyn B. Knobler, Mark D. Mortimer, Gapgoung Kong, and M. Frederick Hawthorne pp 1235 - 1243; DOI: 10.1021/ic951069o |
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First Resolution of a Free Fluorophosphine Chiral at Phosphorus. Resolution and Reactions of Free and Coordinated (±)-Fluorophenylisopropylphosphine Michael Pabel, Anthony C. Willis, and S. Bruce Wild pp 1244 - 1249; DOI: 10.1021/ic950897e |
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Oxidative Addition of Group 14 Element Hydrido Compounds to OsH2(2-CH2=CHEt)(CO)(PiPr3)2: Synthesis and Characterization of the First Trihydrido-Silyl, Trihydrido-Germyl, and Trihydrido-Stannyl Derivatives of Osmium(IV) María L. Buil, Pablo Espinet, Miguel A. Esteruelas, Fernando J. Lahoz, Agustí Lledós, Jesús M. Martínez-Ilarduya, Feliu Maseras, Javier Modrego, Enrique Oñate, Luis A. Oro, Eduardo Sola, and Cristina Valero pp 1250 - 1256; DOI: 10.1021/ic9509591 |
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Bonding Properties of the 1,2-Semiquinone Radical-Anionic Ligand in the [M(CO)4-n(L)n(DBSQ)] Complexes (M = Re, Mn; DBSQ = 3,5-di-tert-butyl-1,2-benzosemiquinone; n = 0, 1, 2). A Comprehensive Spectroscopic (UV-Vis and IR Absorption, Resonance Raman, EPR) and Electrochemical Study Franti  ek Hartl and Antonín Vl ek, Jr.pp 1257 - 1265; DOI: 10.1021/ic950018o |
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Transition-Metal Derivatives of the Cyclopentadienylphosphine Ligands. 11. Reactivity of the Dinuclear Bridged Rhodium(II) Complexes toward Nitrogen-Containing Ligands Alexei Iretskii, Michael C. Jennings, and René Poilblanc pp 1266 - 1272; DOI: 10.1021/ic9502335 |
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Theoretical Studies on Models for the Oxo-Transfer Reaction of Dioxomolybdenum Enzymes Michelle A. Pietsch and and Michael B. Hall pp 1273 - 1278; DOI: 10.1021/ic951044p |
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Synthesis, Molecular Structure, and Vibrational Spectra of mer-Tris(carbonyl)iridium(III) Fluorosulfate, mer-Ir(CO)3(SO3F)3 Changqing Wang, Andrew R. Lewis, Raymond J. Batchelor, Frederick W. B. Einstein, Helge Willner, and Friedhelm Aubke pp 1279 - 1285; DOI: 10.1021/ic9506769 |
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Synthesis and Characterization of a Bis(--diketonato)bis((1,2,5,6-)-1,5-dimethyl-1,5- cyclooctadiene)disilver Complex. An Intermediate in the Synthesis of an Isomerically Pure (-Diketonato)((1,2,5,6-)-1,5-dimethyl-1,5-cyclooctadiene)copper(I) Complex Pascal Doppelt and, Thomas H. Baum, and Louis Ricard pp 1286 - 1291; DOI: 10.1021/ic9410102 |
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Nature of the Rh-H2 Bond in a Dihydrogen Complex Stabilized Only by Nitrogen Donors. Inelastic Neutron Scattering Study of TpMe2RhH2(2-H2) (TpMe2 = Hydrotris(3,5-dimethylpyrazolyl)borate) Juergen Eckert, Alberto Albinati, Urs E. Bucher, and Luigi M. Venanzi pp 1292 - 1294; DOI: 10.1021/ic950452q |
* Molecular Orbital Crossing a2( )/b1( ) in 1,10-Phenanthroline Derivatives. Ab Initio Calculations and EPR/ENDOR Studies of the 4,7-Diaza-1,10-phenanthroline Radical Anion and Its M(CO)4 Complexes (M = Cr, Mo, W)Sylvia Ernst, Conny Vogler, Axel Klein, Wolfgang Kaim, and Stanislav Zali pp 1295 - 1300; DOI: 10.1021/ic950892h |
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Vapor Phase Vibrational Spectra for Re2O7 and the Infrared Spectrum of Gaseous HReO4. Molecular Shapes of Mn2O7, Tc2O7, and Re2O7 I. R. Beattie, T. R. Gilson, and P. J. Jones pp 1301 - 1304; DOI: 10.1021/ic950675g |
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A Density Functional Study of the Structure and Stability of CrF4, CrF5, and CrF6 L. G. Vanquickenborne, A. E. Vinckier, and K. Pierloot pp 1305 - 1309; DOI: 10.1021/ic941381i |
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Raman Study of Aluminum Chloride-Dimethylsulfone Solutions L. Legrand, A. Tranchant, R. Messina, F. Romain, and A. Lautie pp 1310 - 1312; DOI: 10.1021/ic941455q |
Identification of the 1,3,2,4-Dithiadiazolyl RCNSNS Radical Dimers in Solution, Their Dimeric Concerted Photochemically Symmetry-Allowed Rearrangement to 1,2,3,5-Dithiadiazolyl RCNSSN by the Net Exchange of Adjacent Cyclic Sulfur and Nitrogen Atoms, and the Photolysis of RCNSNSJack Passmore and Xiaoping Sun pp 1313 - 1320; DOI: 10.1021/ic9509140 |
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Effects of Cyclopentadienyl and Phosphine Ligands on the Basicities and Nucleophilicities of Cp'Ir(CO)(PR3) Complexes Dongmei Wang and Robert J. Angelici pp 1321 - 1331; DOI: 10.1021/ic951079p |
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Reactivity of the Coordinated Hydroperoxo Ligand Shaukat A. Mirza, Bernard Bocquet, Chantal Robyr, Silvia Thomi, and Alan F. Williams pp 1332 - 1337; DOI: 10.1021/ic950950z |
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Nitrogen-14 NMR Study on Solvent Exchange of the Octahedral Cobalt(II) Ion in Neat 1,3-Propanediamine and n-Propylamine at Various Temperatures and Pressures. Tetrahedral-Octahedral Equilibrium of the Solvated Cobalt(II) Ion in n-Propylamine As Studied by EXAFS and Electronic Absorption Spectroscopy Sen-ichi Aizawa, Shigeo Iida, Kayoko Matsuda, and Shigenobu Funahashi pp 1338 - 1342; DOI: 10.1021/ic950855q |
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Synthesis, Characterization, and Electrochemistry of Ruthenium Porphyrins Containing a Nitrosyl Axial Ligand Karl M. Kadish, Victor A. Adamian, Eric Van Caemelbecke, Zheng Tan, Pietro Tagliatesta, Paola Bianco, Tristano Boschi, Geun-Bae Yi, Masood A. Khan, and George B. Richter-Addo pp 1343 - 1348; DOI: 10.1021/ic950799t |
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Secondary Amine Stabilized Aluminum Hydrides Derived from N,N'-Di-tert-butylethylenediamines Michael G. Gardiner, Stacey M. Lawrence, and Colin L. Raston pp 1349 - 1354; DOI: 10.1021/ic950978a |
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Hydroxoundecahydro-closo-dodecaborate(2-) as a Nucleophile. Preparation and Structural Characterization of O-Alkyl and O-Acyl Derivatives of Hydroxoundecahydro-closo-dodecaborate(2-) Toralf Peymann, Enno Lork, and Detlef Gabel pp 1355 - 1360; DOI: 10.1021/ic951111f |
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Gold(I) Complexes with the nido-Diphosphino Ligand [7,8-(Ph2P)2-7,8-C2B9H10]-. Preparation of the First Metallocarborane Complex of this Ligand. Crystal Structures of [Au{(PPh2)2C2B9H10}(PPh3)]·CH2Cl2 and [Au2{(PPh2)2C2B9H10}2{(PPh2)2(CH2)3}]·3Me2CO Olga Crespo, M. Concepción Gimeno, Peter G. Jones, and Antonio Laguna pp 1361 - 1366; DOI: 10.1021/ic951204x |
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Composition Space of the (CuO, 1/2Nb2O5)/(HF)x·pyridine/H2O System. Structure and Synthesis of [pyH+]2[CuNb2(py)4O2F10]2- and CuNb(py)4OF5 Paramasivan Halasyamani, Michael J. Willis, Charlotte L. Stern, Paul M. Lundquist, George K. Wong, and Kenneth R. Poeppelmeier pp 1367 - 1371; DOI: 10.1021/ic951189w |
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A Six-Coordinate Tris(3,5-dimethyl-1-pyrazolyl)methane-Thallium(I) Complex with a Stereochemically Inactive Lone Pair: Syntheses and Solid State Structures of {[HC(3,5-Me2pz)3]2Tl}PF6 and {[HC(3,5-Me2pz)3]Tl}PF6 (pz = Pyrazolyl) Daniel L. Reger, James E. Collins, Ralph Layland, and Richard D. Adams pp 1372 - 1376; DOI: 10.1021/ic951167+ |
Synthesis and NMR Investigation of Dirhodium(II) Formamidinate Complexes Containing Bidentate Phosphorus Donors. X-ray Crystal Structure of the Ortho-Metalated Complex Rh2(form)(-O2CCF3)[(C6H4)(C6H5)P(CH2)2P(C6H5)2]( -O2CCF3)(p-toluidine)Giuseppe Tresoldi, Giovanni De Munno, Francesco Nicolò, Sandra Lo Schiavo, and Pasquale Piraino pp 1377 - 1381; DOI: 10.1021/ic9502032 |
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Evidence of Protonated and Deprotonated Forms of Symmetrical and Asymmetrical Lutetium(III) Porphyrin Double-Deckers by 1H-NMR Spectroscopy G. A. Spyroulias and A. G. Coutsolelos pp 1382 - 1385; DOI: 10.1021/ic950796g |
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Synthesis and Molecular Structure of a Novel Monocarbon Hydridorhodacarborane: closo-2,7-(PPh3)2-2-H-2-Cl-1-(NMe3)-2,1-RhCB10H9 Igor T. Chizhevsky, Irina V. Pisareva, Pavel V. Petrovskii, Vladimir I. Bregadze, Fedor M. Dolgushin, Alexandr I. Yanovsky, Yuri T. Struchkov, and M. Frederick Hawthorne pp 1386 - 1388; DOI: 10.1021/ic9509950 |
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Et4N[Mo2O2S2(-O2CCF3)(S2P(OEt)2)2], the First Six-Coordinate [Mo2O2(-S)2L2] Complex (L = Bidentate Sulfido Ligands) Li Xu, Jinshun Huang, Duancao Yan, and Qianer Zhang pp 1389 - 1392; DOI: 10.1021/ic950890x |
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Nitrite Reductase Activity of Deoxy Carcinus maenas Hemocyanin: Formation of the Half-Met Derivative Luigi Bubacco, Richard S. Magliozzo, Mariano Beltramini, Jack Peisach, and Benedetto Salvato pp 1393 - 1394; DOI: 10.1021/ic951008q |
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Synthesis, Molecular Structure, and Electrochemistry of a Paramagnetic Diruthenium(III) Complex. Characterization of Ru2(hpp)4Cl2, Where hpp Is the 1,3,4,6,7,8- Hexahydro-2H-pyrimido[1,2-a]pyrimidinate Ion John L. Bear, Yulan Li, Baocheng Han, and Karl M. Kadish pp 1395 - 1398; DOI: 10.1021/ic950956o |
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Isolation and Structural Characterization of [P(AuPPh3)5][BF4]2 via Cleavage of a P-P Bond by Cationic Gold Fragments: Direct Evidence of the Structure of the Elusive Tetrakis[phosphineaurio(I)]phosphonium(+) Cation Robert E. Bachman and Hubert Schmidbaur pp 1399 - 1401; DOI: 10.1021/ic950946n |
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Electron Self-Exchange Kinetics for a Water-Soluble Ferrocenium/Ferrocene Couple: Rate Modulation via Charge Dependent Calix[6]arene-p-sulfonate Encapsulation Roger M. Nielson and Joseph T. Hupp pp 1402 - 1404; DOI: 10.1021/ic951191n |
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Reduction of the Unique Carbonyl in (-H)2Os3(CO)9(3-CCO) by BH3·THF. Molecular Structure of (-H)3Os3(CO)9(3-CCH3) Jeanette A. Krause Bauer, Jang-Hoon Chung, Edwin P. Boyd, Jianping Liu, Debra S. Strickland, Heinz-Josef Kneuper, John R. Shapley, and Sheldon G. Shore pp 1405 - 1407; DOI: 10.1021/ic951118x |
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Convenient Synthesis of Bis(alkoxy)rhenium(VII) Complexes Zuolin Zhu, Ahmad M. Al-Ajlouni, and James H. Espenson pp 1408 - 1409; DOI: 10.1021/ic951181m |
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Synthesis, Structure, and Properties of {N,N'- Bis[2-(2-pyridyl)ethyl]pyridine-2,6-dicarboxamido}copper(II) Ferman A. Chavez, Marilyn M. Olmstead, and Pradip K. Mascharak pp 1410 - 1412; DOI: 10.1021/ic9512136 |
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Triammineplatinum(II) Coordinated to a Guanine Does Not Prevent Platination of an Adjacent Guanine in Single-Stranded Oligonucleotides Franziska Reeder, Ji  í Kozelka, and J. C. Chottardpp 1413 - 1415; DOI: 10.1021/ic951135m |
Proton-Coupled Electron-Transfer Reactions in [MnIV2( -O)3L,2]2+ (L, = 1,4,7-Trimethyl-1,4,7-triazacyclononane)Ronald Hage, Bert Krijnen, Johann B. Warnaar, Frantisek Hartl, Derk J. Stufkens, and Theo L. Snoeck pp 1416 - 1416; DOI: 10.1021/ic951442s |
Issue 6
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Synthesis of (E)- and (Z)-1-H-Difluoromethanimine Charles W. Bauknight, Jr. and Darryl D. DesMarteau pp 1417 - 1418; DOI: 10.1021/ic951149s |
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Catalytic Disproportionation of Hydrogen Peroxide by the Tetranuclear Manganese Complex [Mnll(2-OHpicpn)]4 Andrew Gelasco, Anke Askenas, and Vincent L. Pecoraro pp 1419 - 1420; DOI: 10.1021/ic951035g |
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Coordination Chemistry and Photoreactivity of the Dinitramide Ion Scott Trammell, Patricia A. Goodson, and B. Patrick Sullivan pp 1421 - 1422; DOI: 10.1021/ic951332l |
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Synthesis and Structure of Novel Bridged Dinuclear Indium Complexes Yuanlin Zhou and Darrin S. Richeson pp 1423 - 1424; DOI: 10.1021/ic951241o |
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New Dicarbollide Complexes of Uranium Daniel Rabinovich, Chereé M. Haswell, Brian L. Scott, Rebecca L. Miller, Jon B. Nielsen, and Kent D. Abney pp 1425 - 1426; DOI: 10.1021/ic951444c |
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Löwenstein's Rule Extended to an Aluminum Rich Framework. The Structure of Bicchulite, Ca8(Al2SiO6)4(OH)8, by MASNMR and Neutron Diffraction Sandra E. Dann, Philip J. Mead, and Mark T. Weller pp 1427 - 1428; DOI: 10.1021/ic9513503 |
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Synthesis and Structure of a Magnesium Hydroxide Complex Supported by Tris(pyrazolyl)hydroborato Ligation, {[TpAr,Me]Mg(-OH)}2 (Ar = p-ButC6H4) Prasenjit Ghosh and Gerard Parkin pp 1429 - 1430; DOI: 10.1021/ic9515970 |
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Electronic Structure of [Ta5(NH)4Cl17]6-: A Cluster with a Distorted Square Pyramidal Ta5 Core Kimberly A. Lawler and and Roald Hoffmann pp 1431 - 1436; DOI: 10.1021/ic950730l |
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The First Mixed-Halide Zirconium Cluster Compounds: Zr6Cl1.6I10.4Be, Zr6Cl1.3I10.7B, and Zr6Cl11.5I1.5B. Matrix Effects and Halogen Substitution in Compact Network Structures Martin Köckerling, Ru-Yi Qi, and John D. Corbett pp 1437 - 1443; DOI: 10.1021/ic950889y |
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A15Tl27 (A = Rb, Cs): A Structural Type Containing Both Isolated Clusters and Condensed Layers Based on the Tl11 Fragment. Syntheses, Structure, Properties, and Band Structure Zhen-Chao Dong and John D. Corbett pp 1444 - 1450; DOI: 10.1021/ic951086d |
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Chiral, Three-Dimensional Supramolecular Compounds: Homo- and Bimetallic Oxalate- and 1,2-Dithiooxalate-Bridged Networks. A Structural and Photophysical Study Silvio Decurtins, Helmut W. Schmalle, René Pellaux, Philippe Schneuwly, and Andreas Hauser pp 1451 - 1460; DOI: 10.1021/ic950791j |
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Syntheses and Properties of New Layered Alkali-Metal/Ammonium Vanadium(V) Methylphosphonates: M(VO2)3(PO3CH3)2 (M = NH4, K, Rb, Tl). Single-Crystal Structures of K(VO2)3(PO3CH3)2 and NH4(VO2)3(PO3CH3)2 William T. A. Harrison, Laurie L. Dussack, and Allan J. Jacobson pp 1461 - 1467; DOI: 10.1021/ic951170t |
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Structure Determination of a Complex Tubular Uranyl Phenylphosphonate, (UO2)3(HO3PC6H5)2(O3PC6H5)2·H2O, from Conventional X-ray Powder Diffraction Data Damodara M. Poojary, Aurelio Cabeza, Miguel A. G. Aranda, Sebastian Bruque, and Abraham Clearfield pp 1468 - 1473; DOI: 10.1021/ic951209u |
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Synthesis and Characterization of a New Quasi-One-Dimensional Copper(II) Phosphate, Ba2Cu(PO4)2 Kristen M. S. Etheredge and Shiou-Jyh Hwu pp 1474 - 1477; DOI: 10.1021/ic9511783 |
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Synthesis and Ligand Substitution Reactions of a Mesitylphosphido-Bridged Platinum(II) Dimer Igor V. Kourkine, Michael B. Chapman, David S. Glueck, Klaus Eichele, Roderick E. Wasylishen, Glenn P. A. Yap, Louise M. Liable-Sands, and Arnold L. Rheingold pp 1478 - 1485; DOI: 10.1021/ic951020i |
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Thermal Coupling Reactions of 1-Phenyl-3,4-dimethylphosphole within the Coordination Sphere of Palladium(II) William L. Wilson, Jean Fischer, Roderick E. Wasylishen, Klaus Eichele, Vincent J. Catalano, John H. Frederick, and John H. Nelson pp 1486 - 1496; DOI: 10.1021/ic951307f |
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Preparation and Tungsten-183 NMR Characterization of [-1-P2W17O61]10-, [-1-Zn(H2O)P2W17O61]8-, and [-2-Zn(H2O)P2W17O61]8- Judit Bartis, Yuliya Kunina, Michael Blumenstein, and Lynn C. Francesconi pp 1497 - 1501; DOI: 10.1021/ic950492u |
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Synthesis and Crystal Structure of Organocobalt(III) Complexes with Secondary Alkyls or Bulky Schiff Base Equatorial Ligands Chen Huilan, Han Deyan, Li Tian, Yan Hong, Tang Wenxia, Jian Chen, Peiju Zheng, and Chenggang Chen pp 1502 - 1508; DOI: 10.1021/ic940516h |
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Synthesis, Characterization, and Single-Crystal EPR Studies of Three Dinuclear Copper(II) Complexes and One Mixed-Valence Tetranuclear Copper(I)-Copper(II) Cluster with an Asymmetric Imidazole-Containing Tripodal Ligand with Copper(II)-Copper(II) Distances between 3.35 and 3.63 Å G. J. Anthony A. Koolhaas, Willem L. Driessen, Jan Reedijk, Jacob L. van der Plas, Rudolf A. G. de Graaff, Dante Gatteschi, Huub Kooijman, and Anthony L. Spek pp 1509 - 1517; DOI: 10.1021/ic951128y |
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Monodentate -N and Bidentate -N,-N' Coordination of 1,1-Bis((N-p-tolylimino)diphenylphosphoranyl)ethane, CHCH3(PPh2=NC6H4-4-CH3)2, to Platinum(II) Mandy W. Avis, Cornelis J. Elsevier, Nora Veldman, Huub Kooijman, and Anthony L. Spek pp 1518 - 1528; DOI: 10.1021/ic950748w |
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Coordinatively Unsaturated Derivatives of Group 6 Metal Carbonyls Containing the -Donating Ligand 3,5-Di-tert-butylcatecholate Donald J. Darensbourg, Kevin K. Klausmeyer, and Joseph H. Reibenspies pp 1529 - 1534; DOI: 10.1021/ic950968+ |
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Coordinatively and Electronically Unsaturated Tungsten(0) Carbonyl Complexes Stabilized by -Donating Amido Ligands Donald J. Darensbourg, Kevin K. Klausmeyer, and Joseph H. Reibenspies pp 1535 - 1539; DOI: 10.1021/ic950985z |
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Synthesis, Structure, and Reactivities of [2-P7M(CO)4]3-, [2-HP7M(CO)4]2-, and [2-RP7M(CO)4]2- Zintl Ion Complexes Where M = Mo, W Scott Charles, James C. Fettinger, and Bryan W. Eichhorn pp 1540 - 1548; DOI: 10.1021/ic9511534 |
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Competition between NH···HIr Intramolecular Proton-Hydride Interactions and NH···FBF3- or NH···O Intermolecular Hydrogen Bonds Involving [IrH(2-thiazolidinethione)4(PCy3)](BF4)2 and Related Complexes Wei Xu, Alan J. Lough, and Robert H. Morris pp 1549 - 1555; DOI: 10.1021/ic950997k |
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Protonation Equilibria of Mononuclear Vanadate: Thermodynamic Evidence for the Expansion of the Coordination Number in VO2+ Johannes J. Cruywagen, J. Bernard B. Heyns, and Arjan N. Westra pp 1556 - 1559; DOI: 10.1021/ic950832b |
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Electron-Transfer Processes in Indium(II) Iodide-o-Quinone Systems Martyn A. Brown, Bruce R. McGarvey, Andrzej Ozarowski, and Dennis G. Tuck pp 1560 - 1563; DOI: 10.1021/ic9508132 |
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Comparative Kinetic Analysis of Reversible Intermolecular Electron-Transfer Reactions between a Series of Pentaammineruthenium Complexes and Cytochrome c Martin Meier, Ji Sun, James F. Wishart, and Rudi van Eldik pp 1564 - 1570; DOI: 10.1021/ic9413528 |
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Kinetics of Dissociation of Iron(III) Complexes of Tiron in Aqueous Acid Zhongsheng Zhang and R. B. Jordan pp 1571 - 1576; DOI: 10.1021/ic941303v |
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Kinetics of Formation and Dissociation of [Cr3O(O2CCH3)6(urea)3]+: An Example of Statistically Controlled Kinetics and Equilibrium John P. Bourke, Elisha Karu, and Roderick D. Cannon pp 1577 - 1581; DOI: 10.1021/ic9505561 |
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Template Synthesis of a Tetraaza Macrocycle Which Involves Benzaldehyde Rather Than Formaldehyde as a Building Block. Isolation and Structure Determination of the Open-Chain Schiff Base Intermediate Complex Luigi Fabbrizzi, Maurizio Licchelli, Anna Maria Manotti Lanfredi, Omar Vassalli, and Franco Ugozzoli pp 1582 - 1589; DOI: 10.1021/ic950841k |
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Synthesis of Cyclic Ethers with Fluorinated Side Chains Jianguo Chen, Yuan-Fa Zhang, Xiaoming Zheng, Ashwani Vij, Duane Wingate, Douglas Meng, Kama White, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 1590 - 1601; DOI: 10.1021/ic9509645 |
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Photochemistry of Dihydrido(hydrotris(3,5-dimethylpyrazolyl)borato)(Z-cyclooctene)iridium. Synthetic Intermediates and Mechanism of the Photochemical Formation of Hydridophenyl(hydrotris(3,5-dimethylpyrazolyl)borato)(trimethyl phosphite)iridium Arlen Ferrari, Eleonora Polo, Heinz Rüegger, Silvana Sostero, and Luigi M. Venanzi pp 1602 - 1608; DOI: 10.1021/ic951025f |
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Ab Initio CI Determination of the Exchange Coupling Constant of Doubly-Bridged Nickel(II) Dimers O. Castell, R. Caballol, V. M. García, and K. Handrick pp 1609 - 1615; DOI: 10.1021/ic9507631 |
Absorption, Circular Dichroism, and Luminescence Spectroscopy of Electrogenerated  -[Ru(bipy)3]+/0/- and -[Os(bipy)3]+/0/- (bipy = 2,2'-Bipyridine)Brian Noble and Robert D. Peacock pp 1616 - 1620; DOI: 10.1021/ic951096e |
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Bis(1,2-bis(diphenylphosphino)ethane)tungsten(0) Complexes Containing Electron-Saturated Metal Centers and Singly-Coordinated Bridging Ligands Cuie Hu, William C. Hodgeman, and Dennis W. Bennett pp 1621 - 1626; DOI: 10.1021/ic9508280 |
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Possible Role of the Iron Coordination Sphere in Hemoprotein Electron Transfer Self-Exchange: 1H NMR Study of the Cytochrome c-PMe3 Complex Nathalie Legrand, Arnaud Bondon, and Gérard Simonneaux pp 1627 - 1631; DOI: 10.1021/ic950572y |
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Influence of Meso Substituents on Electronic States of (Oxoferryl)porphyrin -Cation Radicals K. Jayaraj, J. Terner, A. Gold, D. A. Roberts, R. N. Austin, D. Mandon, R. Weiss, E. Bill, M. Müther, and A. X. Trautwein pp 1632 - 1640; DOI: 10.1021/ic951058v |
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Unique Fluxional Behavior. Synthesis, Structure, and Properties of Novel (Diamine)platinum(II) Complexes of 9-Fluorenylidene- and Benzhydrylidenemalonate Ligands Young-A Lee, Ok-Sang Jung, Seong-Joo Kang, Kang-Bong Lee, and Youn Soo Sohn pp 1641 - 1646; DOI: 10.1021/ic951011+ |
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Model of the Second Most Abundant Cisplatin-DNA Cross-Link: X-ray Crystal Structure and Conformational Analysis of cis-[(NH3)2Pt(9-MeA-N7)(9-EtGH-N7)](NO3)·2H2O (9-MeA = 9-Methyladenine; 9-EtGH = 9-Ethylguanine) Guy Schröder, Jirí Kozelka, Michal Sabat, Marie-Hélène Fouchet, Rut Beyerle-Pfnür, and Bernhard Lippert pp 1647 - 1652; DOI: 10.1021/ic950754s |
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Kinetic Analysis of the Reactions between GG-Containing Oligonucleotides and Platinum Complexes. 1. Reactions of Single-Stranded Oligonucleotides with cis-[Pt(NH3)2(H2O)2]2+ and [Pt(NH3)3(H2O)]2+ Florence Gonnet, Franziska Reeder, Ji í Kozelka, and Jean-Claude Chottardpp 1653 - 1658; DOI: 10.1021/ic951136e |
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Chemical and Biological Studies of Dichloro(2-((dimethylamino)methyl)phenyl)gold(III) Richard V. Parish, Brian P. Howe, Jonathan P. Wright, Jürgen Mack, Robin G. Pritchard, Robert G. Buckley, Amanda M. Elsome, and Simon P. Fricker pp 1659 - 1666; DOI: 10.1021/ic950343b |
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Oxidation Kinetics of the Potent Insulin Mimetic Agent Bis(maltolato)oxovanadium(IV) (BMOV) in Water and in Methanol Yan Sun, Brian R. James, Steven J. Rettig, and Chris Orvig pp 1667 - 1673; DOI: 10.1021/ic951452t |
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Oxygen Abstraction Reactions of N-Substituted Hydroxamic Acids with Molybdenum(V) and Vanadium(III) and -(IV) Compounds David A. Brown, H. Bögge, R. Coogan, D. Doocey, T. J. Kemp, A. Müller, and B. Neumann pp 1674 - 1679; DOI: 10.1021/ic950819r |
A Product Formed from Glycylglycine in the Presence of Vanadate and Hydrogen Peroxide: The (Glycylde-N-hydroglycinato- 3N2,NN,O1)oxoperoxovanadate(V) AnionFrederick W. B. Einstein, Raymond J. Batchelor, Sarah J. Angus-Dunne, and Alan S. Tracey pp 1680 - 1684; DOI: 10.1021/ic951007y |
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Synthesis and Characterization of Oxotechnetium(V) Mixed-Ligand Complexes Containing a Tridentate N-Substituted Bis(2-mercaptoethyl)amine and a Monodentate Thiol I. C. Pirmettis, M. S. Papadopoulos, S. G. Mastrostamatis, C. P. Raptopoulou, A. Terzis, and E. Chiotellis pp 1685 - 1691; DOI: 10.1021/ic950971t |
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New Type 2 Copper-Cysteinate Proteins. Copper Site Histidine-to-Cysteine Mutants of Yeast Copper-Zinc Superoxide Dismutase Yi Lu, James A. Roe, Christopher J. Bender, Jack Peisach, Lucia Banci, Ivano Bertini, Edith B. Gralla, and Joan Selverstone Valentine pp 1692 - 1700; DOI: 10.1021/ic9513189 |
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1-Phenyl-1,2-dicarba-closo-dodecaborane, 1-Ph-1,2-closo-C2B10H11. Synthesis, Characterization, and Structure As Determined in the Gas Phase by Electron Diffraction, in the Crystalline Phase at 199 K by X-ray Diffraction, and by ab Initio Computations Paul T. Brain, Jill Cowie, David J. Donohoe, Drahomír Hnyk, David W. H. Rankin, David Reed, Bruce D. Reid, Heather E. Robertson, Alan J. Welch, Matthias Hofmann, and Paul von Ragué Schleyer pp 1701 - 1708; DOI: 10.1021/ic9511128 |
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Carboxylation of Dihydroxoplatinum(IV) Complexes via a New Synthetic Pathway M. Galanski and B. K. Keppler pp 1709 - 1711; DOI: 10.1021/ic9509490 |
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A Dinuclear Ruthenium(II) Complex with the Dianion of 2,5-Dihydroxy-1,4-benzoquinone as Bridging Ligand. Redox, Spectroscopic, and Mixed-Valence Properties Michael D. Ward pp 1712 - 1714; DOI: 10.1021/ic950877c |
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Synthesis and Crystal Structure of a trans-Diaquabis(amidato) Complex of Platinum(II) Francesco P. Intini, Maurizio Lanfranchi, Giovanni Natile, Concetta Pacifico, and Antonio Tiripicchio pp 1715 - 1717; DOI: 10.1021/ic951014m |
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Synthesis and Properties of Fluorinated Ethers with Fluorobenzene Rings Jianguo Chen, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 1718 - 1720; DOI: 10.1021/ic950962k |
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Generation of 19-Electron Adducts in Aqueous Solution Using the Water-Soluble (HOCH2)2PCH2CH2P(CH2OH)2 Ligand Gregory F. Nieckarz, T. J. R. Weakley, Warren K. Miller, Brian E. Miller, David K. Lyon, and David R. Tyler pp 1721 - 1724; DOI: 10.1021/ic951071f |
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Joint Molecular Mechanics and Atom-Atom Pair Potential Computations on the Solid State Dynamics of [Fe3(CO)12] Angelo Sironi pp 1725 - 1728; DOI: 10.1021/ic9500063 |
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(Phosphinoalkyl)silanes. 3.1 Poly(o-(diphenylphosphino)benzyl)silanes: Synthesis, Spectroscopic Properties, and Complexation at Platinum or Iridium Robert A. Gossage, Geoff D. McLennan, and Stephen R. Stobart pp 1729 - 1732; DOI: 10.1021/ic941230f |
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A Zinc(II)-Driven Intramolecular Photoinduced Electron Transfer Luigi Fabbrizzi, Maurizio Licchelli, Piersandro Pallavicini, and Angelo Taglietti pp 1733 - 1736; DOI: 10.1021/ic950504b |
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Spectroscopic and Electrochemical Properties of a Series of Mixed-Metal d6,d8 Bimetallic Complexes of the Form [(bpy)2M(BL)PtCl2]2+ (bpy = 2,2'-Bipyridine; BL = dpq (2,3-Bis(2- pyridyl)quinoxaline) or dpb (2,3-Bis(2-pyridyl)- benzoquinoxaline); M = OsII or RuII) Matthew Milkevitch, Eric Brauns, and Karen J. Brewer pp 1737 - 1739; DOI: 10.1021/ic950693y |
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The Poly(heptatellurium) Dication: A New Twist Greg W. Drake, George L. Schimek, and Joseph W. Kolis pp 1740 - 1742; DOI: 10.1021/ic951021a |
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Synthesis and Structure of a Mo3S4 Cluster Complex with Seven Cluster Electrons Roger E. Cramer, Kazuhiro Yamada, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 1743 - 1746; DOI: 10.1021/ic951103z |
Issue 7
Cyanide-Bridged Lanthanide-Transition Metal One-Dimensional Arrays {(DMF)10Yb2[Ni(CN)4]3} and {(DMF)10Yb2[Pt(CN)4]3}David W. Knoeppel and Sheldon G. Shore pp 1747 - 1748; DOI: 10.1021/ic9600846 |
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An Unsymmetrical, Doubly Bridged Diiron(II) Complex with Readily Accessible Coordination Sites Joe H. Satcher, Jr., Alan L. Balch, Marilyn M. Olmstead, and Michael W. Droege pp 1749 - 1750; DOI: 10.1021/ic951171l |
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Electrocatalytic Reduction of Dioxygen by Diruthenium Cofacial Diporphyrins Axially-Bound to a Gold-Supported, Self-Assembled Monolayer James P. Collman, Matthew S. Ennis, David A. Offord, Leng Leng Chng, and John H. Griffin pp 1751 - 1752; DOI: 10.1021/ic950734q |
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Chemistry in Environmentally Benign Media. 3.1 Synthesis and Characterization of Rhenium(V) Complexes Derived from Novel Water-Soluble (Hydroxymethyl)phosphines. Crystal Structures of [Re(O)2{(HOH2C)2PC6H4P(CH2OH)2}2]I and [Re(O)2{(HOH2C)2PCH2CH2P(CH2OH)2}2]Cl V. Sreenivasa Reddy, Douglas E. Berning, Kattesh V. Katti, Charles L. Barnes, Wynn A. Volkert, and A. R. Ketring pp 1753 - 1757; DOI: 10.1021/ic9510167 |
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Crystal Structures and Packing of the Tricarbonylbis(phosphine)iron(0) Complexes trans-Fe(CO)3L2 (L = PPh2Me, PPh3). Interplay between Arene-Arene Interactions and Phosphine Conformations Rainer Glaser, Paul E. Haney, and Charles L. Barnes pp 1758 - 1764; DOI: 10.1021/ic9509894 |
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Mixed Ruthenium-Rhodium Carbonyl Clusters. Synthesis and Crystal Structure of the [PPh4]+ Salts of the Anions [Ru2Rh2(CO)7(-CO)5]2-, [Ru2Rh2(CO)9(-CO)3(-H)]-, and [Ru2Rh2(CO)7(-CO)5(3-AuPPh3)]- Alessandro Fumagalli, Davide Italia, Maria Carlotta Malatesta, Gianfranco Ciani, Massimo Moret, and Angelo Sironi pp 1765 - 1772; DOI: 10.1021/ic950728u |
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Syntheses, Structures, and Reactivity of a Series of (Pentamethylcyclopentadienyl)molybdenum(V) and -tungsten(V) Imido Complexes Katrin Köhler, Herbert W. Roesky, Axel Herzog, Heinz Gornitzka, Alexander Steiner, and Isabel Usón pp 1773 - 1777; DOI: 10.1021/ic950919x |
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Ionization of TiCl4 and MgCl2 during the Formation of a High-Activity -Olefin Polymerization Catalyst. Crystal Structures of [cis-{C2H4(CO2Et)2}2Cl2Ti][SbCl6]2·CH2Cl2 and [Mg{C2H4(CO2Et)2}3][MgCl4]·2CH2Cl2 Piotr Sobota and and S awomir Szafertpp 1778 - 1781; DOI: 10.1021/ic9504093 |
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Synthesis of Rhodium, Iridium, and Palladium Tetranuclear Complexes Directed by 2,6-Dimercaptopyridine. X-ray Crystal Structure of [Rh4(-PyS2)2(cod)4] (cod = 1,5-Cyclooctadiene) Jesús J. Pérez-Torrente, Miguel A. Casado, Miguel A. Ciriano, Fernando J. Lahoz, and Luis A. Oro pp 1782 - 1791; DOI: 10.1021/ic950849u |
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Rhodium and Palladium Complexes of a 3,5-Lutidine-Based Phosphine Ligand Alexander Weisman, Michael Gozin, Heinz-Bernhard Kraatz, and David Milstein pp 1792 - 1797; DOI: 10.1021/ic951131h |
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Coordination of Tetrakis(pyrazolyl)borate in Rhenium Complexes Containing the [ReV=O]3+ Core António Paulo, Ângela Domingos, and Isabel Santos pp 1798 - 1807; DOI: 10.1021/ic950972l |
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Spectroscopy, Molecular Structure, Electrochemistry, and Reactivity of Vanadium(IV,V) Imido Complexes of 5,7,12,14-Tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine Hans Schumann pp 1808 - 1813; DOI: 10.1021/ic9508381 |
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Immobilization of Carbonylnickel Complexes: A Solid-State NMR Study K. D. Behringer and J. Blümel pp 1814 - 1819; DOI: 10.1021/ic950756c |
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Homoleptic Copper(I) and Silver(I) Complexes with o-Phenylene-Backboned Bis(thioethers), Bis(selenoethers), and Bis(telluroethers): Synthesis, Multinuclear NMR Studies, and Crystal Structures of [Cu{o-C6H4(SeMe)2}2]PF6, [Cu{o-C6H4(TeMe)2}2]PF6, and [Agn{-o-C6H4(SeMe)2}n{o-C6H4(SeMe)2}n][BF4]n·nCH2Cl2 Jane R. Black, Neil R. Champness, William Levason, and Gillian Reid pp 1820 - 1824; DOI: 10.1021/ic951139r |
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Synthesis, Electronic Properties, and Solid-State Structure of {[(tpy)(Me2bpy)Tc]2(-O)}4+/2+ Joseph Barrera and and Jeffrey C. Bryan pp 1825 - 1830; DOI: 10.1021/ic950671b |
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Metal-Metal Multiply-Bonded Complexes of Technetium. 3.1 Preparation and Characterization of Phosphine Complexes of Technetium Possessing a Metal-Metal Bond Order of 3.5 F. Albert Cotton, Steven C. Haefner, and Alfred P. Sattelberger pp 1831 - 1838; DOI: 10.1021/ic9508583 |
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A Novel Tetranuclear Compound: Crystal Structure and Mass Spectra of [Re4(C6H5NCOCH3)6(Cl)(-O)(-OH)(MeOH)3][ReO4]2 F. Albert Cotton, Jian Lu, and Yong Huang pp 1839 - 1841; DOI: 10.1021/ic941092u |
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Variations in Catenation Behavior in Aromatic Guest Clathrates Containing Rigid Host Entities p-Xylylenediamine (p-xda) and Tetracyanonickelate(II) Linking Octahedral Cadmium(II) in [Cd(p-xda)nNi(CN)4] Host (n = 1, 1.5, or 2) and the Related Complex [Cd(C6H5NH2)2(p-xda)Ni(CN)4] Hidetaka Yuge, Yohsuke Noda, and Toschitake Iwamoto pp 1842 - 1848; DOI: 10.1021/ic950382n |
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A Dicyanoargentate(I) Rod Behaving as a Discrete Anion, a Monodentate Shaft or Shank, and an Ambidentate Shaft in the Crystal Structures of Imidazole-Blade Ligated Cadmium(II) Dicyanoargentate(I) Complexes: trans-Bis[dicyanoargentato(I)]tetrakis(imidazole)cadmium(II), [Dicyanoargentato(I)]pentakis(imidazole)cadmium(II) Dicyanoargentate(I), catena-Poly[tetrakis(N-methylimidazole)cadmium(II)-trans--dicyanoargentato(I)] Dicyanoargentate(I), and catena-Poly[tetrakis(2-methylimidazole)cadmium(II)-trans--dicyanoargentato(I)] Dicyanoargentate(I) Hydrate Takayoshi Soma and Toschitake Iwamoto pp 1849 - 1856; DOI: 10.1021/ic950629g |
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Structural and Magnetization Studies of a New (-Oxo)bis(-carboxylato)dimanganese(III) Complex with a Terminal Hydroxo Ligand Montserrat Corbella, Ramon Costa, Joan Ribas, Pascal H. Fries, Jean-Marc Latour, Lars Öhrström, Xavier Solans, and Víctor Rodríguez pp 1857 - 1865; DOI: 10.1021/ic950930x |
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Synthesis, Reactivity, and Stability of Di- and Trivalent Samarium Amides Ravinder K. Minhas, Yinlin Ma, Jae-Inh Song, and Sandro Gambarotta pp 1866 - 1873; DOI: 10.1021/ic951253+ |
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One- vs Two-Electron Reduction of N2O Promoted by a Divalent Chromium Macrocyclic Complex Michel Dionne, Jayne Jubb, Hillary Jenkins, Shirley Wong, and Sandro Gambarotta pp 1874 - 1879; DOI: 10.1021/ic9510728 |
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Retention of Structural Cores in the Synthesis of High-Nuclearity Polyoxoalkoxomolybdate Clusters Encapsulating [Na(H2O)3]+ and [MoO3] Moieties. Hydrothermal Syntheses and Structures of (NH4)7[NaH12Mo16O52]·4H2O and (Me3NH)4K2[H14Mo16O52]·8H2O and Their Structural Relationships to the Class of Superclusters [XHnMo42O109{(OCH2)3CR}7]m- (X = Na(H2O)3+: n = 13, m = 9; n = 15, m = 7. X = MoO3: n = 14, m = 9; n = 13, m = 10) M. Ishaque Khan, Qin Chen, Jose Salta, Charles J. O'Connor, and Jon Zubieta pp 1880 - 1901; DOI: 10.1021/ic9508841 |
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Pressure Dependence of the Crystal Structures and EPR Spectra of Potassium Hexaaquacopper(II) Sulfate and Deuterated Ammonium Hexaaquacopper(II) Sulfate Wolfgang Rauw, Hans Ahsbahs, Michael A. Hitchman, Sergei Lukin, Dirk Reinen, Arthur J. Schultz, Charles J. Simmons, and Horst Stratemeier pp 1902 - 1911; DOI: 10.1021/ic950857a |
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Crystal Structure of (Fluorosulfonyl)fluoroacetic Acid: A Novel Four-Center Hydrogen-Bond System Involving a C-H Donor Dale A. Braden, Gary L. Gard, and Timothy J. R. Weakley pp 1912 - 1914; DOI: 10.1021/ic951315w |
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Magnetic Properties of Cu2(OH)3(alkanecarboxylate) Compounds: Drastic Modification with Extension of the Alkyl Chain Wataru Fujita and Kunio Awaga pp 1915 - 1917; DOI: 10.1021/ic950965x |
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Acyclic Sulfur-Nitrogen Compounds. Syntheses and Crystal and Molecular Structures of Bis((trifluoromethyl)sulfonyl)amine ((CF3SO2)2NH), Magnesium Hexaaquo Bis((trifluoromethyl)sulfonyl)amide Dihydrate ([Mg(H2O)6][(CF3SO2)2N]2·2H2O), and Bis(bis(fluorosulfonyl)amino)sulfur ((FSO2)2NSN(SO2F)2) A. Haas, Ch. Klare, P. Betz, J. Bruckmann, C. Krüger, Y.-H. Tsay, and F. Aubke pp 1918 - 1925; DOI: 10.1021/ic9507934 |
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Giant Clusters with Unusual Electronic and Magnetic Structures Due to Open Shell Metal Centers Embedded Far Apart from Each Other: Spin Frustration and Antisymmetric Exchange Dante Gatteschi, Roberta Sessoli, Winfried Plass, Achim Müller, Erich Krickemeyer, Jochen Meyer, Dirk Sölter, and Peter Adler pp 1926 - 1934; DOI: 10.1021/ic951085l |
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Carboxyl-Bonded Low-Spin Iron(III). Chemistry of a Family of Coordination Type cis-FeN4O2 Soma Karmakar and Animesh Chakravorty pp 1935 - 1939; DOI: 10.1021/ic950976q |
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Observation of a Stable Water-Soluble Lithium Porphyrin Rosalie A. Richards, Kelly Hammons, Melanie Joe, and Gordon M. Miskelly pp 1940 - 1944; DOI: 10.1021/ic941434w |
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Effect of the NH---S Hydrogen Bond on the Nature of Hg-S Bonding in Bis[2-(acylamino)benzenethiolato]mercury(II) and Bis[2,6-bis(acylamino)benzenethiolato]mercury(II) Complexes Norikazu Ueyama, Kaku Taniuchi, Taka-aki Okamura, Akira Nakamura, Hironobu Maeda, and Shuichi Emura pp 1945 - 1951; DOI: 10.1021/ic950472s |
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2,2'-Bis(3-(2-pyridyl)-1-methyltriazolyl)biphenyl: A Tetracoordinating Wrapping Ligand Inducing Similar Skew Coordination Geometries at Copper(I) and Copper(II) Edgar Müller, Gérald Bernardinelli, and Jan Reedijk pp 1952 - 1957; DOI: 10.1021/ic950983e |
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Solution Studies of ReVO(anti-D-PENICILLAMINATO-N,S,O)(SYN-D-penicillaminato-N,S) Lory Hansen, Xiaolong Xu, Kwok To Yue, Zsuzsanna Kuklenyik, Andrew Taylor, Jr., and Luigi G. Marzilli pp 1958 - 1966; DOI: 10.1021/ic950992n |
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Zinc(II) and Copper(II) Complexes of Pentacoordinating (N4S) Ligands with Flexible Pyrazolyl Arms: Syntheses, Structure, and Redox and Spectroscopic Properties Sudeep Bhattacharyya, Sujit Baran Kumar, Subodh Kanti Dutta, Edward R. T. Tiekink, and Muktimoy Chaudhury pp 1967 - 1973; DOI: 10.1021/ic950594k |
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Binuclear Copper(II) Complexes of Bis(pentadentate) Ligands Derived from Alkyl-Bridged Bis(1,4,7-triazacyclonane) Macrocycles Suzanne J. Brudenell, Leone Spiccia, and Edward R. T. Tiekink pp 1974 - 1979; DOI: 10.1021/ic951146f |
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19F NMR Studies of Fluorine-Labeled Chromatium vinosum High-Potential Iron Protein Dawei Li, Aileen Soriano, and J. A. Cowan pp 1980 - 1987; DOI: 10.1021/ic951159t |
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Multiple Bonds between Main Group Elements and Transition Metals. 153.1 Rhenium(V) Oxo Complexes with Tetradentate Schiff Bases: Structural Considerations Wolfgang A. Herrmann, Monika U. Rauch, and Georg R. J. Artus pp 1988 - 1991; DOI: 10.1021/ic9508278 |
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Oxidation of a Dimeric Nickel Thiolate Complex with O2 Shaukat A. Mirza, Roberta O. Day, and Michael J. Maroney pp 1992 - 1995; DOI: 10.1021/ic950736a |
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Trigonal-Bipyramidal Copper(II) Complexes with Symmetric and Unsymmetric Tripodal Tetramine Ligands Andreas M. Dittler-Klingemann and and F. Ekkehardt Hahn pp 1996 - 1999; DOI: 10.1021/ic9506670 |
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Synthesis and Coordination of a Cleft-Stabilized Triphosphazane Hydride: C6H4N2[P(S)(NEt2)2]2PH Susan M. Young, Vasili Carperos, and Arlan D. Norman pp 2000 - 2005; DOI: 10.1021/ic951179v |
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(-Oxo)diiron Complexes of Gated Glyoximes. Structural Changes Accompanying Ligation Trans to the Oxo Bridge Isak Vernik and Dennis V. Stynes pp 2006 - 2010; DOI: 10.1021/ic950801g |
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(-Oxo)diiron Complexes of Borylated Dimethylglyoximes. Stepwise Ligation to Allosterically Linked Binding Sites and 1H NMR Spectra of Paramagnetic Nitrile, Amine, Imidazole, and Pyridine Derivatives Isak Vernik and Dennis V. Stynes pp 2011 - 2018; DOI: 10.1021/ic9508029 |
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Alkali Metal Complexes of the Pendant Arm Macrocyclic Ligand 1,4,7,10-Tetrakis(2-methoxyethyl)-1,4,7,10-tetraazacyclododecane. An Equilibrium and Inter- and Intramolecular Exchange Study Ashley K. W. Stephens, Ramesh S. Dhillon, Samer E. Madbak, Sonya L. Whitbread, and Stephen F. Lincoln pp 2019 - 2024; DOI: 10.1021/ic9509995 |
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Solution and Solid State Characterization of a Cadmium Octaazacryptand Complex Julia A. Thompson, Mary E. Barr, Doris K. Ford, Louis A. Silks, III, Jack McCormick, and Paul H. Smith pp 2025 - 2031; DOI: 10.1021/ic951010h |
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Photoinduced Electron Transfer and Intramolecular Folding in a Tricarbonylrhenium (Bi)pyridine Based Donor/Crown/Acceptor Assembly: Dependence on Solvent Christine A. Berg-Brennan, Dong I. Yoon, Robert V. Slone, Amy P. Kazala, and Joseph T. Hupp pp 2032 - 2035; DOI: 10.1021/ic950534e |
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Kinetics of Ligand Exchange Reactions for Uranyl(2+) Fluoride Complexes in Aqueous Solution Zoltán Szabó, Julius Glaser, and Ingmar Grenthe pp 2036 - 2044; DOI: 10.1021/ic951140q |
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The Potentially Hexadentate Isomeric Macrocycles trans- and cis-6,13-Diethyl-1,4,8,11-tetraazacyclotetradecane-6,13-diamine and Their Cobalt(III) Complexes: Unexpected Conformational Behavior Paul V. Bernhardt, Karl A. Byriel, Colin H. L. Kennard, and Philip C. Sharpe pp 2045 - 2052; DOI: 10.1021/ic951260y |
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Redox Behavior of Edge-Shared Bioctahedral [Re2(-NCS)2(NCS)8]3- and Its Relationship to the Direct Metal-Metal-Bonded Ion [Re2(NCS)8]2-: A Spectroelectrochemical Study Robin J. H. Clark and and David G. Humphrey pp 2053 - 2061; DOI: 10.1021/ic9511276 |
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Chemistry of the Hexaborane(10) Analogue (PPh3)2(CO)IrB5H8: Formation and Characterization of the Heterobimetallaheptaboranes 1,1,1-(CO)3-2,2-(CO)2-2,4-(PPh3)2-closo-1,2-FeIrB5H4 and 2-(CO)-2,2-(PPh3)2-7-Cl-7-(PMe2Ph)-nido-2,7-IrPtB5H7 Jonathan Bould, Nigam P. Rath, Hong Fang, and Lawrence Barton pp 2062 - 2069; DOI: 10.1021/ic951165p |
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Electron Transfer in Phenothiazine/Ru(bpy)32+ Donor-Chromophore Complexes S. L. Larson, C. Michael Elliott, and D. F. Kelley pp 2070 - 2076; DOI: 10.1021/ic9504699 |
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Role of -Bonding for Trigonal Level Splittings in Chromium(III) Complexes. 4. Doublet States and Zeeman Level Splittings in [Cr(bpy)3]3+ Thomas Schönherr, Michail Atanasov, and Andreas Hauser pp 2077 - 2084; DOI: 10.1021/ic950150o |
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Are the Compounds InH3 and TlH3 Stable Gas Phase or Solid State Species? Patricia Hunt and Peter Schwerdtfeger pp 2085 - 2088; DOI: 10.1021/ic950411u |
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Stability of Group 11 Carbonyl Complexes Cl-M-CO (M = Cu, Ag, Au) I. Antes, S. Dapprich, G. Frenking, and P. Schwerdtfeger pp 2089 - 2096; DOI: 10.1021/ic950910v |
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Bent's Rule and the Structure of Transition Metal Compounds V. Jonas, C. Boehme, and G. Frenking pp 2097 - 2099; DOI: 10.1021/ic951397o |
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Variable-Temperature Studies of Laser-Initiated 5T2 1A1 Intersystem Crossing in Spin-Crossover Complexes: Empirical Correlations between Activation Parameters and Ligand Structure in a Series of Polypyridyl Ferrous Complexes James K. McCusker, Arnold L. Rheingold, and David N. Hendrickson pp 2100 - 2112; DOI: 10.1021/ic9507880 |
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Geometry Optimizations of the Ground and Excited Triplet State Structures of the Low-Valent Metal-Metal Bonded Isocyanide and Carbonyl Di- and Trinuclear Palladium Complexes Using Density Functional Theory Réjean Provencher and and Pierre D. Harvey pp 2113 - 2118; DOI: 10.1021/ic950761g |
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Generation and Characterization of Diphosphene and Triphosphene Radical Anions. Computational Studies on the Structure and Stability of P3H3- Herbert Binder, Bernhard Riegel, Gernot Heckmann, Michael Moscherosch, Wolfgang Kaim, Hans-Georg von Schnering, W. Hönle, Heinz-Jürgen Flad, and Andreas Savin pp 2119 - 2126; DOI: 10.1021/ic950661a |
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Coexistence of Ligand Localized and MLCT Excited States in a 2-(2'-Pyridyl)benzo[g]quinoline Complex of Ruthenium(II) Emmanuelle Taffarel, Sarah Chirayil, Won Y. Kim, Randolph P. Thummel, and Russell H. Schmehl pp 2127 - 2131; DOI: 10.1021/ic9412973 |
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Structures of Alkali Metal Pseudohalides: LiOCP, NaOCP, LiSCP, NaSCP Tamás Veszprémi, Tibor Pasinszki, and Miklós Fehér pp 2132 - 2135; DOI: 10.1021/ic950865r |
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Electron Transfer. 128. Rate Enhancements by Donor Sulfur in Hexadentate Ligands Swapan K. Chandra and and Edwin S. Gould pp 2136 - 2139; DOI: 10.1021/ic950870v |
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Derivatives of the Dimethylbis(2-pyridyl)borate(1-) Ion: Synthesis and Structure Thomas G. Hodgkins and Douglas R. Powell pp 2140 - 2148; DOI: 10.1021/ic950775m |
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Copper(I) Isocyanide Complexes of Highly Fluorinated Poly(pyrazolyl)borates H. V. Rasika Dias, Hui-Ling Lu, John D. Gorden, and Wiechang Jin pp 2149 - 2151; DOI: 10.1021/ic951245t |
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Room Temperature Luminescence of Silicate Sol-Gel Materials Containing Trisodium Tris(dipicolinato)neodymate(III) Dorothy C. Lai, Bruce Dunn, and Jeffrey I. Zink pp 2152 - 2154; DOI: 10.1021/ic951310z |
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Structure Determination of the One-Dimensional Compound Sr3ZnPtO6, Containing Zinc in a Highly Unusual Trigonal Prismatic Coordination Environment Christina Lampe-Önnerud and Hans-Conrad zur Loye pp 2155 - 2156; DOI: 10.1021/ic9514511 |
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Synthesis and Conformation of Chiral Eight-Membered 12H-Dibenzo[d,g][1,3,2]dioxaphosphocins Stephen D. Pastor, Jonathan S. Rogers, M. Ali NabiRahni, and Edwin D. Stevens pp 2157 - 2161; DOI: 10.1021/ic951130p |
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K18Tl20Au3: A Novel Derivative of K8Tl11 with the Unprecedented Polyanion Tl9Au29-, the Parent Tl117-, and an Isolated Au- Ion Zhen-Chao Dong and John D. Corbett pp 2162 - 2162; DOI: 10.1021/ic960045u |
Issue 8
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Rare Earth Azatrane Chemistry: Facile Cleavage of THF To Give a Y2Li3O Cluster Helen C. Aspinall and and Martin R. Tillotson pp 2163 - 2164; DOI: 10.1021/ic950674o |
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Molecular Mechanics Force Field for Modeling Technetium(V) Complexes Robert D. Hancock, David E. Reichert, and Michael J. Welch pp 2165 - 2166; DOI: 10.1021/ic951422q |
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Formation of Dinitrogen by Oxidation of [(bpy)2(NH3)RuORu(NH3)(bpy)2]4+ Osamu Ishitani, Peter S. White, and Thomas J. Meyer pp 2167 - 2168; DOI: 10.1021/ic9512643 |
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Electrospray Tandem Mass Spectrometry of Nitrido and Imido Complexes Tai-Chu Lau and, Zhibiao Wu, Jiangyao Wang, K. W. Michael Siu, and Roger Guevremont pp 2169 - 2170; DOI: 10.1021/ic950852d |
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Novel Pathways in the Reactions of Superoxometal Complexes A. Bakac, Tae-Jin Won, and J. H. Espenson pp 2171 - 2175; DOI: 10.1021/ic951144v |
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Influence of Sulfur Metalation on the Accessibility of the NiII/I Couple in [N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II): Insight into the Redox Properties of [NiFe]-Hydrogenase Ghezai Musie, Patrick J. Farmer, Thawatchai Tuntulani, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 2176 - 2183; DOI: 10.1021/ic9515968 |
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Application of Dicyanohexasulfane for the Synthesis of cyclo-Nonasulfur. Crystal and Molecular Structures of S6(CN)2 and of -S9 Ralf Steudel, Klaus Bergemann, Jürgen Buschmann, and Peter Luger pp 2184 - 2188; DOI: 10.1021/ic951225r |
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Synthesis of B2H5FeCo(CO)6, Fe2Co(CO)9(-CO)BH2, FeCo2(CO)9(-CO)BH, FeCo2(CO)9(BH)2, and HFe3Co(CO)12BH. Co(CO)3 Fragment Addition and Fragment Exchange in Ferraborane Clusters Chang Soo Jun, Ananda K. Bandyopadhyay, and Thomas P. Fehlner pp 2189 - 2195; DOI: 10.1021/ic951352n |
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Magnetic Susceptibility Trends in Oxo-Bridged, Dinuclear Chromium(III) Complexes. Crystal Structure of [(tmpa)Cr(-O)(-CO3)Cr(tmpa)](ClO4)2·2H2O N. Kent Dalley, Xiaolan Kou, Charles J. O'Connor, and Robert A. Holwerda pp 2196 - 2201; DOI: 10.1021/ic951214y |
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Lanthanide Structures, Coordination, and Extraction Investigations of a 1,3-Bis(diethyl amide)-Substituted Calix[4]arene Ligand Paul D. Beer, Michael G. B. Drew, Mark Kan, Philip B. Leeson, Mark I. Ogden, and Gareth Williams pp 2202 - 2211; DOI: 10.1021/ic9512441 |
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Photoinduced Electron Transfer in Pentaammineruthenium(II) Complexes of 1-(4-Cyanophenyl)imidazole Antonios Hatzidimitriou, André Gourdon, Jean Devillers, Jean-Pierre Launay, Elena Mena, and Edmond Amouyal pp 2212 - 2219; DOI: 10.1021/ic950493m |
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Characterization of the Lowest Excited States of [Rh(bpy-h8)n(bpy-d8)3-n]3+ by Highly Resolved Emission and Excitation Spectra Werner Humbs and Hartmut Yersin pp 2220 - 2228; DOI: 10.1021/ic9510932 |
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Energy of the Photosubstitutionally Reactive Excited State of Pentaammine(pyridine)ruthenium(II) Rose M. Carlos, Miguel G. Neumann, and Elia Tfouni pp 2229 - 2234; DOI: 10.1021/ic950670j |
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Theoretical Study and Luminescence Properties of the Cyclic Cu3(dppm)3OH2+ Cluster. The First Luminescent Cluster Host at Room Temperature Réjean Provencher and Pierre D. Harvey pp 2235 - 2241; DOI: 10.1021/ic950812+ |
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Effect of Delocalization and Rigidity in the Acceptor Ligand on MLCT Excited-State Decay Joseph A. Treadway, Barbara Loeb, Rosa Lopez, Peter A. Anderson, F. Richard Keene, and Thomas J. Meyer pp 2242 - 2246; DOI: 10.1021/ic950961s |
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M(CN)2 Species (M = Be, Mg, Ca, Sr, Ba): Cyanides, Nitriles, or Neither? Jürgen Kapp and Paul v. R. Schleyer pp 2247 - 2252; DOI: 10.1021/ic9511837 |
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Synthesis, Characterization, and Crystal Structure of a Novel Copper(II) Complex with an Asymmetric Coordinated 2,2'-Bipyridine Derivative: A Model for the Associative Complex in the Ligand-Substitution Reactions of [Cu(tren)L]2+? Zhong-lin Lu, Chun-ying Duan, Yu-peng Tian, Xiao-zeng You, and Xiao-ying Huang pp 2253 - 2258; DOI: 10.1021/ic950362l |
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Structure of Dicopper Complexes of N,N,N',N'-Tetrakis[(2-benzimidazolyl)methyl]-2-hydroxy-1,3-diaminopropane with Coordinated Thiocyanate Counterions Weng Feng Zeng, Cheu Pyeng Cheng, Sung Mao Wang, and Gene-Hsian Lee pp 2259 - 2267; DOI: 10.1021/ic951432r |
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Electronic Structure of [Pt2(-O2CCH3)4(H2O)2]2+ Using the Quasi-Relativistic X-SW Method: Analysis of Metal-Metal Bonding, Assignment of Electronic Spectra, and Comparison with Rh2(-O2CCH3)4(H2O)2 Robert Stranger, Gregory A. Medley, John E. McGrady, Jodie M. Garrett, and Trevor G. Appleton pp 2268 - 2275; DOI: 10.1021/ic9506015 |
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Experimental and Theoretical Electronic Structure Investigations on -Nb3Cl8 and the Intercalated Phase '-NaNb3Cl8 John Rory Kennedy, Peter Adler, Richard Dronskowski, and Arndt Simon pp 2276 - 2282; DOI: 10.1021/ic951348b |
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Synthesis and Structural Investigations of [Mn3O4(phen)4(H2O)2](NO3)4·2.5H2O: A Water-Bound Complex Obtained by Cerium(IV) Oxidation K. Rajender Reddy, M. V. Rajasekharan, Navamoney Arulsamy, and Derek J. Hodgson pp 2283 - 2286; DOI: 10.1021/ic9502640 |
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Palladium Complexes with the Tridentate Dianionic Ligand Pyridine-2,6-dicarboxylate, dipic. Crystal Structure of [Pd(dipic)(PBu3)]2 Pablo Espinet and, Jesús A. Miguel, Santiago García-Granda and, and Daniel Miguel pp 2287 - 2291; DOI: 10.1021/ic951024n |
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Model Compounds for Iron Proteins. Structures and Magnetic, Spectroscopic, and Redox Properties of FeIIIMII and [CoIIIFeIII]2O Complexes with (-Carboxylato)bis(-phenoxo)dimetalate and (-Oxo)diiron(III) Cores Sujit K. Dutta, Rüdiger Werner, Ulrich Flörke, Sasankasekhar Mohanta, Kausik K. Nanda, Wolfgang Haase, and Kamalaksha Nag pp 2292 - 2300; DOI: 10.1021/ic9508334 |
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CsTl: A New Example of Tetragonally Compressed Tl66- Octahedra. Electronic Effects and Packing Requirements in the Diverse Structures of ATl (A = Li, Na, K, Cs) Zhen-Chao Dong and John D. Corbett pp 2301 - 2306; DOI: 10.1021/ic951265v |
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Self-Assembly of an 11-Component Cylindrical Inorganic Architecture: Electrospray Mass Spectrometry and Thermodynamic Studies Annie Marquis-Rigault, Annick Dupont-Gervais, Paul N. W. Baxter, Alain Van Dorsselaer, and Jean-Marie Lehn pp 2307 - 2310; DOI: 10.1021/ic951362o |
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Surface-Mediated Organometallic Synthesis: High-Yield Preparations of Neutral and Anionic Osmium Carbonyl Clusters by Controlled Reduction of Silica-Supported [Os(CO)3Cl2]2 and OsCl3 in the Presence of Na2CO3 or K2CO3 Dominique Roberto, Elena Cariati, Renato Ugo, and Rinaldo Psaro pp 2311 - 2316; DOI: 10.1021/ic950624j |
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Polyfluorinated Tris(pyrazolyl)borates. Syntheses and Spectroscopic and Structural Characterization of Group 1 and Group 11 Metal Complexes of [HB(3,5-(CF3)2Pz)3]- and [HB(3-(CF3)Pz)3]- H. V. Rasika Dias, Wiechang Jin, Hyoung-Juhn Kim, and Hui-Ling Lu pp 2317 - 2328; DOI: 10.1021/ic951361w |
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Reactions of [(6-arene)RuCl2]2 with Aromatic Phosphines Containing Methoxy Groups in 2,6-Positions Yasuhiro Yamamoto, Ryoichi Sato, Fumiko Matsuo, Chihiro Sudoh, and Toshiaki Igoshi pp 2329 - 2336; DOI: 10.1021/ic950625b |
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Competitive Substitution and Electron Transfer in Reactions between Haloamminegold(III) and Halocyanoaurate(III) Complexes and Thiocyanate Sofi K. C. Elmroth and Lars I. Elding pp 2337 - 2342; DOI: 10.1021/ic951126d |
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Kinetics and Mechanism of the Formation and Acid Dissociation of Cobalt(II), Nickel(II), and Copper(II) Complexes with the Highly Enolized -Diketone 3-(N-Acetylamido)pentane-2,4-dione (=Hamac) in Aqueous Solution Jürgen Hirsch, Helmut Paulus, and Horst Elias pp 2343 - 2351; DOI: 10.1021/ic950272g |
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Second-Sphere Coordination of Ferrioxamine B and Association of Deferriferrioxamine B, CH3(CH2)4NH3+, NH4+, K+, and Mg2+ with Synthetic Crown Ethers and the Natural Ionophores Valinomycin and Nonactin in Chloroform Ines Batini -Haberle, Ivan Spasojevi, and Alvin L. Crumblisspp 2352 - 2359; DOI: 10.1021/ic951414+ |
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FeIIIFeIII and FeIIFeIII Complexes as Synthetic Analogues for the Oxidized and Reduced Forms of Purple Acid Phosphatases Ademir Neves and, Marcos A. de Brito, Ivo Vencato, Valderes Drago, Klaus Griesar, and Wolfgang Haase pp 2360 - 2368; DOI: 10.1021/ic950456v |
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Electrospray Ionization Mass Spectral Characterization of Transient Iron Species of Bioinorganic Relevance Jinheung Kim, Yanhong Dong, Edmund Larka, and Lawrence Que, Jr. pp 2369 - 2372; DOI: 10.1021/ic951091h |
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ESR Studies of A1u and A2u Oxoiron(IV) Porphyrin -Cation Radical Complexes. Spin Coupling between Ferryl Iron and A1u/A2u Orbitals Hiroshi Fujii, Tetsuhiko Yoshimura, and Hitoshi Kamada pp 2373 - 2377; DOI: 10.1021/ic9513752 |
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Oxygen-17 NMR, Electronic, and Vibrational Spectroscopy of Transition Metal Peroxo Complexes: Correlation with Reactivity Martha S. Reynolds and Alison Butler pp 2378 - 2383; DOI: 10.1021/ic951212d |
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Observation of an Unusual Molecular Switching Device. The Position of One 1,2-Dimethylimidazole Switched "On" or "Off" the Rotation of the Other 1,2-Dimethylimidazole in cis,cis,cis-RuIICl2(Me2SO)2(1,2-dimethylimidazole)2 Marian Iwamoto, Enzo Alessio, and Luigi G. Marzilli pp 2384 - 2389; DOI: 10.1021/ic951063z |
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(Perylene)3[Bi4Br12]: A New Arene -Complex Containing the [Bi4Br12] Unit Luigi Pietro Battaglia, Carlo Bellitto, Maria Rita Cramarossa, and Ida Maria Vezzosi pp 2390 - 2392; DOI: 10.1021/ic950986r |
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Phosphorus Longitudinal Relaxation Times as a Probe of the Coordination Site of the Phosphine Ligands in Rhenium Complexes T. Beringhelli, G. D'Alfonso, M. Freni, and A. P. Minoja pp 2393 - 2395; DOI: 10.1021/ic950126a |
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Synthesis and X-ray Structure of the Novel Polymeric Lanthanum(III) 2,2'-Oxydiacetate [La2(C4H4O5)3(H2O)3·5H2O]n Ricardo Baggio, Maria Teresa Garland, Mireille Perec, and Daniel Vega pp 2396 - 2399; DOI: 10.1021/ic951078x |
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A Genuine Example of a Discrete Bimetallic (Cu, Gd) Complex: Structural Determination and Magnetic Properties Jean-Pierre Costes, Françoise Dahan, Arnaud Dupuis, and Jean-Pierre Laurent pp 2400 - 2402; DOI: 10.1021/ic951382q |
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A Bivanadyl Capped, Highly Reduced Keggin Polyanion, [PMoV6MoVI6O40(VIVO)2]5- Qin Chen and Craig. L. Hill pp 2403 - 2405; DOI: 10.1021/ic951231n |
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MO Analysis of the Fluxional Behavior of M(3-S2CPMe3)(CO)2(PMe3)2 (M = Mo, W) Complexes Agustín Galindo and Carlo Mealli pp 2406 - 2408; DOI: 10.1021/ic9509138 |
Issue 9
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Dioxygen Binding to Dinuclear Iron Centers on Methane Monooxygenase Models Kazunari Yoshizawa and Roald Hoffmann pp 2409 - 2410; DOI: 10.1021/ic9511480 |
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Nitric Oxide Reduction of the Copper(II) Complex Cu(dmp)22+ (dmp = 2,9-Dimethyl-1,10-phenanthroline) Dat Tran and Peter C. Ford pp 2411 - 2412; DOI: 10.1021/ic9511175 |
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The N2O2 Porphyrinogen Skeleton: Access to a Novel Class of Coordinatively Unsaturated Transition Metal Ions Raffaella Crescenzi, Euro Solari, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli pp 2413 - 2414; DOI: 10.1021/ic951649l |
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Bis(pyrazolylethyl) Ether Ligation to Zinc and Cobalt: Meridional vs Facial Coordination and the Suitability of Such Ligands in Providing a NNO Donor Set for Modeling Bioinorganic Aspects of Zinc Chemistry Conor Dowling, Vincent J. Murphy, and Gerard Parkin pp 2415 - 2420; DOI: 10.1021/ic9512744 |
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Synthesis of Tris(1,2-dimethoxyethane-O,O')barium Bis(2,2,5,5-tetramethyl-2,5-disilaphospholanide) and the Monomer-Dimer Equilibrium in Toluene Solution M. Westerhausen, M. Hartmann, and W. Schwarz pp 2421 - 2426; DOI: 10.1021/ic950854y |
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Pd···H-C Interactions. Preparation and Structure of Orthometalated Tetranuclear Complexes of Palladium(II) and Platinum(II) Tatsuya Kawamoto, Isoroku Nagasawa, Hiro Kuma, and Yoshihiko Kushi pp 2427 - 2432; DOI: 10.1021/ic950769q |
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Stabilizing Heterobimetallic Complexes Containing Unsupported Ti-M Bonds (M = Fe, Ru, Co): The Nature of Ti-M Donor-Acceptor Bonds Stefan Friedrich, Harald Memmler, Lutz H. Gade, Wan-Sheung Li, Ian J. Scowen, Mary McPartlin, and Catherine E. Housecroft pp 2433 - 2441; DOI: 10.1021/ic951353f |
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A Bis(azo-imine)palladium(II) System with 10 Ligand Electrons. Synthesis, Structure, Serial Redox, and Relationship to Bis(azooximates) and Other Species Chandan Kumar Pal, Surajit Chattopadhyay, Chittaranjan Sinha, and Animesh Chakravorty pp 2442 - 2447; DOI: 10.1021/ic950361t |
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Bulky Amidinate Complexes of Indium(III). Synthesis and Structure of [CyNC(tBu)NCy]2InCl Yuanlin Zhou and Darrin S. Richeson pp 2448 - 2451; DOI: 10.1021/ic950943a |
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Spectroelectrochemical Studies of Copper(I) Complexes with Binaphthyridine and Biquinoline Ligands. Crystal Structure Determination of Bis(6,7-dihydrodipyrido[2,3-b:3',2'-j][1,10]phenanthroline)copper(I) Tetrafluoroborate Sonya M. Scott, Keith C. Gordon, and Anthony K. Burrell pp 2452 - 2457; DOI: 10.1021/ic951217a |
X-ray Crystal Structure, ab Initio Calculations, and Reactivity of 1,3,2 5-Diazaphosphetes: A New Type of 4--Electron 4-Membered HeterocycleGilles Alcaraz, Antoine Baceiredo, Martin Nieger, Wolfgang W. Schoeller, and Guy Bertrand pp 2458 - 2462; DOI: 10.1021/ic951474f |
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The CeO2+ Cation: Gas-Phase Reactivity and Electronic Structure Christoph Heinemann, Hans H. Cornehl, Detlef Schröder, Michael Dolg, and Helmut Schwarz pp 2463 - 2475; DOI: 10.1021/ic951322k |
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Monomeric Bis(2-alkyne)copper(I) and -silver(I) Halides, Pseudohalides, and Arenethiolates Maurits D. Janssen, Mathias Herres, Laszló Zsolnai, Anthony L. Spek, David M. Grove, Heinrich Lang, and Gerard van Koten pp 2476 - 2483; DOI: 10.1021/ic950710j |
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Solid State Structures and Gold-Gold Bonding in Luminescent Halo(dimethylphenylphosphine)gold(I) Complexes Dawn V. Toronto, Brian Weissbart, Dino S. Tinti, and Alan L. Balch pp 2484 - 2489; DOI: 10.1021/ic951099r |
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Optical and ODMR Studies of Luminescent Halo(dimethylphenylphosphine)gold(I) Crystals Brian Weissbart, Dawn V. Toronto, Alan L. Balch, and Dino S. Tinti pp 2490 - 2496; DOI: 10.1021/ic951100m |
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Separation of Intrinsic and Electrostrictive Volume Effects in Redox Reaction Volumes of Metal Complexes Measured Using High-Pressure Cyclic Staircase Voltammetry John I. Sachinidis, Richard D. Shalders, and Peter A. Tregloan pp 2497 - 2503; DOI: 10.1021/ic951206h |
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Study of the Electronic Structure of Ni(5-C5H5)(NO) by Variable-Photon-Energy Photoelectron Spectroscopy and Density Functional Calculations Christian N. Field, Jennifer C. Green, Markus Mayer, Vladimir A. Nasluzov, Notker Rösch, and Michele R. F. Siggel pp 2504 - 2514; DOI: 10.1021/ic951120o |
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Variable-Energy Photoelectron Spectroscopy of (5-C5H5)NiNO: Molecular Orbital Assignment and X-SW Calculations Xiaorong Li, J. S. Tse, G. M. Bancroft, R. J. Puddephatt, and K. H. Tan pp 2515 - 2523; DOI: 10.1021/ic951013u |
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Deoxygenation of Polynuclear Metal-Oxo Anions: Synthesis, Structure, and Reactivity of the Condensed Polyoxoanion [(C4H9)4N]4(NbW5O18)2O Ying-Jie Lu, Roger Lalancette, and Robert H. Beer pp 2524 - 2529; DOI: 10.1021/ic951197c |
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An Approach to Heterometallic Complexes with Selenolate and Tellurolate Ligands: Crystal Structures of cis-[Mn(CO)4(SePh)2]-, [(CO)3Mn(-SeMe)3Mn(CO)3]-, (CO)4Mn(-TePh)2Co(CO)(-SePh)3Mn(CO)3, and (CO)3Mn(-SePh)3Fe(CO)3 Wen-Feng Liaw, Chih-Yuan Chuang, Way-Zen Lee, Chen-Kang Lee, Gene-Hsiang Lee, and Shie-Ming Peng pp 2530 - 2537; DOI: 10.1021/ic951487t |
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Orientation and Restricted Rotation of Lopsided Aromatic Ligands. Octahedral Complexes Derived from cis-RuCl2(Me2SO)4 Enzo Alessio, Mario Calligaris, Marian Iwamoto, and Luigi G. Marzilli pp 2538 - 2545; DOI: 10.1021/ic9509793 |
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Synthesis of New Bidentate Phosphine Ligands Containing Saturated Phosphorus Heterocycles Leslie D. Field and Iain P. Thomas pp 2546 - 2548; DOI: 10.1021/ic951374+ |
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Synthesis and Characterization of Heterodinuclear IrCo, RuCo, IrNi, and RuNi Complexes Containing Pyrazolate and Pyrazolylborate Ligands Daniel Carmona, Fernando J. Lahoz, Reinaldo Atencio, Andrew J. Edwards, Luis A. Oro, M. Pilar Lamata, Montserrat Esteban, and Swiatoslaw Trofimenko pp 2549 - 2557; DOI: 10.1021/ic950896m |
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Molecular Assemblies Containing Unsupported [FeIII-(2:2-RCO2)-CuII] Bridges Michael J. Scott, Christine A. Goddard, and R. H. Holm pp 2558 - 2567; DOI: 10.1021/ic9512035 |
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Synthesis and Characterization of a New Alkenyldecaborane and Alkenyl Monocarbon Carboranes Glamarie Burgos-Adorno, Patrick J. Carroll, and William Quintana pp 2568 - 2575; DOI: 10.1021/ic951138z |
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Osmium Complexes of 1,4,7-Triazacyclononane (tacn) and 1,4,7-Trimethyl-1,4,7-triazacyclononane (Me3tacn) and the X-ray Crystal Structure of [(Me3tacn)Os(6-C6H5BPh3)]BPh4·CH3CN David C. Ware, Marilyn M. Olmstead, Renyi Wang, and Henry Taube pp 2576 - 2582; DOI: 10.1021/ic951296q |
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Heteroatomic Centering of Icosahedral Clusters. Crystal and Electronic Structure of the K6(NaCd)2Tl12Cd Compound Containing the Not-So-Naked Tl12Cd12- Polyanion Monique M. Tillard-Charbonnel, Claude H. E. Belin, Alain P. Manteghetti, and David M. Flot pp 2583 - 2589; DOI: 10.1021/ic9600792 |
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Mechanistic Studies of the Formation and Decay of Diiron(III) Peroxo Complexes in the Reaction of Diiron(II) Precursors with Dioxygen Andrew L. Feig, Michael Becker, Siegfried Schindler, Rudi van Eldik, and Stephen J. Lippard pp 2590 - 2601; DOI: 10.1021/ic951242g |
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Transition Metal Complexes of p-Sulfonatocalix[5]arene Carl P. Johnson, Jerry L. Atwood, Jonathan W. Steed, Cary B. Bauer, and Robin D. Rogers pp 2602 - 2610; DOI: 10.1021/ic950862e |
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Reaction of Sulfur with Ga-C Bonds: Synthesis and Characterization of [PyRGaS]3 Formed from Ga(S2R)3 (R = Et, Me) Guihua Shang, Mark J. Hampden-Smith, and Eileen N. Duesler pp 2611 - 2615; DOI: 10.1021/ic951469b |
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Synthesis, Structure, and Bonding of Two Lanthanum Indium Germanides with Novel Structures and Properties Arnold M. Guloy and John D. Corbett pp 2616 - 2622; DOI: 10.1021/ic951378e |
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Synthesis and Structure of a New Quinary Sulfide Halide: LaCa2GeS4Cl3 Robert L. Gitzendanner and and Francis J. DiSalvo pp 2623 - 2626; DOI: 10.1021/ic951184z |
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Kinetic Studies of the Reactions of Pentacyanoferrate(II) Complexes with Peroxydisulfate Ming Hung Chen, Sheena Lee, Scott Liu, and Andrew Yeh pp 2627 - 2629; DOI: 10.1021/ic9505920 |
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Copper(II) Complexes of the Hexaaza Macrocyclic Ligand 3,6,9,16,19,22-Hexaaza-27,28-dioxatricyclo[22.2.1.111,14]octacosa-1(26),11,13,24-tetraene and Their Interaction with Oxalate, Malonate, and Pyrophosphate Anions Qin Lu, Joseph J. Reibenspies, Arthur E. Martell, and Ramunas J. Motekaitis pp 2630 - 2636; DOI: 10.1021/ic951384a |
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Photoinduced DNA Cleavage Reactions by Designed Analogues of Co(III)-Bleomycin: The Metalated Core Is the Primary Determinant of Sequence Specificity Edgardo T. Farinas, Jennifer D. Tan, and Pradip K. Mascharak pp 2637 - 2643; DOI: 10.1021/ic9503139 |
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Mononuclear Titanium Complexes That Contain Aminopyridinato Ligands Rhett Kempe and and Perdita Arndt pp 2644 - 2649; DOI: 10.1021/ic951177a |
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Structural Criteria for the Rational Design of Selective Ligands. 2. Effect of Alkyl Substitution on Metal Ion Complex Stability with Ligands Bearing Ethylene-Bridged Ether Donors Benjamin P. Hay, Delong Zhang, and Jim R. Rustad pp 2650 - 2658; DOI: 10.1021/ic9514760 |
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Synthesis and Characterization of a New Series of Nickel(II) meso-Tetrakis (polyfluorophenyl)porphyrins Functionalized by Pyrrole Groups and Their Electropolymerized Films Maria A. Carvalho de Medeiros, Serge Cosnier, Alain Deronzier, and Jean-Claude Moutet pp 2659 - 2664; DOI: 10.1021/ic9510268 |
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Synthesis, Spectroscopic Characterization, and Structural Studies of Bis(-sulfido)bis[{O,O-dialkyl (alkylene) dithiophosphato}oxomolybdenum(V)] Complexes. Crystal Structures of Mo2O2S2[S2P(OEt)2]2, Mo2O2S2[S2P(OEt)2]2·2NC5H5, and Mo2O3[S2P(OPh)2]4 John E. Drake, Anil G. Mislankar, and Raju Ratnani pp 2665 - 2673; DOI: 10.1021/ic950507o |
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13C CP/MAS NMR Studies of Hemoprotein Models with and without an Axial Hindered Base: 13C Shielding Tensors and Comparison with Hemoproteins and X-ray Structural Data I. P. Gerothanassis, M. Momenteau, P. J. Barrie, C. G. Kalodimos, and G. E. Hawkes pp 2674 - 2679; DOI: 10.1021/ic950830r |
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Synthesis and X-ray Crystal Structure Determination of the First Homoleptic Four-Coordinate Phosphido Complex of Samarium: Sm[(-PtBu2)2Li(thf)]2 Gerd W. Rabe, Jürgen Riede, and Annette Schier pp 2680 - 2681; DOI: 10.1021/ic951098z |
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Synthesis and X-ray Structure of the Novel Aluminum Complex [{3-HB(3-Phpz)2(5-Phpz)}2Al][AlCl4]. Catalysis of CO2/Propylene Oxide to Propylene Carbonate by the AlCl4- Anion Donald J. Darensbourg, Ernest L. Maynard, Matthew W. Holtcamp, Kevin K. Klausmeyer, and Joseph H. Reibenspies pp 2682 - 2684; DOI: 10.1021/ic951018r |
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Ruthenatetraboranes: Molecular Structure of [Ru(B3H8)(PPh3){3-HB(pz)3}] (pz = Pyrazol-1-yl) Ian D. Burns, Anthony F. Hill, and David J. Williams pp 2685 - 2687; DOI: 10.1021/ic951346r |
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Synthesis and Structure of the Diphenyl Binuclear Rhodium A-Frame Complex Rh2(-CO)(Ph)2(dmpm)2 D. Joe Anderson, Kurt W. Kramarz, and Richard Eisenberg pp 2688 - 2691; DOI: 10.1021/ic951095m |
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Study of cis-Tetraammineruthenium(II) Chemistry with Linear Dienes Toshihiro Sugaya, Atsuko Tomita, Hiromitu Sago, and Mitsuru Sano pp 2692 - 2694; DOI: 10.1021/ic950427k |
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Preparation and Single-Crystal Characterization of iPr2P(S)NHP(S)iPr2 and Homoleptic [iPr2P(S)NP(S)iPr2]- Complexes of Zinc, Cadmium, and Nickel Dominico Cupertino, Robin Keyte, Alexandra M. Z. Slawin, David J. Williams, and J. Derek Woollins pp 2695 - 2697; DOI: 10.1021/ic951333d |
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Neutron Diffraction Structure Analysis of a Triply-Bridged Binuclear Cobalt Hydride Complex, [(5-Cp*)Co]2H3 Frank Lutz, Robert Bau, Ping Wu, Thomas F. Koetzle, Carl Krüger, and Jörg J. Schneider pp 2698 - 2700; DOI: 10.1021/ic951297i |
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Effects of Systematic Variation in Bridging Ligand Structure on the Electrochemical and Magnetic Properties of a Series of Dinuclear Molybdenum Complexes Alexander M. W. Cargill Thompson, Dante Gatteschi, Jon A. McCleverty, Jon A. Navas, Eva Rentschler, and Michael D. Ward pp 2701 - 2703; DOI: 10.1021/ic9515057 |
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Exchange Coupling in Symmetrically syn,syn-Mono(carboxylato)-Bridged Dinuclear Copper(II) Complexes Kai-Silke Bürger, Phalguni Chaudhuri, and Karl Wieghardt pp 2704 - 2707; DOI: 10.1021/ic951381y |
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Synthesis, Structure, and Bonding of the Butterfly Cluster Containing the 4-Oxo and 4-Sulfido Ligands: [(PPh3)2N][Fe3M(CO)12(4-E)] (E = O, S; M = Mn, Re) Cynthia K. Schauer, Suzanne Harris, Michal Sabat, Eric J. Voss, and Duward F. Shriver pp 2708 - 2708; DOI: 10.1021/ic9600184 |
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Synthesis and Structure of [TpBut2]In, a Highly Twisted [Tris(3,5-di-tert-butylpyrazolyl)hydroborato]indium(I) Complex: Comparison with the Re-Evaluated Ordered Structure of [TpBut]In Matthew C. Kuchta, H. V. Rasika Dias, Simon G. Bott, and Gerard Parkin pp 2708 - 2708; DOI: 10.1021/ic961981c |
Issue 10
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The New Inorganic Ligands TeCl2 and TeBr2: Syntheses and Crystal Structures of Re6Te6Cl6(TeCl2)2 and [Re6Te8(TeBr2)6]Br2 Yuri V. Mironov, Michael A. Pell, and James A. Ibers pp 2709 - 2710; DOI: 10.1021/ic951559g |
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Preparation and Crystal Structure of the Silver(I) p-Toluenesulfonate-p-Aminobenzoic Acid Complex Polymer Adduct, the First Reported Example of a Silver(I) Complex Involving Two Different Organic Acid Species Graham Smith, Daniel E. Lynch, and Colin H. L. Kennard pp 2711 - 2712; DOI: 10.1021/ic950900u |
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The First Hexanuclear Tungsten Telluride Clusters [W6Te8L6]n- as Amine Complexes with L = Piperidine (n = 0) and L = Pyridine (n = 1) Xiaobing Xie and Robert E. McCarley pp 2713 - 2714; DOI: 10.1021/ic951656+ |
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New Stable Dinuclear Organocobalt Complexes with a Tridentate Imino-Oxime Ligand Renata Dreos, Giovanni Tauzher, Dimitrina H. Trendafilova, Giorgio Nardin, and Lucio Randaccio pp 2715 - 2716; DOI: 10.1021/ic951407l |
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Synthesis and Structure of Mes*AlN(Ph)Al(Mes*)N(Ph)NPh: A Formal Aluminum-Nitrogen Analog of the Cyclopentadienide Ion Rudolf J. Wehmschulte and Philip P. Power pp 2717 - 2718; DOI: 10.1021/ic9516065 |
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Spectral and Structural Characterization of Two Ferric Coordination Modes of a Simple Bis(catecholamide) Ligand: Metal-Assisted Self-Assembly in a Siderophore Analog Eric J. Enemark and T. D. P. Stack pp 2719 - 2720; DOI: 10.1021/ic960022f |
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Synthesis and Characterization of a New Class of 3-OH-Bridged Trimers That Contain Octahedrally Coordinated Divalent Metal Ions Bridged by Three Acetate Ligands and a Unique Catecholate Ligand. Solid State Molecular Structures of the [(py)5MII3(OAc)3(3-OH)((cat)] Complexes (M = Mn(II), Fe(II), Co(II), Ni(II)) R. A. Reynolds, III, W. O. Yu, W. R. Dunham, and D. Coucouvanis pp 2721 - 2722; DOI: 10.1021/ic960097j |
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Resonance Raman Characterization of (Oxoferryl)tetraphenylporphyrin Formed during Photodisproportionation of (Fe(TPP))2O in a Detergent Micelle at Room Temperature P. K. Shantha and A. L. Verma pp 2723 - 2725; DOI: 10.1021/ic951293d |
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Relaxometric, Structural, and Dynamic NMR Studies of DOTA-like Ln(III) Complexes (Ln = La, Gd, Ho, Yb) Containing a p-Nitrophenyl Substituent Silvio Aime, Mauro Botta, Giuseppe Ermondi, Enzo Terreno, Pier Lucio Anelli, Franco Fedeli, and Fulvio Uggeri pp 2726 - 2736; DOI: 10.1021/ic950981u |
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EPR and Magnetic Susceptibility Studies of Cobalt(II)- and Nickel(II)-Substituted Azurins from Pseudomonas aeruginosa. Electronic Structure of the Active Sites Hermas R. Jiménez, Jesús Salgado, José M. Moratal, and Irene Morgenstern-Badarau pp 2737 - 2741; DOI: 10.1021/ic9513548 |
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Chiral Phosphine Ligands Derived from Sugars. 3. Syntheses, Structures, and Spectroscopic Properties of Gold(I) Complexes with Chiral Phosphines from Glucose. X-ray Structures of [Au(2-MBPA)Cl] and [Au(3-MBPA)(2-pyS)] Ji-Cheng Shi, Xiao-Ying Huang, Da-Xu Wu, Qiu-Tian Liu, and Bei-Sheng Kang pp 2742 - 2746; DOI: 10.1021/ic9511682 |
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Neutral Four-Coordinate (Thiolato)- and (Selenolato)iron(II) Complexes: Synthesis and Characterization of Fe(E-2,6-i-Pr2C6H3)2(1-MeIm)2 (E = S, Se; 1-MeIm = 1-Methylimidazole). Potential Models for a Biological, Mononuclear N2S2 Binding Site for Iron? Cameron E. Forde, Alan J. Lough, Robert H. Morris, and Ravindranath Ramachandran pp 2747 - 2751; DOI: 10.1021/ic951222e |
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Discrete Mononuclear and Dinuclear Nickel(II) Complexes of Alkane- and Areneselenolates: Syntheses, Structures, and Properties of (Et4N)2[Ni2(Se(CH2)3Se)3], (Ph4P)2[Ni(SePh)4], and (Ph4P)2[Ni2(-2,4,6-(Me)3C6H2Se)2(2,4,6-(Me)3C6H2Se)4]·8CH3CN Christine Marganian Goldman, Marilyn M. Olmstead, and Pradip K. Mascharak pp 2752 - 2757; DOI: 10.1021/ic951257e |
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Synthesis and Reactivity of Group 4 Homoleptic Selenolates and Tellurolates: Lewis Base Induced Conversion to Terminal and Bridging Chalcogenides Christopher P. Gerlach, Victor Christou, and John Arnold pp 2758 - 2766; DOI: 10.1021/ic9600689 |
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Synthesis of a [Fe4S4]-S-Ferriheme Bridged Assembly Containing an Isobacteriochlorin Component: A Further Analogue of the Active Site of Sulfite Reductase Chaoyin Zhou, Lisheng Cai, and R. H. Holm pp 2767 - 2772; DOI: 10.1021/ic951493p |
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Cleavage of Functionally Relevant Sites in Ferritin mRNA by Oxidizing Metal Complexes H. Holden Thorp, R. Ann McKenzie, Peng-Nian Lin, William E. Walden, and Elizabeth C. Theil pp 2773 - 2779; DOI: 10.1021/ic951094u |
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Reductive Quenching of the Triplet State of Zinc Cytochrome c by the Hexacyanoferrate(II) Anion and by Conjugate Bases of Ethylenediaminetetraacetic Acid Chengyu Shen and Nenad M. Kosti pp 2780 - 2784; DOI: 10.1021/ic9510270 |
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Effect of Base on the Solution Behavior of Oxo(D-PENICILLAMINATO)(L-penicillaminato)rhenate(V) Lory Hansen, Xiaolong Xu, Kwok To Yue, Andrew Taylor, Jr., and Luigi G. Marzilli pp 2785 - 2791; DOI: 10.1021/ic951446x |
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Mechanistic Studies of Dichloro(1,4,7-triazacyclononane)copper(II)-Catalyzed Phosphate Diester Hydrolysis Kim A. Deal and Judith N. Burstyn pp 2792 - 2798; DOI: 10.1021/ic951488l |
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Mobility of Copper in Binding Sites in Rabbit Liver Metallothionein 2 Anna Rae Green and Martin J. Stillman pp 2799 - 2807; DOI: 10.1021/ic950540a |
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Synthesis and Characterization of Mono-, Bis-, and Tetrakis-Pyridyltriarylporphyrin Pd(II) and Pt(II) Supramolecular Assemblies. Molecular Structure of a Pd-Linked Bisporphyrin Complex Hongping Yuan, Leonard Thomas, and L. Keith Woo pp 2808 - 2817; DOI: 10.1021/ic951594n |
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[Tris(pyrazolyl)borato]vanadium(III) Phosphates: Structural Motifs from the Extended Solid and Models for the Interaction with DNA Norman S. Dean, Ladd M. Mokry, Marcus R. Bond, C. J. O'Connor, and Carl J. Carrano pp 2818 - 2825; DOI: 10.1021/ic9514556 |
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H2N(CH2CH2)2NH2[(VO)4(H2O)4(HPO4)2(PO4)2]: An Organically Templated Vanadium Phosphate with One Dimensional {-V-O=V-O-} Chains Victoria Soghomonian, Robert C. Haushalter, Jon Zubieta, and Charles J. O'Connor pp 2826 - 2830; DOI: 10.1021/ic941486l |
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Synthesis and Spectroscopic Characterization of Halodimethyl(O-alkyl dithiocarbonato)tellurium(IV) Compounds. Crystal Structures of Me2TeCl[S2COEt] and Me2TeI[S2CO(i-Pr)] John E. Drake, Robert J. Drake, Layla N. Khasrou, and Raju Ratnani pp 2831 - 2840; DOI: 10.1021/ic9511736 |
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Characterization of Aqueous Plutonium(IV) Nitrate Complexes by Extended X-ray Absorption Fine Structure Spectroscopy P. G. Allen, D. K. Veirs, S. D. Conradson, C. A. Smith, and S. F. Marsh pp 2841 - 2845; DOI: 10.1021/ic9511231 |
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Pressure-Induced Valence Tautomerism in Cobalt o-Quinone Complexes: An X-ray Absorption Study of the Low-Spin [CoIII(3,5-DTBSQ)(3,5-DTBCat)(phen)] to High-Spin [CoII(3,5-DTBSQ)2(phen)] Interconversion Cecile Roux, David M. Adams, Jean P. Itié, Alain Polian, David N. Hendrickson, and Michel Verdaguer pp 2846 - 2852; DOI: 10.1021/ic951080o |
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Magnetic Properties of (NH4)2FeF5·H2O: Influence of a Structural Phase Transformation and Relevance of Ambient Temperature Structure Determinations to the Interpretation of Low Temperature Magnetic Behavior W. M. Reiff, M. C. Moron, and Y. Calage pp 2853 - 2857; DOI: 10.1021/ic960020v |
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Coordination Modes of the 1,3-Dithiosquarate (1,3-dtsq) Ligand. Syntheses, Crystal Structures, and Magnetic Properties of [Ni(tren)(1,3-dtsq)(H2O)] and [Ni2(tren)2(1,3-dtsq)](ClO4)2 [tren = Tris(2-aminoethyl)amine] María Luisa Calatayud, Isabel Castro, Jorunn Sletten, Juan Cano, Francesc Lloret, Juan Faus, Miguel Julve, Gunther Seitz, and Klaus Mann pp 2858 - 2865; DOI: 10.1021/ic951393j |
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Cyclophanes with Sharp Corners: Synthesis of Macrocycles Containing One or Two 1,5,2,4,6,8-Dithiatetrazocine Rings Steven Dell, Douglas M. Ho, and Robert A. Pascal, Jr. pp 2866 - 2871; DOI: 10.1021/ic960172q |
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Cluster and Molecular Mechanical Analysis of the Conformations of All Six-Membered Cobalt(III) Diamine Rings in the Cambridge Structure Database Maria Fatima DaCruz and Marc Zimmer pp 2872 - 2877; DOI: 10.1021/ic9512237 |
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Characterization of the Structural and Electronic Properties of Spin-Coupled Dinuclear Copper(II) Centers by Proton NMR Spectroscopy Julie M. Brink, Rachel A. Rose, and Richard C. Holz pp 2878 - 2885; DOI: 10.1021/ic951472v |
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Density Functional Study of the Photodissociation of Mn2(CO)10 Angela Rosa, Giampaolo Ricciardi, Evert Jan Baerends, and Derk J. Stufkens pp 2886 - 2897; DOI: 10.1021/ic950518h |
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Photophysics and Photochemistry of Chromophore-Quencher Assemblies on Glass and Powdered Silica Brian W. Pfennig, Pingyun Chen, and Thomas J. Meyer pp 2898 - 2901; DOI: 10.1021/ic940676t |
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Halide-Dependent Change of the Lowest-Excited-State Character from MLCT to XLCT for the Complexes Re(X)(CO)3(-diimine) (X = Cl, Br, I; -diimine = bpy, iPr-PyCa, iPr-DAB) Studied by Resonance Raman, Time-Resolved Absorption, and Emission Spectroscopy Brenda D. Rossenaar, Derk J. Stufkens, and Antonín Vl ek, Jr.pp 2902 - 2909; DOI: 10.1021/ic9509802 |
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State Mixings in the Excited Triplet and Singlet States of Fluorine-Substituted Magnesium Tetraphenylporphines Studied by Optical and Time-Resolved EPR Spectroscopy Seigo Yamauchi, Yasuhisa Matsukawa, Yasunori Ohba, and Masamoto Iwaizumi pp 2910 - 2914; DOI: 10.1021/ic951108w |
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Fluoride Ion Induced Reactions of Silicon-Oxygen and Silicon-Sulfur Bonds with Hexafluorocyclotriphosphazenes: Synthesis, Reactivity, and X-ray Structural Analyses of Sulfur/Oxygen-Containing Monospirofluorophosphazenes Ashwani Vij, Steven J. Geib, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 2915 - 2929; DOI: 10.1021/ic951065j |
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Quadruply Bonded Complexes Containing Bridging Acetate and 3-Phosphine Ligands. Synthesis and Structural Characterization of Mo2(OAc)Cl3(3-tetraphos-2) and Mo2(OAc)Cl3(3-etp) (tetraphos-2 = P(CH2CH2PPh2)3; etp = Ph2PCH2CH2P(Ph)CH2CH2PPh2) Chang-Tai Lee, Shih-Fu Chiang, Chun-Ting Chen, Jhy-Der Chen, and Chwan-Deng Hsiao pp 2930 - 2936; DOI: 10.1021/ic951187b |
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Mononuclear and Binuclear Tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine (tpphz) Ruthenium and Osmium Complexes Joseph Bolger, André Gourdon, Eléna Ishow, and Jean-Pierre Launay pp 2937 - 2944; DOI: 10.1021/ic951436w |
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Ditin(IV) Chalcogenide Anions: 77Se, 119Sn, and 125Te Solution NMR Study of the Sn2Ch64- and Sn2Ch74- (Ch = Se, Te) Anions, X-ray Crystal Structures and Raman Spectra of K+(N(CH3)4+)3Sn2Se64-, (enH+)2(2,2,2-crypt-K+)2Sn2Se64-, and (K+)2(2,2,2-crypt-K+)2Sn2Te64-, and X-ray Crystal Structures of K+(2,2,2-crypt-K+)2HOSnTe33- and K+(2,2,2-crypt-K+)2HOSnTe33-·en Janette Campbell, Lesley A. Devereux, Michael Gerken, Hélène P. A. Mercier, Ayaaz M. Pirani, and Gary J. Schrobilgen pp 2945 - 2962; DOI: 10.1021/ic950917c |
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Synthesis and Structure of the Elusive [a2-B20H19]3- Anion Rachel A. Watson-Clark, Carolyn B. Knobler, and M. Frederick Hawthorne pp 2963 - 2966; DOI: 10.1021/ic951484g |
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Synthesis of Monocarbollide Complexes of Rhodium John C. Jeffery, Vyacheslav N. Lebedev, and F. Gordon A. Stone pp 2967 - 2976; DOI: 10.1021/ic951550e |
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Cesium Trialkylfluorometalates of Gallium and Indium: Compounds with Heterocubane Structure Bert Werner, Thomas Kräuter, and Bernhard Neumüller pp 2977 - 2980; DOI: 10.1021/ic951467r |
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Heterometallic Alkoxides of Zirconium with Tin(II) or Lead(II) Daniel J. Teff, John C. Huffman, and Kenneth G. Caulton pp 2981 - 2987; DOI: 10.1021/ic951413h |
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Zirconium Clusters from the Reaction of ZrCl4 with HSnBu3 Followed by Addition of Phosphines: Zr6Cl14H4(PR3)4 Compounds Linfeng Chen, F. Albert Cotton, and William A. Wojtczak pp 2988 - 2994; DOI: 10.1021/ic951256m |
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Synthesis and Reactivity of Heteroleptic Complexes of Gold with 2-Thioxo-1,3-dithiole-4,5-dithiolate (dmit). X-ray Structure of [Au2(-dmit)(PPh3)2], (NBu4)[Au(dmit)(PPh3)], and (PPN)[Au(dmit)(C6F5)2] Elena Cerrada, Peter G. Jones, Antonio Laguna, and Mariano Laguna pp 2995 - 3000; DOI: 10.1021/ic950893+ |
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Iridium(III) Complex Containing a Unique Bifurcated Hydrogen Bond Interaction Involving Ir-H···H(N)···F-B atoms. Crystal and Molecular Structure of [IrH(1-SC5H4NH)(2-SC5H4N)(PPh3)2](BF4)·0.5C6H6 Sunghan Park, Alan J. Lough, and Robert H. Morris pp 3001 - 3006; DOI: 10.1021/ic950438d |
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An 1-Aldehyde Complex and the Role of Hydrogen Bonding in Its Conversion to an 1-Imine Complex Wenbin Yao and Robert H. Crabtree pp 3007 - 3011; DOI: 10.1021/ic9508076 |
Effect of Axial Ligands on the Oxidation State, Structure, and Electronic Configuration of Diruthenium Complexes. Synthesis and Characterization of Ru2(dpf)4Cl, Ru2(dpf)4(C CC6H5), Ru2(dpf)4(CCC6H5)2, and Ru2(dpf)4(CN)2 (dpf = N,N'-Diphenylformamidinate)John L. Bear, Baocheng Han, Shurong Huang, and Karl M. Kadish pp 3012 - 3021; DOI: 10.1021/ic950864z |
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Oxidation at a Dimolybdenum(V) Sulfur Bridge. Formation of SO and SO2 Bridges. Facile Extrusion of SO from the SO2 Bridge Runtong Wang, Mark S. Mashuta, John F. Richardson, and Mark E. Noble pp 3022 - 3030; DOI: 10.1021/ic951518k |
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Chiral Induction in the Inner-Sphere Reduction of [Co(ox)3]3- by [Co(2,2,2-tet)(OH2)2]2+ and Derivatives Eileen C. Sheu, Maoyu Shang, and A. Graham Lappin pp 3031 - 3038; DOI: 10.1021/ic951403g |
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Electronic Structure of -Conjugated Redox Systems with Borane/Borataalkene End Groups Jan Fiedler, Stanislav Zali , Axel Klein, Fridmann M. Hornung, and Wolfgang Kaimpp 3039 - 3043; DOI: 10.1021/ic951482w |
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Effects of Coordination to Transition Metals on the Hydration and Electroactivity of the Chelating Ligand 1,10-Phenanthroline-5,6-dione Yabin Lei, Chunnian Shi, and Fred C. Anson pp 3044 - 3049; DOI: 10.1021/ic951569h |
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A Novel Example of Metal-Mediated Aromatic Thiolation in a Ruthenium Complex. Crystal Structure of RuII(SC6H4N=NC6H4N)2 Bidyut Kumar Santra, Ganesh A. Thakur, Prasanta Ghosh, Amitava Pramanik, and Goutam Kumar Lahiri pp 3050 - 3052; DOI: 10.1021/ic950810p |
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Synthesis and Characterization of a New Structural Type of Diruthenium(III) Complex John L. Bear, Yulan Li, Baocheng Han, Eric Van Caemelbecke, and Karl M. Kadish pp 3053 - 3055; DOI: 10.1021/ic9509600 |
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Synthesis and Structural Characterization of Bis- and Tris(closo-1,2-C2B10H11-1-yl)-Substituted Biphenyl and Benzene Wei Jiang, Carolyn B. Knobler, and M. Frederick Hawthorne pp 3056 - 3058; DOI: 10.1021/ic951575d |
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Complexation of Molybdenum by Siderophores: Synthesis and Structure of the Double-Helical cis-Dioxomolybdenum(VI) Complex of a Bis(catecholamide) Siderophore Analogue Anne-K. Duhme, Zbigniew Dauter, Robert C. Hider, and Siegfried Pohl pp 3059 - 3061; DOI: 10.1021/ic9512183 |
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1,2-Addition Reaction of a Protic Phosphonium Cation with a Phosphaalkyne Jason A. C. Clyburne and and Melbourne J. Schriver pp 3062 - 3063; DOI: 10.1021/ic951132+ |
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Synthesis and Characterization of {Pd(dmba)(py)[OC(CH3)=C(H)PPh3]}(ClO4)·CH2Cl2. Unusual O-Coordination of the (Acetylmethylene)triphenylphosphorane Ligand to a Soft Metal Center Larry R. Falvello, Susana Fernández, Rafael Navarro, and Esteban P. Urriolabeitia pp 3064 - 3066; DOI: 10.1021/ic951311r |
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A Binuclear Chloroferrate Anion with Octahedral Metal Coordination: Octachloro(-oxalato)diferrate(III), [(FeCl4)2(-C2O4)]4- Michael Feist, Sergei Troyanov, and Erhard Kemnitz pp 3067 - 3068; DOI: 10.1021/ic9513043 |
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Synthesis, Structural Studies, and Magnetic Exchange Interactions in Low-Valent Manganese Alkoxide Cubes Laura E. Pence, Andrea Caneschi, and Stephen J. Lippard pp 3069 - 3072; DOI: 10.1021/ic951448h |
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Evaluation of Triflate Displacement by Water in CH2Cl2 Solution: Comparison of trans-[Rh(CO)(PPh3)2(OSO2CF3)] and the Crystalline Salt trans-[Rh(CO)(PPh3)2(OH2)][OTf] Anna Svetlanova-Larsen and John L. Hubbard pp 3073 - 3076; DOI: 10.1021/ic951287h |
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Solubilities of Copper(II) and Chromium(III) -Diketonates in Supercritical Carbon Dioxide Anthony F. Lagalante, Brian N. Hansen, Thomas J.Bruno, and Robert E. Sievers pp 3076 - 3076; DOI: 10.1021/ic960236x |
Issue 11
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The Layered Planar Structure of Barium 1,3-Dithiepan-2-ylidenemalonate Kwan Mook Kim, Sung Sil Lee, Ok-Sang Jung, and Youn Soo Sohn pp 3077 - 3078; DOI: 10.1021/ic960083d |
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Optimized Structures of Bimetallic Systems: A Comparison of Full- and Broken-Symmetry Density Functional Calculations Timothy Lovell, John E. McGrady, Robert Stranger, and Stuart A. Macgregor pp 3079 - 3080; DOI: 10.1021/ic951564k |
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[(2-H)Ru3(CO)9{3-NS(O)MePh}]: An Electron-Deficient Trinuclear Cluster Containing a Chiral Sulfoximido Cap Georg Süss-Fink, Gerd Rheinwald, Helen St  ckli-Evans, Carsten Bolm, and Daniel Kaufmannpp 3081 - 3082; DOI: 10.1021/ic960006i |
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Weak Effect on Tc with Increased Interchain Distances. Structure and Magnetic Properties of (meso-Tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphinato)manganese(III) Tetracyanoethenide, [MnIIITP'P]+[TCNE]- Arno Böhm, Carlos Vazquez, R. Scott McLean, Joseph C. Calabrese, Sandra E. Kalm, Jamie L. Manson, Arthur J. Epstein, and Joel S. Miller pp 3083 - 3088; DOI: 10.1021/ic9516267 |
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Chemistry of Thiobenzoates: Syntheses, Structures, and NMR Spectra of Salts of [M(SOCPh)3]- (M = Zn, Cd, Hg) Jagadese J. Vittal and Philip A. W. Dean pp 3089 - 3093; DOI: 10.1021/ic9514298 |
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A Novel Pentadentate Coordination Mode for the Carbonato Bridge: Synthesis, Crystal Structure, and Magnetic Behavior of (3-CO3)[Ni3(Medpt)3(NCS)4], a New Trinuclear Nickel(II) Carbonato-Bridged Complex with Strong Antiferromagnetic Coupling Albert Escuer, Ramon Vicente, Sujit B. Kumar, Xavier Solans, Mercé Font-Bardía, and Andrea Caneschi pp 3094 - 3098; DOI: 10.1021/ic9514105 |
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Syntheses and Characterization of -[SiW10M2S2O38]6- (M = MoV, WV). Two Keggin Oxothio Heteropolyanions with a Metal-Metal Bond E. Cadot, V. Béreau, B. Marg, S. Halut, and F. Sécheresse pp 3099 - 3106; DOI: 10.1021/ic951054q |
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Na23K9Tl15.3: An Unusual Zintl Compound Containing Apparent Tl57-, Tl48-, Tl37-, and Tl5- Anions Zhen-Chao Dong and John D. Corbett pp 3107 - 3112; DOI: 10.1021/ic960014z |
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Observation of 31P-31P Indirect Spin-Spin Coupling in Copper-Bis(phosphine) Complexes by Two-Dimensional Solid-State NMR Gang Wu and Roderick E. Wasylishen pp 3113 - 3116; DOI: 10.1021/ic9512800 |
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Magnetostructural Correlations in Bis(2-phenoxide)-Bridged Macrocyclic Dinuclear Copper(II) Complexes. Influence of Electron-Withdrawing Substituents on Exchange Coupling Laurence K. Thompson, Sanat K. Mandal, Santokh S. Tandon, John N. Bridson, and Murray K. Park pp 3117 - 3125; DOI: 10.1021/ic9514197 |
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Ligand-Assisted Liquid Crystal Templating in Mesoporous Niobium Oxide Molecular Sieves David M. Antonelli, Atsushi Nakahira, and Jackie Y. Ying pp 3126 - 3136; DOI: 10.1021/ic951533p |
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Axial Bonding Capabilities of Square Planar d8-ML4 Complexes. Theoretical Study and Structural Correlations Gabriel Aullón and Santiago Alvarez pp 3137 - 3144; DOI: 10.1021/ic951643w |
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Crystal Structures of a Family of New Copper(I) Cyanide Complexes of Thiourea and Substituted Thioureas Fred B. Stocker, Melissa A. Troester, and Doyle Britton pp 3145 - 3153; DOI: 10.1021/ic9511027 |
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Crystal Structures of Two New Complexes Produced by Reaction of Copper(I) Cyanide with Thioacetamide. In Situ Formation of the Thiosulfate Anion Fred B. Stocker and and Melissa A. Troester pp 3154 - 3158; DOI: 10.1021/ic9502436 |
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Electron Transfer. 129. Copper Catalysis in the Thiol Reduction of Oxime-Bound Nickel(IV) Subrata Mandal, R. N. Bose, J. W. Reed, and E. S. Gould pp 3159 - 3162; DOI: 10.1021/ic951520b |
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Syntheses and Crystal Structures of Ruthenium Complexes of 1,4,8,11-Tetraazacyclotetradecane, Tris(2-aminoethyl)amine (tren), and Bis(2-aminoethyl)(iminomethyl)amine. A Microporous Layered Structure Consisting of {[K(tren)]2[RuCl6]}nn- and {(H5O2)4[RuCl6]}nn+ Ken Sakai, Yasutaka Yamada, and Taro Tsubomura pp 3163 - 3172; DOI: 10.1021/ic950688u |
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Steric Crowding and Redox Reactivity in Platinum(II) and Platinum(IV) Complexes Containing Substituted 1,10-Phenanthrolines Francesco P. Fanizzi, Giovanni Natile, Maurizio Lanfranchi, Antonio Tiripicchio, Franco Laschi, and Piero Zanello pp 3173 - 3182; DOI: 10.1021/ic960125y |
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Transition Metal Complexes of Cyanoisocyanoarenes as Building Blocks for One-, Two-, and Three-Dimensional Molecular Solids Li-Feng Mao and Andreas Mayr pp 3183 - 3187; DOI: 10.1021/ic950580e |
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Synthesis and Reaction Chemistry of the Disodium Alkoxide of 2,6-Bis(trifluoromethyl)-2,6-dihydroxy-3,3,4,4,5,5-hexafluorooxane John D. O. Anderson, William T. Pennington, and Darryl D. DesMarteau pp 3188 - 3193; DOI: 10.1021/ic9508435 |
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Synthesis, Characterization, and Crystal Structures of New Dications Bearing the -Se-Se- Bridge Francesco Bigoli, Francesco Demartin, Paola Deplano, Francesco A. Devillanova, Francesco Isaia, Vito Lippolis, Maria Laura Mercuri, Maria Angela Pellinghelli, and Emanuele F. Trogu pp 3194 - 3201; DOI: 10.1021/ic9510019 |
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A New Type of Heterobimetallic Compound Containing Tungstenocene: Synthesis, Reactivity, NMR, and Stereochemical Studies Sandrine Rigny, Vladimir I. Bakhmutov, Bernd Nuber, Jean-Claude Leblanc, and Claude Moïse pp 3202 - 3209; DOI: 10.1021/ic950966p |
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Equilibrium and Redox Kinetics of Copper(II)-Thiourea Complexes Christopher J. Doona and and David M. Stanbury pp 3210 - 3216; DOI: 10.1021/ic9502077 |
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Synthesis and Structure of an Extended Cluster Lead(II) Carboxylate, [Pb{(CO)9Co3(3-CCO2)}2]n. Role of Core Metals in Cluster-Derived Hydrogenation Catalysts Xinjian Lei, Maoyu Shang, Atul Patil, Eduardo E. Wolf, and Thomas P. Fehlner pp 3217 - 3222; DOI: 10.1021/ic951498m |
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Photochemical Synthesis of (6-Arene)chromium Hydrido Stannyl and (6-Arene)chromium Bis(stannyl) Complexes Abbas Khaleel and Kenneth J. Klabunde pp 3223 - 3227; DOI: 10.1021/ic951431z |
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Syntheses of Tantalum(V) Complexes Containing Tetramethylpyrrolyl, Pyrrolyl, and Indolyl Ligands Keith G. Parker, Bruce Noll, C. G. Pierpont, and M. Rakowski DuBois pp 3228 - 3234; DOI: 10.1021/ic9509544 |
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Dinuclear and Tetranuclear Cages of Oxodiphenylantimony Phosphinates: Synthesis and Structures Musa A. Said, K. C. Kumara Swamy, Damodara M. Poojary, Abraham Clearfield, M. Veith, and V. Huch pp 3235 - 3241; DOI: 10.1021/ic950713w |
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Ditungsten Siloxide Hydrides, [(silox)2WHn]2 (n = 1, 2; silox = tBuSiO), and Related Complexes Rebecca L. Miller, Kimberly A. Lawler, Jordan L. Bennett, and Peter T. Wolczanski pp 3242 - 3253; DOI: 10.1021/ic9513191 |
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Imide Transfer Properties and Reactions of the Magnesium Imide ((THF)MgNPh)6: A Versatile Synthetic Reagent Warren J. Grigsby, Tony Hascall, Jeffrey J. Ellison, Marilyn M. Olmstead, and Philip P. Power pp 3254 - 3261; DOI: 10.1021/ic951510a |
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New Routes to Synthetically Useful, Sterically Encumbered Arylaluminum Halides and Hydride Halides Rudolf J. Wehmschulte and and Philip P. Power pp 3262 - 3267; DOI: 10.1021/ic9515416 |
Terminally Bifurcated Tetraaurio-, -bis(sulfonium) Salts as Building Blocks for Auriophilicity-Determined Coordination PolymersAlexander Sladek and Hubert Schmidbaur pp 3268 - 3272; DOI: 10.1021/ic9516119 |
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Polyoxoanions Derived from [-SiO4W10O32]8--Containing Oxo-Centered Dinuclear Chromium(III) Carboxylato Complexes: Synthesis and Single-Crystal Structural Determination of [-SiO4W10O32(OH)Cr2(OOCCH3)2(OH2)2]5- Knut Wassermann, Hans-Joachim Lunk, Rosemarie Palm, Joachim Fuchs, Norbert Steinfeldt, Reinhard Stösser, and Michael T. Pope pp 3273 - 3279; DOI: 10.1021/ic9513954 |
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Studies on the Oral Anticancer Drug JM-216: Synthesis and Characterization of Isomers and Related Complexes Christopher F. J. Barnard, Jean F. Vollano, Penny A. Chaloner, and Shaliza Z. Dewa pp 3280 - 3284; DOI: 10.1021/ic951548n |
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New Explanation for Ligand Bending in Transition Metal Tris(dithiolate) Complexes Scott Campbell and Suzanne Harris pp 3285 - 3288; DOI: 10.1021/ic9513907 |
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Strain Energies in Homoatomic Nitrogen Clusters N4, N6, and N8 Benjamin M. Gimarc and Ming Zhao pp 3289 - 3297; DOI: 10.1021/ic951373h |
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Electronic Structure of Rh2(-CO)(CO)2(H2PCH2PH2)2. An Example of a Non-A-Frame Structure Carles Bo, Miquel Costas, Josep M. Poblet, Marie-Mad. Rohmer, and Marc Benard pp 3298 - 3306; DOI: 10.1021/ic9505256 |
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Orbital Configuration of the Valence Electrons, Ligand Field Symmetry, and Manganese Oxidation States of the Photosynthetic Water Oxidizing Complex: Analysis of the S2 State Multiline EPR Signals Ming Zheng and G. Charles Dismukes pp 3307 - 3319; DOI: 10.1021/ic9512340 |
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Near-Infrared Luminescence Spectroscopy of Nickelocene Doped into Single Crystals of Ruthenocene Martin J. Davis and Christian Reber pp 3320 - 3324; DOI: 10.1021/ic941346b |
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Dinuclear Copper(II) Complexes Incorporating a New Septadentate Polyimidazole Ligand Hanlin Nie, Sheila M. J. Aubin, Mark S. Mashuta, Richard A. Porter, John F. Richardson, David N. Hendrickson, and Robert M. Buchanan pp 3325 - 3334; DOI: 10.1021/ic9511985 |
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Proton-Induced Tuning of Electrochemical and Photophysical Properties in Mononuclear and Dinuclear Ruthenium Complexes Containing 2,2'-Bis(benzimidazol-2-yl)-4,4'-bipyridine: Synthesis, Molecular Structure, and Mixed-Valence State and Excited-State Properties Masa-aki Haga, Md. Meser Ali, Shiro Koseki, Kaori Fujimoto, Akio Yoshimura, Koichi Nozaki, Takeshi Ohno, Kiyohiko Nakajima, and Derk J. Stufkens pp 3335 - 3347; DOI: 10.1021/ic950083y |
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Oxidation of DNA Hairpins by Oxoruthenium(IV): Effects of Sterics and Secondary Structure Pamela J. Carter, C.-C. Cheng, and H. Holden Thorp pp 3348 - 3354; DOI: 10.1021/ic9515517 |
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Photophysics of Supercomplexes. Adduct between Ru(bpy)(CN)42- and the [32]ane-N8H88+ Polyaza Macrocycle Maria Anita Rampi, Maria Teresa Indelli, Franco Scandola, Fernando Pina and, and A. Jorge Parola pp 3355 - 3361; DOI: 10.1021/ic951590i |
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Dioxomolybdenum(VI) Complexes with New Enantiomerically Pure Amino Diol Ligands Pierluigi Barbaro, Tomás R. Belderrain, Claudio Bianchini, Giancarlo Scapacci, and Dante Masi pp 3362 - 3368; DOI: 10.1021/ic951464e |
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Bis(amido)ruthenium(IV) Complexes with 2,3-Diamino-2,3-dimethylbutane. Crystal Structure and Reversible Ru(IV)-Amide/Ru(III)-Amine and Ru(IV)-Amide/Ru(II)- Amine Redox Couples in Aqueous Solution Wing-Hong Chiu, Shie-Ming Peng, and Chi-Ming Che pp 3369 - 3374; DOI: 10.1021/ic951145n |
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Water Exchange and Rotational Dynamics of the Dimeric Gadolinium(III) Complex [BO{Gd(DO3A)(H2O)}2]: A Variable-Temperature and -Pressure 17O NMR Study Éva Tóth, Sylvain Vauthey, Dirk Pubanz, and André E. Merbach pp 3375 - 3379; DOI: 10.1021/ic951492x |
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Synthesis of a Heteroditopic Cryptand Capable of Imposing a Distorted Coordination Geometry onto Cu(II): Crystal Structures of the Cryptand (L), [Cu(L)(CN)](picrate), and [Cu(L)(NCS)](picrate) and Spectroscopic Studies of the Cu(II) Complexes Dillip K. Chand and Parimal K. Bharadwaj pp 3380 - 3387; DOI: 10.1021/ic950933+ |
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Speciation in Vanadium Bioinorganic Systems. 2. An NMR, ESR, and Potentiometric Study of the Aqueous H+-Vanadate-Maltol System K. Elvingson, A. González Baró, and L. Pettersson pp 3388 - 3393; DOI: 10.1021/ic951195s |
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Heterogeneous Kinetics of Metal- and Ligand-Based Redox Reactions within Adsorbed Monolayers Robert J. Forster pp 3394 - 3403; DOI: 10.1021/ic951343e |
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Perturbation of the Electronic Structure of a Copper(II) ion by a CuICl Moiety in a Class I Mixed Valence Copper Complex, CuII(Me5dien)Cl2(CuICl) Steven R. Breeze and Suning Wang pp 3404 - 3408; DOI: 10.1021/ic951239x |
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Structural and Functional Models for the Dinuclear Copper Active Site in Catechol Oxidases: Syntheses, X-ray Crystal Structures, Magnetic and Spectral Properties, and X-ray Absorption Spectroscopic Studies in Solid State and in Solution Frank Zippel, Friedhelm Ahlers, Rüdiger Werner, Wolfgang Haase, Hans-Friedrich Nolting, and Bernt Krebs pp 3409 - 3419; DOI: 10.1021/ic9513604 |
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Silver(I) Complexes of the Derivatized Crown Thioether Ligands 3,6,9,12,15,18-Hexathianonadecanol and 3,6,9,13,16,19-Hexathiaicosanol. Determination of Stability Constants and the Crystal Structures of [Ag(19-aneS6-OH)][CF3SO3] and [Ag(20-aneS6-OH)][BF4] Roger Alberto, Walter Nef, Alan Smith, Thomas A. Kaden, Markus Neuburger, Margareta Zehnder, Alfred Frey, Ulrich Abram, and P. August Schubiger pp 3420 - 3427; DOI: 10.1021/ic951421y |
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Synthesis and 109Ag NMR Studies of Homoleptic Silver(I) Stibines Angela M. Hill, William Levason, and Michael Webster pp 3428 - 3430; DOI: 10.1021/ic9515618 |
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Stable Cyclohexadienyl Complexes of Ruthenium in a Piano Stool Geometry Containing a Tridentate Nitrogen Donor Ligand. First Structural Characterization of the (5-Cyanocyclohexadienyl)ruthenium(II) Complex and Spectroelectrochemical Correlation Zahida Shirin, Amitava Pramanik, Prasanta Ghosh, and Rabindranath Mukherjee pp 3431 - 3433; DOI: 10.1021/ic950750n |
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Electronic Spectroscopy of Gold(I) Pseudomonas aeruginosa Azurin Derivatives T. Mark McCleskey, Tadashi J. Mizoguchi, John H. Richards, and Harry B. Gray pp 3434 - 3435; DOI: 10.1021/ic951055i |
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Synthesis and Characterization of Bis(arenethiolato)magnesium Complexes with Intramolecular Coordination. X-ray Structure of [Mg{S(C6H4-2-CH2NMe2)}2]2 Maurits D. Janssen, Remco van der Rijst, Anthony L. Spek, David M. Grove, and Gerard van Koten pp 3436 - 3439; DOI: 10.1021/ic951288+ |
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Thermal Transformation of cis- and trans-[{Mo(CO)3H}2{-5:5-C5H3(SiMe2)2C5H3}] into [{Mo(CO)3}2{-5:5-C5H4(SiMe2SiMe2)- C5H4}](Mo-Mo) Promoted by Hydride Migration Francisco Amor, Ernesto de Jesús, Pascual Royo, and Amelio Vázquez de Miguel pp 3440 - 3441; DOI: 10.1021/ic950091e |
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Synthesis and Characterization of a Novel Green Cobalt Corrinoid Kenneth L. Brown, Shifa Cheng, Jeffrey D. Zubkowski, and Edward J. Valente pp 3442 - 3446; DOI: 10.1021/ic9513088 |
Issue 12
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Degree and Influence of MoS··S Interactions in Oxo-Molybdenum(VI,V,IV) Complexes Jason P. Hill, Les J. Laughlin, Robert W. Gable, and Charles G. Young pp 3447 - 3448; DOI: 10.1021/ic951645g |
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Controlled Synthesis of a New, Soluble, Conjugated Metallopolymer Containing Ruthenium Chromophoric Units Seth C. Rasmussen, David W. Thompson, Virendra Singh, and John D. Petersen pp 3449 - 3450; DOI: 10.1021/ic9502786 |
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A2AuP2Se6 (A = K, Rb): Mixed-Valent Compounds with All Possible Coordination Geometries for Gold Konstantinos Chondroudis, Timothy J. McCarthy, and Mercouri G. Kanatzidis pp 3451 - 3452; DOI: 10.1021/ic9516020 |
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Ruthenium Porphyrins Containing Nitrosyl, Nitrosamine, Thiolate, and Amine Ligands Geun-Bae Yi, Masood A. Khan, and George B. Richter-Addo pp 3453 - 3454; DOI: 10.1021/ic951600f |
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Reactions of Ti+ with CH3PH2. Metal-Catalyzed Oligomerization of Phosphorus in the Gas Phase Asgeir Bjarnason and Ingvar Arnason pp 3455 - 3458; DOI: 10.1021/ic951337i |
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A Novel Luminescent 4-Selenido-Bridged Copper(I) Tetramer Vivian Wing-Wah Yam, Kenneth Kam-Wing Lo, and Kung-Kai Cheung pp 3459 - 3462; DOI: 10.1021/ic951565c |
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Red-Shifted Cyanide Stretching Frequencies in Cyanide-Bridged Transition Metal Donor-Acceptor Complexes. Support for Vibronic Coupling Murielle A. Watzky, John F. Endicott, Xiaoqing Song, Yabin Lei, and Ariel Macatangay pp 3463 - 3473; DOI: 10.1021/ic950834w |
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Solid-State 1H NMR Studies of Aluminum Oxide Hydroxides and Hydroxides Gilberto Piedra, John J. Fitzgerald, Neal Dando, Steven F. Dec, and Gary E. Maciel pp 3474 - 3478; DOI: 10.1021/ic951162c |
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Electron Paramagnetic Resonance Study of a Langmuir-Blodgett Film of Manganese Octadecylphosphonate and Comparison of the Magnetic Properties to Those of Solid-State Manganese Alkylphosphonates Candace T. Seip, Houston Byrd, and Daniel R. Talham pp 3479 - 3483; DOI: 10.1021/ic9514096 |
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Spin-Transition and Ferromagnetic Interactions in Copper(II) Complexes of a 3-Pyridyl-Substituted Imino Nitroxide. Dependence of the Magnetic Properties upon Crystal Packing Fabrice Lanfranc de Panthou, Dominique Luneau, Ryza Musin, Lars Öhrström, André Grand, P. Turek, and Paul Rey pp 3484 - 3491; DOI: 10.1021/ic951295y |
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Syntheses, Structural Analyses, and Unusual Magnetic Properties of Ba2CoSi2O7 and BaCo2Si2O7 Richard D. Adams, Christophe Payen, Timir Datta, Lars Öhrström, and Ralph Layland pp 3492 - 3497; DOI: 10.1021/ic960167m |
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Kinetics and Mechanism for Reduction of trans-Dichlorotetracyanoplatinate(IV) by Thioglycolic Acid, L-CYSTEINE, DL-Penicillamine, and Glutathione in Aqueous Solution Tiesheng Shi, Johan Berglund, and Lars I. Elding pp 3498 - 3503; DOI: 10.1021/ic951598s |
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Effect of Second-Sphere Coordination. 4.1 Factors Influencing the Electrochemical Behavior of Ruthenium-Ammine Complexes Caused by Second-Sphere Coordination of Crown Ethers Isao Ando, Daisuke Ishimura, Kikujiro Ujimoto, and Hirondo Kurihara pp 3504 - 3508; DOI: 10.1021/ic941048e |
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Selective Photolabilization in trans-[Ru(NH3)4(P(III))H2O]2+ and trans-[Ru(NH3)4(P(OR)3)2]2+ Complexes (P(III) = P(OR)3, P(R)3) Selma E. Mazzetto, Elia Tfouni, and Douglas W. Franco pp 3509 - 3513; DOI: 10.1021/ic9509847 |
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Limits of the in Situ Synthesis of Tris(2,2'-bipyridine)ruthenium(II) in the Supercages of Zeolite Y Philippe Lainé, Martin Lanz, and Gion Calzaferri pp 3514 - 3518; DOI: 10.1021/ic9600339 |
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Studies on Aerobic Reactions of Ammonia/3,5-Di-tert-butylcatechol Schiff-Base Condensation Products with Copper, Copper(I), and Copper(II). Strong Copper(II)-Radical Ferromagnetic Exchange and Observations on a Unique N-N Coupling Reaction Gabor Speier, Jozsef Csihony, Anne M. Whalen, and Cortlandt G. Pierpont pp 3519 - 3524; DOI: 10.1021/ic950805l |
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Copper(II) Coordination Compounds with Bis(imidazol-2-yl)methylamine and Bis(imidazol-2-yl)methylaminomethane in Relation to Bis(imidazol-2-yl)methylamine-Modified Poly(glycidyl methacrylate) Polymers and Other Bis(imidazol-2-yl)-Containing Ligands G. J. Anthony A. Koolhaas, Petronella M. van Berkel, Saskia C. van der Slot, Guillermo Mendoza-Diaz, Willem L. Driessen, Jan Reedijk, Huub Kooijman, Nora Veldman, and Anthony L. Spek pp 3525 - 3532; DOI: 10.1021/ic9513705 |
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Synthesis, Structures, and Spectroscopic Characterization of a Series of N,N'-Dimethyl-2,11-diaza[3.3](2,6)pyridinophane Vanadium(III), -(IV), and -(V) Complexes Harald Kelm and and Hans-Jörg Krüger pp 3533 - 3540; DOI: 10.1021/ic9510730 |
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Vanadium Hydridotris(pyrazolyl)borate Complexes of Diphenyl Phosphate. Homometallic Trimeric Complexes of the [LV{(PhO)2PO2}3]- Fragment Norman S. Dean, Ladd M. Mokry, Marcus R. Bond, C. J. O'Connor, and Carl J. Carrano pp 3541 - 3547; DOI: 10.1021/ic9600238 |
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Synthesis and Characterization of Rhenium Thiolate Complexes. Crystal and Molecular Structures of [NBu4][ReO(H2O)Br4)]·2H2O, [Bu4N][ReOBr4(OPPh3)], [ReO(SC5H4N)3], [ReO(SC4H3N2)3][ReO(OH)(SC5H4N-3,6-(SiMe2But)2)2], [Re(N2COC6H5)(SC5H4N)Cl(PPh3)2], and [Re(PPh3)(SC4H3N2)3] David J. Rose, Kevin P. Maresca, Peter B. Kettler, Yuan Da Chang, Victoria Soghomomian, Qin Chen, Michael J. Abrams, Scott K. Larsen, and Jon Zubieta pp 3548 - 3558; DOI: 10.1021/ic950881o |
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Planar Solid-State and Solution Structures of (Porphinato)nickel(II) As Determined by X-ray Diffraction and Resonance Raman Spectroscopy Walter Jentzen, Ilona Turowska-Tyrk, W. Robert Scheidt, and John A. Shelnutt pp 3559 - 3567; DOI: 10.1021/ic960157l |
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Synthesis, X-ray Structural Determination, and Magnetic Susceptibility, Mössbauer, and EPR Studies of (Ph4P)2[Fe2(Cat)4(H2O)2]·6H2O, a Catecholato-Bridged Dimer of Iron(III) Vincent A. Grillo, Graeme R. Hanson, Deming Wang, Trevor W. Hambley, Lawrence R. Gahan, Keith S. Murray, Boujemaa Moubaraki, and Clifford J. Hawkins pp 3568 - 3576; DOI: 10.1021/ic950499b |
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Mechanism for the Homolytic Cleavage of Alkyl Hydroperoxides by the Manganese(III) Dimer MnIII2(2-OHsalpn)2 M. Tyler Caudle, Pamela Riggs-Gelasco, Andrew K. Gelasco, James E. Penner-Hahn, and Vincent L. Pecoraro pp 3577 - 3584; DOI: 10.1021/ic951462u |
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Zinc-Containing Carboxylate-Bridged Heterodimetallic Complexes and Their Reactions with Phosphodiester Ligands Tomoaki Tanase, Joanne W. Yun, and Stephen J. Lippard pp 3585 - 3594; DOI: 10.1021/ic951625e |
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Extremely Facile Template Synthesis of Gold(III) Complexes of a Saturated Azamacrocycle and Crystal Structure of a Six-Coordinate Gold(III) Complex Myunghyun Paik Suh, Il Soon Kim, Boo Yong Shim, Daewon Hong, and Tae-Sung Yoon pp 3595 - 3598; DOI: 10.1021/ic9601201 |
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Factors Affecting Solution Properties of Vanadium(V) Compounds: X-ray Structure of -cis-NH4[VO2(EDDA)] Debbie C. Crans, Anastasios D. Keramidas, Mohammad Mahroof-Tahir, Oren P. Anderson, and Mary M. Miller pp 3599 - 3606; DOI: 10.1021/ic951270z |
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Structural Characterization of OC3OPor Capped Porphyrins: H2(OC3OPor), Fe(OC3OPor)(Cl), Fe(OC3OPor)(CO)(1-MeIm), and Fe(OC3OPor)(CO)(1,2-Me2Im) Carla Slebodnick, Michelle L. Duval, and James A. Ibers pp 3607 - 3613; DOI: 10.1021/ic951417m |
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Sulfur-Induced Pentacoordination in Cyclic Silanes Natalya V. Timosheva, T. K. Prakasha, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 3614 - 3621; DOI: 10.1021/ic9516018 |
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Synthesis and Characterization of the Mercaptosulfonium Cation, HSSH2+ Rolf Minkwitz and, Andreas Kornath, Wolfgang Sawodny, and Josef Hahn pp 3622 - 3625; DOI: 10.1021/ic951599k |
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Synthesis, Structure, and Coordination Chemistry of Aminophosphanylboranes Danan Dou, Gerald W. Linti, Tuqiang Chen, Eileen N. Duesler, Robert T. Paine, and Heinrich Nöth pp 3626 - 3634; DOI: 10.1021/ic9514399 |
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The Derivatives of the 7,8,9- Series of Tricarbollides. Preparation and Structural Characterization of the 11-Vertex Tricarbaboranes 7-L-nido-7,8,9-C3B8H10 (L = Amines) Bohumil  tíbr, Josef Holub, Ivana Císaová, Francesc Teixidor, Clara Viñas, Jií Fusek, and Zbyn k Plzákpp 3635 - 3642; DOI: 10.1021/ic951437o |
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Solution Studies of Ru2(O2CR)4n+ Complexes (n = 0, 1; O2CR = Octanoate, Crotonate, Dimethylacrylate, Benzoate, p-Toluate) and Solid-State Structures of Ru2(O2C-p-tolyl)4(THF)2, [Ru2(O2C-p-tolyl)4(THF)2]+[BF4]-, and Ru2(O2C-p-tolyl)4(CH3CN)2: Investigations of the Axial Ligation of the Ru2 Core Malcolm H. Chisholm, George Christou, Kirsten Folting, John C. Huffman, Chris A. James, John A. Samuels, Jodi L. Wesemann, and William H. Woodruff pp 3643 - 3658; DOI: 10.1021/ic950860u |
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Tetranuclear Phosphinidine, Phosphide, Arsenide, and Oxide Anionic Clusters of Molybdenum and Tungsten Supported by Neopentoxide Ligands: Na(18-crown-6)[M4(3-PSiMe3)(OCH2tBu)11], K(18-crown-6)[M4(3-E)(OCH2tBu)10] (E = P, As), K(18-crown-6)2[Mo4(3-O)(OCH2tBu)11] Theodore A. Budzichowski, Malcolm H. Chisholm, Kirsten Folting, William E. Streib, and Manfred Scheer pp 3659 - 3666; DOI: 10.1021/ic951292l |
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Stereochemical Analysis of Palladium(II) Complexes of the Selenium Coronands 1,5,9,13-Tetraselenacyclohexadecane and 1,5,9,13,17,21-Hexaselenacyclotetracosane Raymond J. Batchelor, Frederick W. B. Einstein, Ian D. Gay, Jian Gu, B. Mario Pinto, and Xuemin Zhou pp 3667 - 3674; DOI: 10.1021/ic951151j |
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Palladium(II) and Platinum(II) Complexes of the Heterodifunctional Ligand Ph2PNHP(O)Ph2 Pravat Bhattacharyya, Alexandra M. Z. Slawin, Martin B. Smith, and J. Derek Woollins pp 3675 - 3682; DOI: 10.1021/ic951247d |
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Reactions of Ir(CO)(H)(P(p-tolyl)3)3 with SO2 and O2 Mixtures and with H2SO4, Formation of a Sulfate-Bridged Dimer, and Crystal and Molecular Structure of Ir(CO)(H)(SO2)(P(p-tolyl)3)2 Cynthia A. Miller, Thomas S. Janik, Melvyn Rowen Churchill, and Jim D. Atwood pp 3683 - 3686; DOI: 10.1021/ic951249y |
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Coinage Metal Carbonyls and Isocyanides: Synthesis and Characterization of the Gold(I) Complexes [HB(3,5-(CF3)2Pz)3]AuCO and [HB(3,5-(CF3)2Pz)3]AuCNBut H. V. Rasika Dias and and Wiechang Jin pp 3687 - 3694; DOI: 10.1021/ic960186w |
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Synthesis of Vanadium(III), -(IV), and -(V) Complexes That Contain the Pentafluorophenyl-Substituted Triamidoamine Ligand [(C6F5NCH2CH2)3N]3- Kotohiro Nomura and Richard R. Schrock pp 3695 - 3701; DOI: 10.1021/ic951433j |
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X-Band ENDOR of the Liganding Environment from the Radical X Intermediate of Escherichia coli Ribonucleotide Reductase Andrei Veselov and Charles P. Scholes pp 3702 - 3705; DOI: 10.1021/ic951544i |
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A Phenoxo-Bridged Diferric Complex with Two Different Coordination Numbers in Two Distinct Coordination Sites Catherine Belle, Isabelle Gautier-Luneau, Jean-Louis Pierre, Corinne Scheer, and Eric Saint-Aman pp 3706 - 3708; DOI: 10.1021/ic951305v |
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Tetrahydrofuran Adducts of Bismuth Trichloride and Bismuth Tribromide Claire J. Carmalt, William Clegg, Mark R. J. Elsegood, R. John Errington, Joanne Havelock, Philip Lightfoot, Nicholas C. Norman, and Andrew J. Scott pp 3709 - 3712; DOI: 10.1021/ic951635f |
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Triamidogerma- and Triamidostannaaurates(I): First Structural Characterization of a Ge-Au-Ge Unit Maria Contel, Konrad W. Hellmann, Lutz H. Gade, Ian J. Scowen, Mary McPartlin, and Mariano Laguna pp 3713 - 3715; DOI: 10.1021/ic9515822 |
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Synthesis and Single-Crystal X-ray Investigation of 4-Azido-2-(triphenylphosphinimino)-3,5,6- trifluorobenzonitrile: A Chromogenic Nitrene Precursor for Photolabeling Raghoottama S. Pandurangi, Kattesh V. Katti, Robert R. Kuntz, Charles L. Barnes, and Wynn A. Volkert pp 3716 - 3718; DOI: 10.1021/ic9510021 |
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Luminescent Ruthenium Polypyridyl Complexes Containing Pendant Pyridinium Acceptors Christine Berg-Brennan, P. Subramanian, Michelle Absi, Charlotte Stern, and Joseph T. Hupp pp 3719 - 3722; DOI: 10.1021/ic951040k |
Issue 13
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Structure and Magnetic Properties of a Heptanuclear Nickel(II) Compound: [Ni7(-NO2)8(2-OH)2(3-OH)2(OHpn)2(Opn)2]2·7H2O M. Salah El Fallah, Eva Rentschler, Andrea Caneschi, Roberta Sessoli, and Dante Gatteschi pp 3723 - 3724; DOI: 10.1021/ic960002d |
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Leaving-Group Effects on Volumes of Activation for Dissociative Substitution Processes Robert B. Jordan pp 3725 - 3726; DOI: 10.1021/ic951513n |
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EPR Evidence for Chromium(V) Binding to Phosphate and Pyrophosphate: Implications for Chromium(V)-DNA Interactions Kent D. Sugden and Karen E. Wetterhahn pp 3727 - 3728; DOI: 10.1021/ic960199+ |
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A New One-Dimensional Quaternary Metal Thiophosphate: Synthesis and Structure of KNb2PS10 Junghwan Do and Hoseop Yun pp 3729 - 3730; DOI: 10.1021/ic951644o |
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Fixation of the 2-Methylimidazole Ligand and Anomalous Pyrrole Chemical Shifts in Bis(2-methylimidazole)(meso-tetraalkylporphyrinato)iron(III) Chloride Caused by the Nonplanar Porphyrin Ring Mikio Nakamura, Takahisa Ikeue, Saburo Neya, Noriaki Funasaki, and Nobuo Nakamura pp 3731 - 3732; DOI: 10.1021/ic9514962 |
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A New Ruthenium(II) Chiroporphyrin Containing a Multipoint Recognition Site: Enantioselective Receptor of Chiral Aliphatic Alcohols Marinella Mazzanti, Marc Veyrat, René Ramasseul, Jean-Claude Marchon, Ilona Turowska-Tyrk, Maoyu Shang, and W. Robert Scheidt pp 3733 - 3734; DOI: 10.1021/ic960016j |
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Intervalence Electron Transfer in Mixed Valence Diferrocenylpolyenes. Decay Law of the Metal-Metal Coupling with Distance Anne-Cécile Ribou, Jean-Pierre Launay, Michelle L. Sachtleben, Hu Li, and Charles W. Spangler pp 3735 - 3740; DOI: 10.1021/ic951376u |
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Influence of the Peripheral Ligand Atoms on the Exchange Interaction in Oxalato-Bridged Nickel(II) Complexes: An Orbital Model. Crystal Structures and Magnetic Properties of (H3dien)2[Ni2(ox)5]·12H2O and [Ni2(dien)2(H2O)2(ox)]Cl2 Pascual Román, Carmen Guzmán-Miralles, Antonio Luque, Javier I. Beitia, Juan Cano, Francesc Lloret, Miguel Julve, and Santiago Alvarez pp 3741 - 3751; DOI: 10.1021/ic951081g |
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Heme-Peptide Models for Hemoproteins. 1. Solution Chemistry of N-Acetylmicroperoxidase-8 Orde Q. Munro and Helder M. Marques pp 3752 - 3767; DOI: 10.1021/ic9502842 |
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Heme-Peptide Models for Hemoproteins. 2. N-Acetylmicroperoxidase-8: Study of the - Dimers Formed at High Ionic Strength Using a Modified Version of Molecular Exciton Theory Orde Q. Munro and Helder M. Marques pp 3768 - 3779; DOI: 10.1021/ic950285u |
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Catalytic Hydrolysis of Phosphate Diesters by Lanthanide(III) Cryptate (2.2.1) Complexes Soon Jin Oh, Kyong Hwa Song, Dongmok Whang, Kimoon Kim, Tae Hyun Yoon, Hichung Moon, and Joon Won Park pp 3780 - 3785; DOI: 10.1021/ic9510526 |
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Complexation of Nickel(II) with Guanosine 5'-Monophosphate and Inosine 5'-Monophosphate: A Potentiometric and Calorimetric Study Luis A. Herrero, Joan J. Fiol, Francesca Mas, Víctor Cerdà, and Angel Terrón pp 3786 - 3791; DOI: 10.1021/ic951219v |
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Dinuclear Nickel(II) Complexes as Models for the Active Site of Urease Dirk Volkmer, Birgit Hommerich, Klaus Griesar, Wolfgang Haase, and Bernt Krebs pp 3792 - 3803; DOI: 10.1021/ic951567x |
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Mechanism of (-H)(-alkenyl)Re2(CO)8 Formation in 350 nm Flash Irradiations of Re2(CO)10 M. Sarakha, M. Cozzi, and G. Ferraudi pp 3804 - 3807; DOI: 10.1021/ic951483o |
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Two-Dimensional 1H NMR Studies on Octahedral Nickel(II) Complexes Richard C. Holz, Evgenij A. Evdokimov, and Feben T. Gobena pp 3808 - 3814; DOI: 10.1021/ic951106b |
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Organic Free Radical-Promoted Isomerization of - and -Alkylcobinamides Xiang Zou, Daqing Zhao, and Kenneth L. Brown pp 3815 - 3820; DOI: 10.1021/ic960093e |
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Stability and Structure of Activated Macrocycles. Ligands with Biological Applications Ramunas J. Motekaitis, Buck E. Rogers, David E. Reichert, Arthur E. Martell, and Michael J. Welch pp 3821 - 3827; DOI: 10.1021/ic960067g |
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Synthesis and Characterization of Cobalt-Cage Complexes with Pendant Phenol Groups George C. Yeh, Alicia M. Beatty, and James K. Bashkin pp 3828 - 3835; DOI: 10.1021/ic951610g |
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Synthesis and Structure of the Layered Thorium Telluride CsTh2Te6 Jason A. Cody and James A. Ibers pp 3836 - 3838; DOI: 10.1021/ic951641b |
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Experimental and Theoretical Investigations of the Formation of the Diazene PhSN=C(H)N=NC(H)=NSPh from HCN2(SPh)3 by a Thiyl-Radical-Catalyzed Mechanism: Identification of the HC(NSPh)2 Radical and X-ray Structures of HCN2(SPh)3 and PhSN=C(H)N=NC(H)=NSPh Tristram Chivers, Bruce McGarvey, Masood Parvez, Ignacio Vargas-Baca, and Tom Ziegler pp 3839 - 3847; DOI: 10.1021/ic960317t |
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Formation of Metal Clusters or Nitrogen-Bridged Adducts by Reaction of a Bis(amino)stannylene with Halides of Two-Valent Transition Metals Michael Veith, Alice Müller, Lothar Stahl, Martin Nötzel, Maria Jarczyk, and Volker Huch pp 3848 - 3855; DOI: 10.1021/ic960007a |
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Metal Complexes of Dithiolate Ligands: 5,6-Dihydro-1,4-dithiin-2,3-dithiolato (dddt2-), 5,7-Dihydro-1,4,6-trithiin-2,3-dithiolato (dtdt2-), and 2-Thioxo-1,3-dithiole-4,5-dithiolato (dmit2-). Synthesis, Electrochemical Studies, Crystal and Electronic Structures, and Conducting Properties Christophe Faulmann, Ahmed Errami, Bruno Donnadieu, Isabelle Malfant, Jean-Pierre Legros, Patrick Cassoux, Carme Rovira, and Enric Canadell pp 3856 - 3873; DOI: 10.1021/ic9600341 |
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First Resolution of a Free Secondary Phosphine Chiral at Phosphorus and Stereospecific Formation and Structural Characterization of a Homochiral Secondary Phosphine-Borane Complex Armin Bader, Michael Pabel, Anthony C. Willis, and S. Bruce Wild pp 3874 - 3877; DOI: 10.1021/ic951494h |
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Synthesis and Characterization of a Boronated Metallophthalocyanine for Boron Neutron Capture Therapy Stephen B. Kahl and Jing Li pp 3878 - 3880; DOI: 10.1021/ic9600240 |
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Electron Transfer. 130. Reductions with Indium(I) Swapan K. Chandra and and Edwin S. Gould pp 3881 - 3884; DOI: 10.1021/ic960039y |
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Electronic Structure of Bis(2,4-pentanedionato-O,O')oxovanadium(IV). A Photoelectron Spectroscopy, Electronic Spectroscopy, and ab Initio Molecular Orbital Study Santo Di Bella, Giuseppe Lanza, Antonino Gulino, and Ignazio Fragalà pp 3885 - 3890; DOI: 10.1021/ic951457q |
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Direct Lanthanide-Transition Metal Interactions: Synthesis of (NH3)2YbFe(CO)4 and Crystal Structures of {[(CH3CN)3YbFe(CO)4]2·CH3CN} and [(CH3CN)3YbFe(CO)4] Haibin Deng, Sung-Ho Chun, Pierre Florian, Philip J. Grandinetti, and Sheldon G. Shore pp 3891 - 3896; DOI: 10.1021/ic9515113 |
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Theoretical and Experimental Study of Medium Effects on the Structure and Spectroscopy of the [Fe(CN)5NO]2- Ion Darío A. Estrin, Luis M. Baraldo, Leonardo D. Slep, Beatriz C. Barja, José A. Olabe, Luca Paglieri, and Giorgina Corongiu pp 3897 - 3903; DOI: 10.1021/ic951202c |
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Phosphorus Chemical Shift Tensors of Phosphole Derivatives Determined by 31P NMR Spectroscopy of Powder Samples Klaus Eichele, Roderick E. Wasylishen, Janet M. Kessler, Ljiljana Soluji , and John H. Nelsonpp 3904 - 3912; DOI: 10.1021/ic960095z |
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Halogen-Bridged Mixed-Valence Linear-Chain Complexes: Molecular Orbital Model of Electron Localization V. Robert, S. A. Borshch, and B. Bigot pp 3913 - 3916; DOI: 10.1021/ic951230v |
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Molecular Orbital Calculation and Spectroscopic Study of the Photochemical Generation of Bis(2,2'-bipyridine)rhodium(I) from Bis(2,2'-bipyridine)(oxalato)rhodium(III) Kazuteru Shinozaki and Naoto Takahashi pp 3917 - 3924; DOI: 10.1021/ic950939z |
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Photocatalytic Oxidation of Aromatic Hydrocarbons Yun Mao and Andreja Bakac pp 3925 - 3930; DOI: 10.1021/ic960142n |
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Octahedral Complexes with Predetermined Helical Chirality: Xylene-Bridged Bis([4,5]-pineno-2,2'-bipyridine) Ligands (Chiragen[o-, m-, p-xyl]) with Ruthenium(II) Hansruedi Mürner, Alex von Zelewsky, and Helen Stoeckli-Evans pp 3931 - 3935; DOI: 10.1021/ic951539e |
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Mono- and Dinuclear Transition Metal Complexes of the Hexadentate Ligand Tris(4-tert-butyl-2-mercaptobenzyl)-1,4,7-triazacyclononane (L) Thomas Beissel, Thorsten Glaser, Frank Kesting, Karl Wieghardt, and Bernhard Nuber pp 3936 - 3947; DOI: 10.1021/ic951623u |
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Stereochemical Consequences of the Bismuth Atom Electron Lone Pair, a Comparison between MX6E and MX6 Systems. Crystal and Molecular Structures of Tris[N-(P,P-diphenylphosphinoyl)-P,P-diphenylphosphinimidato]bismuth(III), [Bi{(OPPh2)2N}3], -indium(III), [In{(OPPh2)2N}3]·C6H6, and -gallium(III), [Ga{(OPPh2)2N}3]·CH2Cl2 Verónica García-Montalvo, Raymundo Cea-Olivares, Daniel J. Williams, and Georgina Espinosa-Pérez pp 3948 - 3953; DOI: 10.1021/ic9512082 |
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Geometry of the Fluorides, Oxofluorides, Hydrides, and Methanides of Vanadium(V), Chromium(VI), and Molybdenum(VI): Understanding the Geometry of Non-VSEPR Molecules in Terms of Core Distortion Ronald J. Gillespie, Ian Bytheway, Ting-Hua Tang, and Richard F. W. Bader pp 3954 - 3963; DOI: 10.1021/ic9514206 |
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Theoretical Study of Metal-Tetrahydroborato Ligand Interactions in [Y(THF)4(BH4)2]+ Zhitao Xu and Zhenyang Lin pp 3964 - 3966; DOI: 10.1021/ic960026k |
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Geometry and Electronic Structure of CuCl64- Polyhedra Doped into (3-Chloroanilinium)8[CdCl6]Cl4-An EPR and Structural Investigation Burkhard Wagner, Salam A. Warda, Michael A. Hitchman, and Dirk Reinen pp 3967 - 3974; DOI: 10.1021/ic951418e |
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Ligand-Driven Light-Induced Spin Change in Transition-Metal Complexes: Selection of an Appropriate System and First Evidence of the Effect, in FeII(4-styrylpyridine)4(NCBPh3)2 Marie-Laure Boillot, Cécile Roux, Jean-Paul Audière, Aurélie Dausse, and Jacqueline Zarembowitch pp 3975 - 3980; DOI: 10.1021/ic960015r |
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Mono- and Dinuclear d10 Metal Complexes of Hexakis(3,5-dimethylpyrazolyl)cyclotriphosphazene. Synthesis, Structures, and Unusual Solution Dynamic Behavior Younghun Byun, Dongwon Min, Junghwan Do, Hoseop Yun, and Youngkyu Do pp 3981 - 3989; DOI: 10.1021/ic950907b |
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Coordination Chemistry of 2,2'-Dipyridyl Diselenide: X-ray Crystal Structures of PySeSePy, [Zn(PySeSePy)Cl2], [(PySeSePy)Hg(C6F5)2], [Mo(SePy)2(CO)3], [W(SePy)2(CO)3], and [Fe(SePy)2(CO)2] (PySeSePy = C5H4NSeSeC5H4N; SePy = [C5H4N(2-Se)-N,Se]) Carsten O. Kienitz, Carsten Thöne, and Peter G. Jones pp 3990 - 3997; DOI: 10.1021/ic951454d |
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Cp*Ir(dab) (dab = 1,4-Bis(2,6-dimethylphenyl)-1,4-diazabutadiene): A Coordinatively Unsaturated Six--Electron Metallaheteroaromatic Compound? Stefan Greulich, Wolfgang Kaim, Andreas F. Stange, Hermann Stoll, Jan Fiedler, and Stanislav Záli pp 3998 - 4002; DOI: 10.1021/ic9514814 |
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Theoretical Study of Ethylene Oligomerization by an Organometallic Nickel Catalyst L. Fan, A. Krzywicki, A. Somogyvari, and T. Ziegler pp 4003 - 4006; DOI: 10.1021/ic950738v |
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Linear Trinuclear Pt···Mo-Mo Complexes [Mo2PtX2(pyphos)2(O2CR)2]2 (X = Cl, Br, I; R = CH3, C(CH3)3; pyphos = 6-(Diphenylphosphino)-2-pyridonate) with an Axial Interaction between the Quadruply Bonded Mo2 Moiety and the Platinum Atom Hiroshi Nakano, Akira Nakamura, and Kazushi Mashima pp 4007 - 4012; DOI: 10.1021/ic950988b |
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Synthesis and Structures of Sb[N(H)(C6H2tBu3)]3 and Bi[N(H)(C6H2tBu3)]3: Implications for the Steric Limits of Supermesityl Substitution Neil Burford, Charles L. B. Macdonald, Katherine N. Robertson, and T. Stanley Cameron pp 4013 - 4016; DOI: 10.1021/ic951532x |
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Direct Electrochemical Investigations of 17-Electron Complexes of CpM(CO)3 (M = Mo, W, and Cr) Denis C. Barbini, Pamela S. Tanner, Todd D. Francone, Kenneth B. Furst, and Wayne E. Jones, Jr. pp 4017 - 4022; DOI: 10.1021/ic951303a |
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Outer-Sphere Electron Transfer in Methylene Chloride: Concentration, Salt, and Temperature Dependences of the Oxidation of -Re2X4(cis-1,2-bis(diphenylphosphino)ethylene)2 (X = Cl, Br) by [Co(dimethylglyoximate)3(BF)2]BF4 and the Oxidation of Re2Br4(PMe2Ph)4 by [Co(1,2-cyclohexanedione dioximate)3(BBu)2]BF4 John Coddington and Scot Wherland pp 4023 - 4028; DOI: 10.1021/ic951654p |
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Polydentate N2S2O and N2S2O2 Ligands as Alcoholic Derivatives of (N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctane)nickel(II) and (N,N'-Bis(2-mercapto-2-methylpropane)-1,5-diazacyclooctane)nickel(II) Dawn C. Goodman, Rizalia M. Buonomo, Patrick J. Farmer, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 4029 - 4037; DOI: 10.1021/ic9514612 |
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Catalytic Reduction of Hydrazine to Ammonia with MoFe3S4-Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in Nitrogenase Konstantinos D. Demadis, Steven M. Malinak, and Dimitri Coucouvanis pp 4038 - 4046; DOI: 10.1021/ic960098b |
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Polymorphism in Lithium Amides: A Structural and Theoretical Study. Synthesis, Mechanism, and NMR Studies of the Lithiation of N,N'-Di-tert-butylethylenediamine Michael G. Gardiner and Colin L. Raston pp 4047 - 4059; DOI: 10.1021/ic951251p |
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Two-Dimensional Polytypism of "Crystalline" (C5Me5)ReO3 Norberto Masciocchi, Paolo Cairati, Filippo Saiano, and Angelo Sironi pp 4060 - 4063; DOI: 10.1021/ic951502u |
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Luminescence and Resonance Raman Study of Molecular Distortions Caused by Ligand-Centered Transitions in Metal Acetylacetonate Complexes David Wexler and Jeffrey I. Zink pp 4064 - 4066; DOI: 10.1021/ic9501374 |
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(Trimethylsilyl)trifluoroethene, a Floppy Molecule Stephen K. Ritter, Robert L. Kirchmeier, Jean'ne M. Shreeve, and Heinz Oberhammer pp 4067 - 4069; DOI: 10.1021/ic9513595 |
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Synthesis and Crystal and Molecular Structure of (BEDT-TTF)2[Pt(S2C4O2)2]: A Radical-Cation Salt of the Platinum(II) Dithiosquarate Complex C. Bellitto, M. Bonamico, V. Fares, and P. Serino pp 4070 - 4072; DOI: 10.1021/ic951401w |
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Why Are [Cu8Te12]4- Cage Clusters and Metallocarbohedrenes M8C12 Topologically Different? An ab Initio SCF Study Josep-M. Poblet, Marie-Madeleine Rohmer, and Marc Bénard pp 4073 - 4075; DOI: 10.1021/ic960085y |
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Two Types of New Polymeric Silver(I) Complexes from 1,4-Thioxane and Silver Triflate Herwig A. Buchholz, G. K. Surya Prakash, Julian F. S. Vaughan, Robert Bau, and George A. Olah pp 4076 - 4077; DOI: 10.1021/ic960123d |
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A Mixed (Arenethiolato)copper(I)/Copper Bromide Aggregate: X-ray Structure of Octanuclear [Cu8{SC6H3(CH2NMe2)2-2,6}3Br5] Maurits D. Janssen, Anthony L. Spek, David M. Grove, and Gerard van Koten pp 4078 - 4081; DOI: 10.1021/ic9515315 |
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Reactions of Copper(I) Halides with Tertiary Phosphines. The Unique Structure of [Cu(tribenzylphosphine)2][CuBr2] Pericles D. Akrivos, Petros P. Karagiannidis, Catherine P. Raptopoulou, Aris Terzis, and Stefan Stoyanov pp 4082 - 4083; DOI: 10.1021/ic951387n |
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A Novel Structure Type for Isolated Rare-Earth-Metal Clusters Centered by Transition Metals: Cs4R6I13Z (R = Ce, Pr; Z = Co, Os) Michael Lulei and John D. Corbett pp 4084 - 4086; DOI: 10.1021/ic960087i |
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A Tetragonal Bisphenoidal Tetracopper(I) Arrangement Supported by a Potentially Tridentate Ligand Containing Thiolate, Secondary Amine, and 2-Pyridine Functions: Hydrogen-Bonded Instead of Cu(I)-Coordinated Pyridine Rings in an S4-Symmetric Compound Andreas F. Stange, Karl Wilhelm Klinkhammer, and Wolfgang Kaim pp 4087 - 4089; DOI: 10.1021/ic951629j |
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Infrared Spectroscopic Study of the Matrix-Isolated Complexes of TiCl4 with PH3 and AsH3 Jennifer B. Everhart and and Bruce S. Ault pp 4090 - 4092; DOI: 10.1021/ic951631a |
Issue 14
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Preparation and Structure of [Li2Se(NtBu)3]2, Containing the Novel Se(NtBu)32- Anion Tristram Chivers, Masood Parvez, and Gabriele Schatte pp 4094 - 4095; DOI: 10.1021/ic960307s |
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Self-Assembly of Luminescent Molecular Squares Featuring Octahedral Rhenium Corners Robert V. Slone, Joseph T. Hupp, Charlotte L. Stern, and Thomas E. Albrecht-Schmitt pp 4096 - 4097; DOI: 10.1021/ic960464r |
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Development of a Synthetic Route to Unsymmetrical Triphosphine Ligands and an Investigation of Their Coordination Chemistry with Nickel and Palladium G. Dyer and J. Roscoe pp 4098 - 4102; DOI: 10.1021/ic960136r |
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Water-Soluble Phosphines. 6.1 Tailor-Made Syntheses of Chiral Secondary and Tertiary Phosphines with Sulfonated Aromatic Substituents: Structural and Quantum Chemical Studies Frank Bitterer, Oliver Herd, Antonella Hessler, Michael Kühnel, Karsten Rettig, Othmar Stelzer, William S. Sheldrick, Sabine Nagel, and Notker Rösch pp 4103 - 4113; DOI: 10.1021/ic9516572 |
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Asymmetrical A-Frame Triplatinum Clusters Bridged by Small Organic Molecules and Bis((diphenylphosphino)methyl)phenylphosphine Tomoaki Tanase, Hirokazu Ukaji, Toshiaki Igoshi, and Yasuhiro Yamamoto pp 4114 - 4119; DOI: 10.1021/ic951186j |
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Coordination and Redox Chemistry of Substituted-Polypyridyl Complexes of Ruthenium Angelos Dovletoglou, S. Ajao Adeyemi, and Thomas J. Meyer pp 4120 - 4127; DOI: 10.1021/ic9512587 |
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Specific Sequestering Agents for the Actinides. 29. Stability of the Thorium(IV) Complexes of Desferrioxamine B (DFO) and Three Octadentate Catecholate or Hydroxypyridinonate DFO Derivatives: DFOMTA, DFOCAMC, and DFO-1,2-HOPO. Comparative Stability of the Plutonium(IV) DFOMTA Complex Donald W. Whisenhunt, Jr., Mary P. Neu, Zhiguo Hou, Jide Xu, Darleane C. Hoffman, and Kenneth N. Raymond pp 4128 - 4136; DOI: 10.1021/ic951064r |
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Solvate Molecule Effects and Unusual 57Fe Mössbauer Line Broadening in the Valence Detrapping of Mixed-Valence [Fe3O(O2CCH3)6(3-Et-py)3]·S Chi-Cheng Wu, Ho Gyeom Jang, Arnold L. Rheingold, Philipp Gütlich, and David N. Hendrickson pp 4137 - 4147; DOI: 10.1021/ic9514509 |
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Dihydrogen Evolution by Protonation Reactions of Nickel(I) Thomas L. James, Lisheng Cai, Mark C. Muetterties, and R. H. Holm pp 4148 - 4161; DOI: 10.1021/ic960216v |
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Solid State Structures and Solution Dynamics of Unsolvated and Diethyl Ether Solvated Dilithium N,N'-Bis(trimethylsilyl)ethylenediamide Complexes Michael G. Gardiner and Colin L. Raston pp 4162 - 4169; DOI: 10.1021/ic9510425 |
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Through-Bond Exchange Coupling and Triplet Excitons in a Dinuclear Copper(II) Macrocyclic Complex Jean Christophe Colin, Talal Mallah, Yves Journaux, Francesc Lloret, Miguel Julve, and Claudette Bois pp 4170 - 4176; DOI: 10.1021/ic950186g |
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Reactions of 29 Transition Metal Cations, in the Same Oxidation State and under the Same Gas-Phase Conditions, with Sulfur Ian G. Dance, Keith J. Fisher, and Gary D. Willett pp 4177 - 4184; DOI: 10.1021/ic960127i |
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Theoretical Analysis of Reactions between Phosphanylnitrenes and Boranes: The Fate of the Adducts Minh Tho Nguyen, Annik Van Keer, and Luc G. Vanquickenborne pp 4185 - 4190; DOI: 10.1021/ic950415z |
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Crystal Structure of an Ammonium Nickel Molybdate Prepared by Chemical Precipitation Doron Levin, Stuart L. Soled, and Jackie Y. Ying pp 4191 - 4197; DOI: 10.1021/ic951200s |
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Structure and Thermodynamics of NaF-AlF3 Melts with Addition of CaF2 and MgF2 Bernard Gilbert, Eric Robert, Eric Tixhon, J  rn E. Olsen, and Terje Østvoldpp 4198 - 4210; DOI: 10.1021/ic951660l |
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A Novel Optical Complex between an Organic Substrate and a Polyoxometalate. Crystal and Molecular Structure of -H4SiW12O40·4HMPA·2H2O (HMPA = Hexamethylphosphoramide) Jing-yang Niu, Xiao-zeng You, Chun-ying Duan, Hoong-kun Fun, and Zhong-yuan Zhou pp 4211 - 4217; DOI: 10.1021/ic951458i |
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Magneto-Optical Investigation of the Exchange-Coupled Dimer Cs3Mo2Br9 Robert Stranger, Lucjan Dubicki, and Elmars Krausz pp 4218 - 4226; DOI: 10.1021/ic951581+ |
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Rhenium(V) Oxo Complexes of Novel N2S2 Dithiourea (DTU) Chelate Ligands: Synthesis and Structural Characterization Malgorzata Lipowska, Brittany L. Hayes, Lory Hansen, Andrew Taylor, Jr., and Luigi G. Marzilli pp 4227 - 4231; DOI: 10.1021/ic9514657 |
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Gold(I)-Purine Interactions: Synthesis and Characterization of Cyclic and Open Chain Polynuclear Gold(I) Complexes Containing Xanthine Derivatives and Bis(phosphine) as Bridging Ligands. Crystal Structures of [Au2(-HX)(-dmpe)]·3H2O and [Au2(-TT)(-dmpe)]·H2O (H3X = Xanthine; H2TT = 8-Mercaptotheophylline) Enrique Colacio, Rafael Cuesta, Juan M. Gutiérrez-Zorrilla, Antonio Luque, Pascual Román, Tania Giraldi, and Max R. Taylor pp 4232 - 4238; DOI: 10.1021/ic951591a |
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Amide Group Coordination to the Pb2+ Ion Gianantonio Battistuzzi, Marco Borsari, Ledi Menabue, Monica Saladini, and Marco Sola pp 4239 - 4247; DOI: 10.1021/ic950599h |
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Individual Reduction Potentials of the Iron Ions in Fe2S2 and High-Potential Fe4S4 Ferredoxins Lucia Banci, Ivano Bertini, Giovanni Gori Savellini, and Claudio Luchinat pp 4248 - 4253; DOI: 10.1021/ic960051q |
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Mechanism of Formation of Peroxocarbonates RhOOC(O)O(Cl)(P)3 and Their Reactivity as Oxygen Transfer Agents Mimicking Monooxygenases. The First Evidence of CO2 Insertion into the O-O Bond of Rh(2-O2) Complexes Michele Aresta, Immacolata Tommasi, Eugenio Quaranta, Carlo Fragale, Joëlle Mascetti, Michel Tranquille, Florence Galan, and Monique Fouassier pp 4254 - 4260; DOI: 10.1021/ic951154w |
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New Rhodium(II) Complexes with 2,2':6',2''-Terpyridine Florian P. Pruchnik, Francis Robert, Yves Jeannin, and Suzanne Jeannin pp 4261 - 4263; DOI: 10.1021/ic950529a |
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Electronic Excitation of the 1,2,3,5-Dithiadiazolyl Radical. A Spectroscopic and Theoretical Analysis Jennifer Campbell, Dieter Klapstein, Peter F. Bernath, William M. Davis, Richard T. Oakley, and John D. Goddard pp 4264 - 4266; DOI: 10.1021/ic951512v |
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Dipyridophenazine Complexes of Cobalt(III) and Nickel(II): DNA-Binding and Photocleavage Studies S. Arounaguiri and Bhaskar G. Maiya pp 4267 - 4270; DOI: 10.1021/ic9508684 |
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Synthesis and Crystal Structure of the Two-Dimensional Coordination Polymer (Ph3Sn)3Fe(CN)6·H2O·2CH3CN Jian Lu, William T. A. Harrison, and Allan J. Jacobson pp 4271 - 4273; DOI: 10.1021/ic960077h |
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Subtle Ring Size Effects on Bonding Mode. Structures and Properties of Platinum(II) Complexes Involving Sulfur-Containing Dicarboxylate Ligands S-(CH2)n-S-C=C(COO-)2 (n = 2, 3, 4) Youn Soo Sohn, Kwan Mook Kim, Seong-Joo Kang, and Ok-Sang Jung pp 4274 - 4276; DOI: 10.1021/ic951312j |
Issue 15
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Halide Effects in the Formation of Four-Coordinate, Cationic Aluminum David Atwood and and Jolin Jegier pp 4277 - 4282; DOI: 10.1021/ic960344j |
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Synthesis and Reactivity of Organosamarium Diarylpnictide Complexes: Cleavage Reactions of Group 15 E-E and E-C Bonds by Samarium(II) William J. Evans, John T. Leman, Joseph W. Ziller, and Saeed I. Khan pp 4283 - 4291; DOI: 10.1021/ic951627z |
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Selective Azide Oxidation of 1,2-Bis(diphenylphosphino)benzene and Related Ethylenebis(phosphines) to Asymmetric Multifunctional Phosphorus Ligands and Formation of Rhodium(I) Complexes of These Ligands. Structural Characterization of the Prototypical Ligand 1-(((Trimethylsilyl)imino)diphenylphosphorano)-2-(diphenylphosphino)benzene and Its Rhodium(I) Complex: 1-Ph2P=N(SiMe3)C6H4-2-(Ph2P)Rh(CO)Cl Robert W. Reed, Bernard Santarsiero, and Ronald G. Cavell pp 4292 - 4300; DOI: 10.1021/ic9514713 |
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Regioselective Substitution Reactions of Sulfur(VI)-Nitrogen-Phosphorus Rings: Reactions of the Halogenated Cyclic Thionylphosphazenes [NSOX(NPCl2)2] (X = Cl or F) with Oxygen-Based Nucleophiles Derek P. Gates, Peter Park, Mong Liang, Mark Edwards, Constantina Angelakos, Louise M. Liable-Sands, Arnold L. Rheingold, and Ian Manners pp 4301 - 4309; DOI: 10.1021/ic9516166 |
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The Osmium(VIII) Oxofluoro Cations OsO2F3+ and F(cis-OsO2F3)2+: Syntheses, Characterization by 19F NMR Spectroscopy and Raman Spectroscopy, X-ray Crystal Structure of F(cis-OsO2F3)2+Sb2F11-, and Density Functional Theory Calculations of OsO2F3+, ReO2F3, and F(cis-OsO2F3)2+ William J. Casteel, Jr., David A. Dixon, Hélène P. A. Mercier, and Gary J. Schrobilgen pp 4310 - 4322; DOI: 10.1021/ic951059n |
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Excited-State Distortions and Electron Delocalization in Mixed-Valence Dimers: Vibronic Analysis of the Near-IR Absorption and Resonance Raman Profiles of [Fe2(OH)3(tmtacn)2]2+ Daniel R. Gamelin, Emile L. Bominaar, Corine Mathonière, Martin L. Kirk, Karl Wieghardt, Jean-Jacques Girerd, and Edward I. Solomon pp 4323 - 4335; DOI: 10.1021/ic960413u |
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Investigations of the TeCl4-tBuNHLi Reaction: Synthesis, X-ray Structures, and Fluxional Behavior of the Tellurium-Nitrogen Compounds [Li2Te(NtBu)3]2, {[LiTe(NtBu)2(NHtBu)]2LiCl}2, and {Te2(NtBu)4[LiTe(NtBu)2(NHtBu)]LiCl}2 Tristram Chivers, Xiaoliang Gao, and Masood Parvez pp 4336 - 4341; DOI: 10.1021/ic960156t |
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Synthesis and Molecular Structures of Pyridine-Containing Large-Membered Cyclic Bis(alkoxy)silanes T. K. Prakasha, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 4342 - 4346; DOI: 10.1021/ic960162p |
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Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe6S8(PEt3)6]n+ (n = 0-4) Cluster Electron Transfer Series Christine A. Goddard, Jeffrey R. Long, and R. H. Holm pp 4347 - 4354; DOI: 10.1021/ic960052i |
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Palladium-Catalyzed Coupling of Ethynylated p-Carborane Derivatives: Synthesis and Structural Characterization of Modular Ethynylated p-Carborane Molecules Wei Jiang, David E. Harwell, Mark D. Mortimer, Carolyn B. Knobler, and M. Frederick Hawthorne pp 4355 - 4359; DOI: 10.1021/ic951574l |
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Stepwise Construction of Polynuclear Complexes of Rhodium and Iridium Assisted by Benzimidazole-2-thiol. NMR and X-ray Diffraction Studies Cristina Tejel, B. Eva Villarroya, Miguel A. Ciriano, Luis A. Oro, Maurizio Lanfranchi, Antonio Tiripicchio, and Marisa Tiripicchio-Camellini pp 4360 - 4368; DOI: 10.1021/ic960046m |
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Hypothetical C60 Metal-Cluster Fullerides and General Aspects of Tetrahedral Cluster Bonding Norman Goldberg and Roald Hoffmann pp 4369 - 4377; DOI: 10.1021/ic951588r |
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Reaction of Ketones with 1,4-Diaza-1,3-diene Zirconium and Hafnium Complexes: First Example of a 1,3-Dipolar Cycloaddition Reaction of 1,4-Diaza-1,3-diene Complexes of Early Transition Metals Joachim Scholz and and Helmar Görls pp 4378 - 4382; DOI: 10.1021/ic950513k |
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Synthesis and Structure of the Ruthenium(II) Complexes [(-C5Me5)Ru(NO)(bipy)]2+ and [(-C5Me5)Ru(NO)(dppz)]2+. DNA Cleavage by an Organometallic dppz Complex (bipy = 2,2'-Bipyridine; dppz = Dipyrido[3,2-a:2',3'-c]phenazine) Thomas K. Schoch, John L. Hubbard, Christopher R. Zoch, Geun-Bae Yi, and Morten S rliepp 4383 - 4390; DOI: 10.1021/ic950743z |
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Five- and Six-Coordinate 2-Methyl-2-propanethiolato Complexes of Zirconium(IV): Synthesis and Structures of [Li(DME)3][Zr(SCMe3)5] and [(THF)Li]2Zr(SCMe3)6 Hiroyuki Kawaguchi, Kazuyuki Tatsumi, and Roger E. Cramer pp 4391 - 4395; DOI: 10.1021/ic951211l |
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Synthesis, Characterization, and Reactivity of Dicationic Dihydrogen Complexes of Osmium D. Michael Heinekey and Thomas A. Luther pp 4396 - 4399; DOI: 10.1021/ic951427n |
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Isolation of a Bismuth Chloride-Iron Carbonyl Adduct: Synthesis and Structural Characterization of [PhCH2NMe3]2[Bi2Cl4(-Cl)2{-Fe(CO)4}] Jeffrey R. Eveland, Kenton H. Whitmire, and Jean-Yves Saillard pp 4400 - 4405; DOI: 10.1021/ic951262i |
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The Reversible Insertion Reaction of Carbon Dioxide with the W(CO)5OH- Anion. Isolation and Characterization of the Resulting Bicarbonate Complex [PPN][W(CO)5O2COH] Donald J. Darensbourg, Monica L. Meckfessel Jones, and Joseph H. Reibenspies pp 4406 - 4413; DOI: 10.1021/ic9516525 |
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Metal Binding of Polyalcohols. 4. Structure and Magnetism of the Hexanuclear, 6-Oxo-Centered [OFe6(H-3thme)3(OCH3)3Cl6]2- (thme = 1,1,1-Tris(hydroxymethyl)ethane) Andrea Cornia, Dante Gatteschi, Kaspar Hegetschweiler, Lorenza Hausherr-Primo, and Volker Gramlich pp 4414 - 4419; DOI: 10.1021/ic960025s |
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Extensively Conjugated Dianionic Tetrathiooxalate-Bridged Copper(II) Complexes for Synthetic Metals Anthony E. Pullen, Stephan Zeltner, Ruth-Maria Olk, Eberhard Hoyer, Khalil A. Abboud, and John R. Reynolds pp 4420 - 4426; DOI: 10.1021/ic9601605 |
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Molecule-Based Magnets: Ferro- and Antiferromagnetic Interactions in Copper(II)-Polyorganosiloxanolate Clusters Eva Rentschler, Dante Gatteschi, Andrea Cornia, Antonio C. Fabretti, Anne-Laure Barra, Olga I. Shchegolikhina, and Alexandr A. Zhdanov pp 4427 - 4431; DOI: 10.1021/ic951317g |
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Self-Assembly of Ribbons and Frameworks Containing Large Channels Based upon Methylene-Bridged Dithio-, Diseleno-, and Ditelluroethers Jane R. Black, Neil R. Champness, William Levason, and Gillian Reid pp 4432 - 4438; DOI: 10.1021/ic9600543 |
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Modeling the Formation of Molybdenum Oxides from Alkoxides: Crystal Structures of [Mo4O4Cl4(2-OEt)4(HOEt)2(3-O)2] and [PPN]+[Et3NH]+[Cl2(O)Mo(2-O)2Mo(O)Cl2]2- Christian Limberg, Anthony J. Downs, Alexander J. Blake and, and Simon Parsons pp 4439 - 4448; DOI: 10.1021/ic951468j |
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Rational Design of a Novel Intercalation System. Layer-Gap Control of Crystalline Coordination Polymers, {[Cu(CA)(H2O)m](G)}n (m = 2, G = 2,5-Dimethylpyrazine and Phenazine; m = 1, G = 1,2,3,4,6,7,8,9-Octahydrophenazine) Satoshi Kawata, Susumu Kitagawa, Hitoshi Kumagai, Chihiro Kudo, Hiroe Kamesaki, Tetsuya Ishiyama, Rieko Suzuki, Mitsuru Kondo, and Motomi Katada pp 4449 - 4461; DOI: 10.1021/ic9603520 |
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Structural, Spectroscopic, and Magnetochemical Characterization of the Trinuclear Vanadium(III) Carboxylates [V3O(O2CR)6L3](ClO4) (R = Various Groups; L = Pyridine, 4-Picoline, 3,5-Lutidine) Stephanie L. Castro, William E. Streib, Jui-Sui Sun, and George Christou pp 4462 - 4468; DOI: 10.1021/ic9602153 |
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Copper(II/I) Complexes of a Hexakis(bipyridyl)cyclotriveratrylene Ligand: A Redox-Induced Conformational Switch Jennifer A. Wytko, Corinne Boudon, Jean Weiss, and Maurice Gross pp 4469 - 4477; DOI: 10.1021/ic9516626 |
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A New Donor Atom System [(SNN)(S)] for the Synthesis of Neutral Oxotechnetium(V) Mixed-Ligand Complexes M. S. Papadopoulos, M. Pelecanou, I. C. Pirmettis, D. M. Spyriounis, C. P. Raptopoulou, A. Terzis, C. I. Stassinopoulou, and E. Chiotellis pp 4478 - 4483; DOI: 10.1021/ic9513649 |
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Synthesis and Characterization of Rhenium(V) Oxo Complexes with a New Thiol-Amide-Thiourea Ligand System. X-ray Crystal Structure of [1-Phenyl-3-[2-((2-thioacetyl)amino)ethyl]thioureato]oxorhenium(V) Malgorzata Lipowska, Lory Hansen, Andrew Taylor, Jr., and Luigi G. Marzilli pp 4484 - 4489; DOI: 10.1021/ic951449+ |
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1H and 113Cd NMR Investigations of Cd2+ and Zn2+ Binding Sites on Serum Albumin: Competition with Ca2+, Ni2+, Cu2+, and Zn2+ Peter J. Sadler and John H. Viles pp 4490 - 4496; DOI: 10.1021/ic951005d |
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Crystal and Molecular Structure of the [6-Deoxy-6-[(2-(4-imidazolyl)ethyl)amino]- cyclomaltoheptaose]copper(II) Ternary Complex with L-Tryptophanate. Role of Weak Forces in the Chiral Recognition Process Assisted by a Metallocyclodextrin Raffaele P. Bonomo, Benedetto Di Blasio, Giuseppe Maccarrone, Vincenzo Pavone, Carlo Pedone, Enrico Rizzarelli, Michele Saviano, and Graziella Vecchio pp 4497 - 4504; DOI: 10.1021/ic951605c |
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A New Family of Nonstoichiometric Layered Rare-Earth Tin Antimonides, RESnxSb2 (RE = La, Ce, Pr, Nd, Sm): Crystal Structure of LaSn0.75Sb2 Michael J. Ferguson, Ryan W. Hushagen, and Arthur Mar pp 4505 - 4512; DOI: 10.1021/ic9602254 |
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A Tetranuclear Ruthenium(II) Complex Containing both Electron-Rich and Electron-Poor Bridging Ligands. Absorption Spectrum, Luminescence, Redox Behavior, and Intercomponent Energy Transfer Scolastica Serroni, Sebastiano Campagna, Gianfranco Denti, Tia E. Keyes, and Johannes G. Vos pp 4513 - 4518; DOI: 10.1021/ic950086a |
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Reactions of Singlet Oxygen with Organometallic Compounds. 4. Photooxidation of Cationic Iridium(I) and Rhodium(I) Complexes with Weakly Bonded Ligands Matthias Selke, Lisa Rosenberg, Jared M. Salvo, and Christopher S. Foote pp 4519 - 4522; DOI: 10.1021/ic960056n |
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Synthesis and Structure of Fe(TIM)(CNBPh3)2: TIM = 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene. Conversion of BPh4- into CNBPh3- Patrick I. Amrhein, Alan J. Lough, and Robert H. Morris pp 4523 - 4525; DOI: 10.1021/ic960201x |
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An Organometallic Methodology Affording Dinuclear Copper(I) Complexes Euro Solari, Mario Latronico, Philippe Blech, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli pp 4526 - 4528; DOI: 10.1021/ic960072k |
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Formation of Explosive Chlorine-Nitrogen Compounds during the Reaction of Ammonium Compounds with Chlorine M. Knothe and W. Hasenpusch pp 4529 - 4530; DOI: 10.1021/ic951503m |
Issue 16
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Solid State Dynamics of Fe3(CO)12 Revisited Fernande Grandjean and Gary J. Long pp 4532 - 4533; DOI: 10.1021/ic960248i |
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[Fe2(Sb2S6)(CO)6]2+: A Cationic Group 15/16 Metal Cluster Greg W. Drake, George L. Schimek, and Joseph W. Kolis pp 4534 - 4535; DOI: 10.1021/ic9603619 |
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Interaction of Trimethylamine and closo-1,6-C2B7H9. Evidence for an "Open" Cage C2B7H9/Amine Adduct Martin Diaz, Jojo Jaballas, Dan Tran, Hans Lee, Joachin Arias, and Thomas Onak pp 4536 - 4540; DOI: 10.1021/ic960254e |
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Synthesis of Carboranyl Amino Acids, Hydantoins, and Barbiturates Iwona M. Wyzlic, Werner Tjarks, Albert H. Soloway, Douglas J. Perkins, Minerva Burgos, and Kevin P. O'Reilly pp 4541 - 4547; DOI: 10.1021/ic9511229 |
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Mixed Sandwich Carborane/Thiamacrocycle Compounds. Synthesis and Characterization of 1-Ph-3,3,3-[9]aneS3-3-S,S',S''-3,1,2-closo-RuC2B9H10 and 1,2-Ph2-3,3,3-[9]aneS3-3-S,S',S''-3,1,2-pseudocloso-RuC2B9H9 Alan J. Welch and and Andrew S. Weller pp 4548 - 4554; DOI: 10.1021/ic9601899 |
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Electrochemical Synthesis of [NEt4]2[enH]2[Ge2Se6] and [NEt4]4[Sn4Se10] Chang-Woo Park, Michael A. Pell, and James A. Ibers pp 4555 - 4558; DOI: 10.1021/ic9514859 |
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Synthesis and Characterization of Two Group 15 Selenometalates: [NEt4][BiSe2] and [Ge(en)3][enH][SbSe4] Michael A. Pell and James A. Ibers pp 4559 - 4562; DOI: 10.1021/ic960181z |
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Stereoselective Synthesis of 1,5,9-Triphosphacyclododecane and Tertiary Derivatives Peter G. Edwards, James S. Fleming, and Sudantha S. Liyanage pp 4563 - 4568; DOI: 10.1021/ic960322x |
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Photodissociation of Bis(S-benzyl-1,2-diphenyl-1,2-ethylenedithiolato)metal (Ni, Pd, Pt) Complexes Shin-ichi Ohkoshi, Yasunori Ohba, Masamoto Iwaizumi, Seigo Yamauchi, Miharu Ohkoshi-Ohtani, Keiichi Tokuhisa, Masatsugu Kajitani, Takeo Akiyama, and Akira Sugimori pp 4569 - 4574; DOI: 10.1021/ic951235s |
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trans-Chromophore-Quencher Complexes Based on Ruthenium(II) Benjamin J. Coe, Duane A. Friesen, David W. Thompson, and Thomas J. Meyer pp 4575 - 4584; DOI: 10.1021/ic9515463 |
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Spectroelectrochemistry and Dimerization Equilibria of Chloro(terpyridine)platinum(II). Nature of the Reduced Complexes Michael G. Hill, James A. Bailey, Vincent M. Miskowski, and Harry B. Gray pp 4585 - 4590; DOI: 10.1021/ic960137j |
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Small Azaparacyclophanes as Potential Selective Scavengers of Mercury. Crystal Structure of the Complex Hg2(L1)Cl4 (L1 = 16,17,19,20-Tetramethyl-2,6,9,13-tetraaza[14]paracyclophane) Enrique García-España, Julio Latorre, Santiago V. Luis, Juan F. Miravet, Pedro E. Pozuelo, José A. Ramírez, and Conxa Soriano pp 4591 - 4596; DOI: 10.1021/ic951615d |
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Anion Binding of Inorganic Phosphates by the Hexaaza Macrocyclic Ligand 3,6,9,17,20,23-Hexaazatricyclo[23.3.1.111,15]triaconta-1(29),11(30),12,14,25,27-hexaene David A. Nation, Joseph Reibenspies, and Arthur E. Martell pp 4597 - 4603; DOI: 10.1021/ic9513090 |
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Characterization of Lanthanide(III) DOTP Complexes: Thermodynamics, Protonation, and Coordination to Alkali Metal Ions A. D. Sherry, J. Ren, J. Huskens, E. Brücher, É. Tóth, C. F. C. G. Geraldes, M. M. C. A. Castro, and W. P. Cacheris pp 4604 - 4612; DOI: 10.1021/ic9600590 |
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Kinetics and Mechanism of the Oxidation of HSO3- by O2. 2. The Manganese(II)-Catalyzed Reaction Robert E. Connick and and Yi-Xue Zhang pp 4613 - 4621; DOI: 10.1021/ic951141i |
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Anomalies in the Kinetics of Substitution in [Os(NH3)5H2O]3+ Vassiliki G. Poulopoulou, Masashi Takahashi, Masuo Takeda, Tai Hasegawa, and Henry Taube pp 4622 - 4628; DOI: 10.1021/ic951537u |
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Kinetic Studies on the Hydrazine and Phenylhydrazine Reductions of the Escherichia coli R2 Subunit of Ribonucleotide Reductase Joo-Yeon Han, Jannie C. Swarts, and A. Geoffrey Sykes pp 4629 - 4634; DOI: 10.1021/ic9515012 |
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Synthesis, Structure, and Reactivity of Clusters Containing the [Mo2O2(-E)2]2+ (E = O, S) Core and Coordinated [Fe2S2(CO)6]2- Units Daniel E. Barber, Robert F. Bryan, Michal Sabat, Kurethara S. Bose, and Bruce A. Averill pp 4635 - 4642; DOI: 10.1021/ic951124t |
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Ruthenium Phthalocyanine and Its Reaction with Dioxygen: Synthesis, Structure, Magnetism, and Electrical Conductivity Properties of the Cofacially Assembled Ruthenoxane Aggregate of Formula HO-[(Pc)RuO]n-H (Average n = 11) A. Capobianchi, G. Pennesi, A. M. Paoletti, G. Rossi, R. Caminiti, C. Sadun, and C. Ercolani pp 4643 - 4648; DOI: 10.1021/ic9516673 |
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F430 Model Chemistry. A Reexamination of the [1,4,7,10,13-Pentaazacyclohexadecane-14,16-dionato(2-)]nickel(II)-Induced Formation of Methane from Methyl Coenzyme-M Zhong Zhang, Jeffrey L. Petersen, and Alan M. Stolzenberg pp 4649 - 4655; DOI: 10.1021/ic960263n |
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Near-IR FT-Raman Spectroscopy of Methyl-B12 and Other Cobalamins and of Imidazole and Imidazolate Methylcobinamide Derivatives in Aqueous Solution James M. Puckett, Jr., Mark B. Mitchell, Shun Hirota, and Luigi G. Marzilli pp 4656 - 4662; DOI: 10.1021/ic960259b |
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Combined NMR and Molecular Mechanics Study of the Isomers Formed in the Reaction of Dichloro(1,4-diazacycloheptane)platinum(II) with the Dinucleotide d(GpG) Trevor W. Hambley, Edwina C. H. Ling, and Barbara A. Messerle pp 4663 - 4668; DOI: 10.1021/ic951489d |
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La15Ge9Z. Interstitial Derivatives with an Ordered Superstructure of the Mn5Si3 Structure Type. Property Trends in a Series of Homologous Intermetallic Phases Arnold M. Guloy and John D. Corbett pp 4669 - 4675; DOI: 10.1021/ic9515158 |
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Intersystem Crossing Dynamics in the Iron(III) Spin-Crossover Compounds [Fe(acpa)2]PF6 and [Fe(Sal2tr)]PF6 Sabine Schenker, Andreas Hauser, and Raylene M. Dyson pp 4676 - 4682; DOI: 10.1021/ic960010u |
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Electronic Structure, Bonding, and Electrical Properties of MoNiP8 Miquel Llunell, Santiago Alvarez, Pere Alemany, and Roald Hoffmann pp 4683 - 4689; DOI: 10.1021/ic9601955 |
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Pentaphosphole: An Aromatic Ring with a Planar 3-Phosphorus László Nyulászi pp 4690 - 4693; DOI: 10.1021/ic9601246 |
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Calculation of Redox Potentials and pKa Values of Hydrated Transition Metal Cations by a Combined Density Functional and Continuum Dielectric Theory Jian Li, Cindy L. Fisher, Jun L. Chen, Donald Bashford, and Louis Noodleman pp 4694 - 4702; DOI: 10.1021/ic951428f |
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Synthesis, Structure, and Reactivity of [(dfepe)Pt(-H)]2. An Unusual Example of Conformational Polymorphism Byron L. Bennett and Dean M. Roddick pp 4703 - 4707; DOI: 10.1021/ic960126q |
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BaZn2(HAs2O7)AsO4: A Novel Barium Zinc Arsenate Containing Zn4O16 Clusters and Hydrogen Diarsenate Groups Nei-Yih Fan and Sue-Lein Wang pp 4708 - 4712; DOI: 10.1021/ic951655h |
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Molecular Structure of Dimethyldichlorotitanium(IV) by Gas-Phase Electron Diffraction, IR and NMR Spectroscopies, and Density Functional Theory Calculations. Unexpected Distortion from Tetrahedral Coordination Geometry G. Sean McGrady and, Anthony J. Downs, Donald C. McKean, Arne Haaland, Wolfgang Scherer, Hans-Peter Verne, and Hans Vidar Volden pp 4713 - 4718; DOI: 10.1021/ic960177n |
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Crystal Structure and Magnetism of (BEDT-TTF)2MCl4 (BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene; M = Ga, Fe) Mohamedally Kurmoo, Peter Day, Philippe Guionneau, George Bravic, Daniel Chasseau, Laurent Ducasse, Margaret L. Allan, Ian D. Marsden, and Richard H. Friend pp 4719 - 4726; DOI: 10.1021/ic951456y |
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Structural and Spectroscopic Characterization of Ditungsten Halide Compounds Kathryn M. Carlson-Day, Judith L. Eglin, Chun Lin, Tong Ren, Edward J. Valente, and Jeffrey D. Zubkowski pp 4727 - 4732; DOI: 10.1021/ic951617y |
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Preparation and Characterization of Bis[(-acetato)halo(-bis(diphenylphosphino)amine)molybdenum(II)] Complexes Deirdre I. Arnold, F. Albert Cotton, and Fritz E. Kühn pp 4733 - 4737; DOI: 10.1021/ic9514758 |
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Further Studies of the Isomeric 1,2,7- and 1,3,6-Re2Cl5(PMe3)3 Compounds F. Albert Cotton and and Evgeny V. Dikarev pp 4738 - 4742; DOI: 10.1021/ic951473n |
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Direct Conversion of -Substituted Ketones to Metallo-1,2-enedithiolates John K. Hsu, Cecilia J. Bonangelino, Sharada P. Kaiwar, Christine M. Boggs, James C. Fettinger, and Robert S. Pilato pp 4743 - 4751; DOI: 10.1021/ic9602052 |
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Copper(I) Arenethiolates with Intramolecular Coordination and the Formation of Mixed Organo(arenethiolato)copper(I) Aggregates. X-ray Structures of Trimeric [Cu(SC6H4NMe2-2)]3, Nonameric [Cu(S-1-C10H6NMe2-8)]9, and Hexanuclear [Cu3(S-1-C10H6NMe2-8)2(CCtBu)]2 Maurits D. Janssen, Johannes G. Donkervoort, Sofia B. van Berlekom, Anthony L. Spek, David M. Grove, and Gerard van Koten pp 4752 - 4763; DOI: 10.1021/ic951664q |
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Cyanide-Bridged Heterobimetallic Complexes of the Group 6 Metal Carbonyls and Copper(I). X-ray Structures of (CO)5MCNCu(PPh3)3 (M = Cr, W) Derivatives Donald J. Darensbourg, Jeffrey C. Yoder, Matthew W. Holtcamp, Kevin K. Klausmeyer, and Joseph H. Reibenspies pp 4764 - 4769; DOI: 10.1021/ic9510627 |
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The Nitrosyl Ligand and the Rhenium-Triflate Bond in Rhenium(I) Complexes Dario Veghini and Heinz Berke pp 4770 - 4778; DOI: 10.1021/ic9510829 |
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Ruthenium(II) Charge-Transfer Sensitizers Containing 4,4'-Dicarboxy-2,2'-bipyridine. Synthesis, Properties, and Bonding Mode of Coordinated Thio- and Selenocyanates Oliver Kohle, Stefan Ruile, and Michael Grätzel pp 4779 - 4787; DOI: 10.1021/ic9515665 |
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Electron Energy Level Transitions in Bis(phthalocyaninato)titanium(IV) Examined by UV-Visible, Near-IR, EELS, and XPS Spectra Marisa Scrocco, Anna Maria Paoletti, and Claudio Ercolani pp 4788 - 4790; DOI: 10.1021/ic950967h |
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Does Diisooxocyan (OCN-NCO) Exist? Axel Schulz and Thomas M. Klapötke pp 4791 - 4793; DOI: 10.1021/ic960049z |
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Activation of the Carbon -Site in Nonlinear Pseudohalides by Coordination. Crystal, Molecular, and Electronic Structure of a Bis{bis(methoxycarbimido)aminato}copper(II) Complex Roman Bo a, Mária Hvastijová, Jozef Ko íek, and Marián Valkopp 4794 - 4797; DOI: 10.1021/ic950422n |
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A Simple and Efficient Approach to a Rigid Diphosphine Ligand Containing Two Phosphorus and Three Carbon Stereogenic Centers by Means of a Palladium Complex Promoted Asymmetric Diels-Alder Reaction S. Selvaratnam, K. F. Mok, Pak-Hing Leung, Andrew J. P. White, and David J. Williams pp 4798 - 4800; DOI: 10.1021/ic951545a |
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Synthesis and Reactivities of (Arylsulfonyl)amido Complexes of Ruthenium(II) Wa-Hung Leung, Man-Ching Wu, Joyce L. C. Chim, and Wing-Tak Wong pp 4801 - 4803; DOI: 10.1021/ic9513806 |
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Targeting of Pallada- and Platinacycles to the N-((tert-Butyloxy)carbonyl)-L-methionine p-Nitrophenyl Ester for Promotion of the Ester Cleavage Elena V. Krooglyak, Gregory M. Kazankov, Sergei A. Kurzeev, Vladimir A. Polyakov, Anatole N. Semenov, and Alexander D. Ryabov pp 4804 - 4806; DOI: 10.1021/ic951180u |
Issue 17
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Unprecedented Influence of the Acid Medium in the Synthesis of Mo3M'S4 Cubane-like Clusters: Preparation of [Mo3PbS4(H2O)9+x]4+ Michael Brorson, Claus J. H. Jacobsen, Hans K. M. Helgesen, and Iver Schmidt pp 4808 - 4809; DOI: 10.1021/ic960197p |
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Synthesis and Characterization of [Mo2O5]2+-Bridged Complexes Containing Cofacially-Oriented, Catechol-Functionalized Macrocyclic and SALPHEN Ligands Steven M. Malinak and Dimitri Coucouvanis pp 4810 - 4811; DOI: 10.1021/ic960407y |
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Monomeric and Trimeric Manganese(III) Complexes of 2-Hydroxy-5,10,15,20-tetraphenylporphyrin. Synthesis and Characterization Jacek Wojaczy ski and Lechosaw Latos-Grayskipp 4812 - 4818; DOI: 10.1021/ic951663y |
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Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase. Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors Hua Holly Zhang, Adriano Filipponi, Andrea Di Cicco, Sonny C. Lee, Michael J. Scott, R. H. Holm, Britt Hedman, and Keith O. Hodgson pp 4819 - 4828; DOI: 10.1021/ic960021n |
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Aryloxo Derivatives of Phosphorus(V) Porphyrins. Synthesis, Spectroscopy, Electrochemistry, and Singlet State Properties T. Anita Rao and Bhaskar G. Maiya pp 4829 - 4836; DOI: 10.1021/ic9513200 |
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Steric and Electronic Effects, Enantiospecificity, and Reactive Orientation in DNA Binding/Cleaving by Substituted Derivatives of [SalenMnIII]+ Dennis J. Gravert and John H. Griffin pp 4837 - 4847; DOI: 10.1021/ic960196x |
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Assembly of Carbohydrates on a Nickel(II) Center by Utilizing N-Glycosidic Bond Formation with Tris(2-aminoethyl)amine (tren). Syntheses and Characterization of [Ni{N-(aldosyl)-tren}(H2O)]2+, [Ni{N,N'-bis(aldosyl)-tren}]2+ and [Ni{N,N',N''-tris(aldosyl)-tren}]2+ Tomoaki Tanase, Mayumi Doi, Reiko Nouchi, Masako Kato, Yutaka Sato, Katsuaki Ishida, Kimiko Kobayashi, Tosio Sakurai, Yasuhiro Yamamoto, and Shigenobu Yano pp 4848 - 4857; DOI: 10.1021/ic960012e |
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(1,3-Dimethyluracil-5-yl)mercury(II): Preparative, Structural, and NMR Spectroscopic Studies of an Analog of CH3HgII Félix Zamora, Michal Sabat, and Bernhard Lippert pp 4858 - 4864; DOI: 10.1021/ic960278l |
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Oxidative Addition of the Dithiobis(formamidinium) Cation to Platinum(II) Chloro Am(m)ine Compounds: Studies on Structure, Spectroscopic Properties, Reactivity, and Cytotoxicity of a New Class of Platinum(IV) Complexes Exhibiting S-Thiourea Coordination Ulrich Bierbach, Trevor W. Hambley, John D. Roberts, and Nicholas Farrell pp 4865 - 4872; DOI: 10.1021/ic960314g |
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EPR Studies of Oxo-Molybdenum(V) Complexes with Sulfur Donor Ligands: Implications for the Molybdenum Center of Sulfite Oxidase Ish K. Dhawan and John H. Enemark pp 4873 - 4882; DOI: 10.1021/ic9605276 |
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Cyclometalated Complexes of Palladium(II) and Platinum(II): cis-Configured Homoleptic and Heteroleptic Compounds with Aromatic CN Ligands Philippe Jolliet, Michel Gianini, Alex von Zelewsky, Gérald Bernardinelli, and Helen Stoeckli-Evans pp 4883 - 4888; DOI: 10.1021/ic951466z |
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Square Planar (SP-4) and Octahedral (OC-6) Complexes of Platinum(II) and -(IV) with Predetermined Chirality at the Metal Center Michel Gianini, Andrea Forster, Paul Haag, Alex von Zelewsky, and Helen Stoeckli-Evans pp 4889 - 4895; DOI: 10.1021/ic960313o |
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1H NMR, EPR, UV-Vis, and Electrochemical Studies of Imidazole Complexes of Ru(III). Crystal Structures of cis-[(Im)2(NH3)4RuIII]Br3 and [(1MeIm)6RuII]Cl2·2H2O M. J. Clarke, V. M. Bailey, P. E. Doan, C. D. Hiller, K. J. LaChance-Galang, H. Daghlian, S. Mandal, C. M. Bastos, and D. Lang pp 4896 - 4903; DOI: 10.1021/ic960355c |
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Syntheses of Cationic, Six-Coordinate Cadmium(II) Complexes Containing Tris(pyrazolyl)methane Ligands. Influence of Charge on Cadmium-113 NMR Chemical Shifts Daniel L. Reger, James E. Collins, Sheila M. Myers, Arnold L. Rheingold, and Louise M. Liable-Sands pp 4904 - 4909; DOI: 10.1021/ic951554j |
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Imido Complexes Derived from the Reactions of Niobium and Tantalum Pentachlorides with Primary Amines: Relevance to the Chemical Vapor Deposition of Metal Nitride Films Kumudini C. Jayaratne, Glenn P. A. Yap, Brian S. Haggerty, Arnold L. Rheingold, and Charles H. Winter pp 4910 - 4920; DOI: 10.1021/ic960178f |
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Theoretical Study of Electronic Structures and Spectra of Chalcogenido Complexes of Molybdenum, trans-Mo(Q)2(PH3)4 (Q = O, S, Se, Te) F. Albert Cotton and and Xuejun Feng pp 4921 - 4925; DOI: 10.1021/ic951261q |
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Reactivity of trans-[PtX2(ketoxime)2] Complexes toward m-Chloroperoxybenzoic Acid: An Efficient Route to Coordinated Nitrosoalkanes and Solvent Dependence of the Reaction Vadim Yu. Kukushkin, David Tudela, Youlia A. Izotova, Vitaly K. Belsky, and Adam I. Stash pp 4926 - 4931; DOI: 10.1021/ic9600691 |
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New Metal Oxamates as Precursors of Low-Dimensional Heterobimetallics Mohammed Fettouhi, Lahcène Ouahab, Ali Boukhari, Olivier Cador, Corine Mathonière, and Olivier Kahn pp 4932 - 4937; DOI: 10.1021/ic960174a |
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A Ferromagnetic Interaction between Cu2+ Centers through a [CrO4]2- Bridge: Crystal Structures and Magnetic Properties of [{Cu(acpa)}2(-MO4)] (M = Cr, Mo) (Hacpa = N-(1-Acetyl-2-propyridene)(2-pyridylmethyl)amine) Hiroki Oshio, Toshihiko Kikuchi, and Tasuku Ito pp 4938 - 4941; DOI: 10.1021/ic960204+ |
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Synthesis and X-ray Powder Structures of Two Lamellar Copper Arylenebis(phosphonates) Damodara M. Poojary, Baolong Zhang, Paul Bellinghausen, and Abraham Clearfield pp 4942 - 4949; DOI: 10.1021/ic960319d |
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Hydrothermal Syntheses and Structural Characterization of Layered Vanadium Oxides Incorporating Organic Cations: -, -(H3N(CH2)2NH3)[V4O10] and -, -(H2N(C2H4)2NH2)[V4O10] Yiping Zhang, Robert C. Haushalter, and Abraham Clearfield pp 4950 - 4956; DOI: 10.1021/ic951237c |
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NMR Characterization of the Na3AlP3O9N and Na2Mg2P3O9N Nitridophosphates: Location of the (NaAl)/Mg2 Substitution Dominique Massiot, Roland Conanec, Walter Feldmann, Roger Marchand, and Yves Laurent pp 4957 - 4960; DOI: 10.1021/ic960164+ |
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"Swollen" Macrocycles: Palladium(II)-Directed Template Syntheses of Pendant-Arm 14-, 16-, and 18-Membered Macrocycles Monica Rossignoli, Christine C. Allen, Trevor W. Hambley, Geoffrey A. Lawrance, and Marcel Maeder pp 4961 - 4966; DOI: 10.1021/ic951628r |
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Synthesis, Characterization, and Crystal Structure of a (-Oxo)bis(-acetato)diiron(III) Complex with a Dinucleating Hexapyridine Ligand, 1,2-Bis[2-(bis(2-pyridyl)methyl)-6-pyridyl]ethane. The First Example of a Discrete (-Oxo)bis(-acetato)diiron(III) Complex with a Dinucleating Ligand Masahito Kodera, Hisashi Shimakoshi, Masato Nishimura, Hisashi Okawa, Seiichiro Iijima, and Koji Kano pp 4967 - 4973; DOI: 10.1021/ic9600994 |
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Manganese(II/II/II) and Manganese(III/II/III) Trinuclear Compounds. Structure and Solid and Solution Behavior Vasilis Tangoulis, Dora A. Malamatari, Kali Soulti, Voula Stergiou, Catherine P. Raptopoulou, Aris Terzis, Themistoklis A. Kabanos, and Dimitris P. Kessissoglou pp 4974 - 4983; DOI: 10.1021/ic960183j |
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Variable Coordination and Conformation of the 3-Cyano-2,4-pentanedionato Anion in a Mixed-Ligand Binuclear Copper(II) Chelate Chris Tsiamis, Leandros C. Tzavellas, Anagnostis Stergiou, and Vasileia Anesti pp 4984 - 4988; DOI: 10.1021/ic951263a |
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A Coordination Polymer of Nickel(II) Based on a Pentadentate N, S, and O Donor Ligand Dawn C. Goodman, Patrick J. Farmer, Marcetta Y. Darensbourg, and Joseph H. Reibenspies pp 4989 - 4994; DOI: 10.1021/ic9601044 |
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Azidotris(trifluoromethyl)germane, (CF3)3GeN3: Spectroscopic Characterization and Density Functional Computations Thomas M. Klapötke and Axel Schulz pp 4995 - 4998; DOI: 10.1021/ic960364l |
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Synthesis, Reactivity, and Structural Characterization of the Nonclassical [MTe7]n- Anions (M = Ag, Au, n = 3; M = Hg, n = 2) Donna M. Smith, Lisa C. Roof, Mohammad A. Ansari, Jonathan M. McConnachie, John C. Bollinger, Michael A. Pell, Robert J. Salm, and James A. Ibers pp 4999 - 5006; DOI: 10.1021/ic951668v |
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Preparation and Characterization of Halogen-Boron-Phosphorus Compounds. X-ray Crystal Structures of X3B·P(SiMe3)3 and [X2BP(SiMe3)2]2 (X = Cl, Br) Michael S. Lube, Richard L. Wells, and Peter S. White pp 5007 - 5014; DOI: 10.1021/ic9516368 |
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Synthesis and Structural Characterization of Tantalum(IV) Amido Compounds Seigi Suh and David M. Hoffman pp 5015 - 5018; DOI: 10.1021/ic960264f |
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Theoretical Modeling of Water Exchange on [Pd(H2O)4]2+, [Pt(H2O)4]2+, and trans-[PtCl2(H2O)2] Robert J. Deeth and Lars I. Elding pp 5019 - 5026; DOI: 10.1021/ic950335v |
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Trans or (Unusual) Cis Geometry in d2 Octahedral Dioxo Complexes. A DFT Study Isabelle Demachy and Yves Jean pp 5027 - 5031; DOI: 10.1021/ic951523o |
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Solvent Cage Effects in Organocobalt Corrinoid Chemistry: Thermal Homolysis of - and -(Cyanomethyl)cobinamides Kenneth L. Brown and and Lanxin Zhou pp 5032 - 5039; DOI: 10.1021/ic9603666 |
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Electronic Structures of Copper(I) and Silver(I) -Diketonate Complexes Xiaorong Li, G. Michael Bancroft, Richard J. Puddephatt, Zheng Yuan, and K. H. Tan pp 5040 - 5049; DOI: 10.1021/ic9509701 |
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Copper Fluoride Luminescence during UV Photofragmentation of Bis(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)copper(II) in the Gas Phase David S. Talaga and Jeffrey I. Zink pp 5050 - 5054; DOI: 10.1021/ic9515362 |
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Structural and Kinetic Studies of Spin Crossover in an Iron(II) Complex with a Novel Tripodal Ligand Ala H. R. Al-Obaidi, Kenneth B. Jensen, John J. McGarvey, Hans Toftlund, Bent Jensen, Steven E. J. Bell, and Jonathan G. Carroll pp 5055 - 5060; DOI: 10.1021/ic960228g |
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On the Existence of a Pyramidality Effect in d8···d8 Contacts. Theoretical Study and Structural Correlation Gabriel Aullón, Pere Alemany, and Santiago Alvarez pp 5061 - 5067; DOI: 10.1021/ic951423i |
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The Dinitramide Anion, N(NO2)2- Karl O. Christe, William W. Wilson, Mark A. Petrie, Harvey H. Michels, Jeffrey C. Bottaro, and Richard Gilardi pp 5068 - 5071; DOI: 10.1021/ic9601697 |
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Partial Quenching of Parametrical Tetragonality of a Chromium(III) Complex by Pressure Tuning C. E. Schäffer, J. M. Lang, and H. G. Drickamer pp 5072 - 5079; DOI: 10.1021/ic9515620 |
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Electronic Structure and Substitution and Redox Reactivity of Imidazolate-Bridged Complexes of Pentacyanoferrate and Pentaammineruthenium Alejandro R. Parise, Luis M. Baraldo, and José A. Olabe pp 5080 - 5086; DOI: 10.1021/ic951558o |
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Rates of Dimethyl Sulfoxide Exchange in Monoalkyl Cationic Platinum(II) Complexes Containing Nitrogen Bidentate Ligands. A Proton NMR Study Raffaello Romeo, Luigi Monsù Scolaro, Nicola Nastasi, and Giuseppe Arena pp 5087 - 5096; DOI: 10.1021/ic960107g |
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Syntheses, Structures, and Properties of New Aluminum(III)-Molybdenum(IV) Heterometallic Clusters M2Al2[Mo3O4(O2CR)8]2·nRCO2H (M = Na, K; R = Me, Et; n = 0, 1) Li Xu, Zaofei Li, and Jinshun Huang pp 5097 - 5100; DOI: 10.1021/ic951542y |
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Synthesis of Mono-B-alkylcyclotriborazanes. Structural Characterization of 2-(PhC2H4)B3N3H11 Andrew E. Wille, Patrick J. Carroll, and Larry G. Sneddon pp 5101 - 5103; DOI: 10.1021/ic960299f |
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Resonance Raman Spectrum of the Phenanthroline Anion: Implications on Electron Delocalization in the MLCT Excited State of Ru(phen)32+ Claudia Turró, Young C. Chung, Nicholas Leventis, Mark E. Kuchenmeister, Peter J. Wagner, and George E. Leroi pp 5104 - 5106; DOI: 10.1021/ic9601091 |
Issue 18
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Heterobimetallic -Nitrido Complexes Formed by Incomplete Nitrogen Atom Transfer Reactions between Nitridorhenium(V) and Chlorochromium(III) Porphyrins Cheng Tong and Lawrence A. Bottomley pp 5108 - 5109; DOI: 10.1021/ic9601450 |
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The First (-Oxo)diferric Chain Complex: Structure and Magnetic Properties of [Fe2(tren)2(mtm)O]n(CF3SO3)nCln Chang Seop Hong, Jinkwon Kim, Nam Hwi Hur, and Youngkyu Do pp 5110 - 5111; DOI: 10.1021/ic9602097 |
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Oxidation of Tricarbonylmolybdacarborane. 1. First Examples of Oxomolybda(VI)carboranes Jae-Hak Kim, Eunkee Hong, Jinkwon Kim, and Youngkyu Do pp 5112 - 5113; DOI: 10.1021/ic960223j |
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Crystallographic and Dynamic NMR Evidence for Organometallic Fragments Pivoting on a Molecular Oxide Surface M. Abe, K. Isobe, K. Kida, and A. Yagasaki pp 5114 - 5115; DOI: 10.1021/ic960297v |
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The First Series of Luminescent (4-Chalcogenido)silver(I) Clusters Vivian Wing-Wah Yam, Kenneth Kam-Wing Lo, Chun-Ru Wang, and Kung-Kai Cheung pp 5116 - 5117; DOI: 10.1021/ic960374m |
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Synthesis of Tungsten (1-Pyridinio)imido Complexes: Facile N-N Bond Cleavage To Form Pyridine from Coordinated Dinitrogen Youichi Ishii, Shin'ichi Tokunaga, Hidetake Seino, and Masanobu Hidai pp 5118 - 5119; DOI: 10.1021/ic960632f |
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Ligand-Bridged Heterobimetallic Polymers: Silver(I)-Benzothiadiazole-Nickel Porphyrin Cation-Benzothiadiazole Arrays M. W. Renner, K. M. Barkigia, D. Melamed, K. M. Smith, and J. Fajer pp 5120 - 5121; DOI: 10.1021/ic960673b |
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Kinetics of CO Addition to Ni(cyclam)+ in Aqueous Solution Craig A. Kelly, Quinto G. Mulazzani, Elliott L. Blinn, and Michael A. J. Rodgers pp 5122 - 5126; DOI: 10.1021/ic951527t |
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Properties of the Nickel(III) Complex with 1,4,8,11-Tetraazacyclotetradecane-1,4,8,11-tetraacetate in Aqueous Solution Mahammad Ali, Israel Zilbermann, Haim Cohen, Alexander I. Shames, and Dan Meyerstein pp 5127 - 5131; DOI: 10.1021/ic950871n |
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Synthesis and Structure of [6,6'-Bi(5,7-dimethyl-1,4,8,11-tetraazacyclotetradecane)]dinickel(II) Triflate and Its Catalytic Activity for Photochemical CO2 Reduction Katsura Mochizuki, Shinobu Manaka, Ikuyo Takeda, and Takeshi Kondo pp 5132 - 5136; DOI: 10.1021/ic960208e |
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Formation and Dissociation Kinetics of the Magnesium(II) Complex of 1,4,7-Triazacyclononane-1,4,7-tris(methylenemethylphosphinic acid) Jurriaan Huskens and A. Dean Sherry pp 5137 - 5143; DOI: 10.1021/ic9602299 |
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Spectral and Electrochemical Properties of the Diastereoisomeric Forms of Azobis(2-pyridine)-Bridged Diruthenium Species Laurence S. Kelso, David A. Reitsma, and F. Richard Keene pp 5144 - 5153; DOI: 10.1021/ic9600893 |
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Oxidation and Protonation of Transition Metal Hydrides: Role of an Added Base as Proton Shuttle and Nature of Protonated Water in Acetonitrile E. Alessandra Quadrelli, Heinz-Bernhard Kraatz, and Rinaldo Poli pp 5154 - 5162; DOI: 10.1021/ic960394o |
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Mechanistic Studies on Halo-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Palladium(II) Complexes of Tris(2-(diphenylphosphino)ethyl)phosphine with Trimethyl Phosphite in Chloroform at Various Temperatures and Pressures Sen-ichi Aizawa, Takashi Iida, and Shigenobu Funahashi pp 5163 - 5167; DOI: 10.1021/ic9601596 |
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Electron Transfer from Aliphatic Radicals to Ring-Substituted Pyridine N-Oxides and Their Cobalt-Ammine Complexes in Aqueous Solution A. Bakac, V. Butkovi , J. H. Espenson, J. Lovri, and M. Orhanovipp 5168 - 5172; DOI: 10.1021/ic960111s |
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Peptide-Based Trihydroxamates as Models for Desferrioxamines. Iron(III)-Holding Properties of Linear and Cyclic N-Hydroxy Peptides with an L-ALANYL-L-alanyl-N-hydroxy--alanyl Sequence Yukihiro Hara and Masayasu Akiyama pp 5173 - 5180; DOI: 10.1021/ic951338a |
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Cyclometalated Complexes of Platinum and Palladium with N-(4-Chlorophenyl)--benzoylbenzylideneamine. In Vitro Cytostatic Activity, DNA Modification, and Interstrand Cross-Link Studies Carmen Navarro-Ranninger, Isabel López-Solera, Víctor M. González, José M. Pérez, Amparo Alvarez-Valdés, Avelino Martín, Paul R. Raithby, José R. Masaguer, and Carlos Alonso pp 5181 - 5187; DOI: 10.1021/ic960050y |
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Models of the Cytochromes. Redox Properties and Thermodynamic Stabilities of Complexes of "Hindered" Iron(III) and Iron(II) Tetraphenylporphyrinates with Substituted Pyridines and Imidazoles Marlys J. M. Nesset, Nikolai V. Shokhirev, Paul D. Enemark, Simone E. Jacobson, and F. Ann Walker pp 5188 - 5200; DOI: 10.1021/ic960491h |
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Ascorbate Oxidation Catalyzed by Bis(histidine)copper(II) Marina Scarpa, Fabio Vianello, Luca Signor, Lucio Zennaro, and Adelio Rigo pp 5201 - 5206; DOI: 10.1021/ic9600644 |
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Ab Initio Study of the Mechanism of the Binding of Triplet O2 to Hemocyanin Fernando Bernardi, Andrea Bottoni, Rita Casadio, Piero Fariselli, and Adelio Rigo pp 5207 - 5212; DOI: 10.1021/ic960102j |
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Synthesis, Characterization, and Stability of Manganese(II) C-Substituted 1,4,7,10,13-Pentaazacyclopentadecane Complexes Exhibiting Superoxide Dismutase Activity Dennis P. Riley, Susan L. Henke, Patrick J. Lennon, Randy H. Weiss, William L. Neumann, Willie J. Rivers, Jr., Karl W. Aston, Kirby R. Sample, Hayat Rahman, Chaur-Sun Ling, Jeng-Jong Shieh, Daryle H. Busch, and Witold Szulbinski pp 5213 - 5231; DOI: 10.1021/ic960262v |
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- and -Bonding Modes of Pyridine and Imidazole Type Ligands in the Transition States of Their Reactions with [CoIII(protoporphyrin IX dimethyl ester)(MeO)(MeOH)] in Methanol Smiljko A perger and Biserka Cetina- imekpp 5232 - 5236; DOI: 10.1021/ic951506z |
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Structural Distortion of the Vanadyltetraphenylporphine Anion Radical Probed by Resonance Raman Spectroelectrochemistry Ching-Yao Lin and Thomas G. Spiro pp 5237 - 5243; DOI: 10.1021/ic960381a |
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Dinuclear Pd(I)-Pd(I) and Pt(II)···Pt(II) Complexes Supported by Tridentate Pyphos Ligands (Pyphos = 6-(Diphenylphosphino)-2-pyridonate) Kazushi Mashima, Mitsuhiro Tanaka, Kazuhide Tani, Hiroshi Nakano, and Akira Nakamura pp 5244 - 5248; DOI: 10.1021/ic951658u |
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Dirhenium Polyhydrides Containing Bridging 2-Mercaptoquinoline Ligands Andrea L. Ondracek, Wengan Wu, Phillip E. Fanwick, and Richard A. Walton pp 5249 - 5253; DOI: 10.1021/ic960187o |
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Synthesis and X-ray Powder Structures of Covalently Pillared Lamellar Zinc Bis(phosphonates) Damodara M. Poojary, Baolong Zhang, Paul Bellinghausen, and Abraham Clearfield pp 5254 - 5263; DOI: 10.1021/ic960029x |
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Synthesis, Crystal Structures, and Proton Conductivity of Two Linear-Chain Uranyl Phenylphosphonates Daniel Grohol, M. A. Subramanian, Damodara M. Poojary, and Abraham Clearfield pp 5264 - 5271; DOI: 10.1021/ic960332y |
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Zr9Co2P4 and Zr9Ni2P4: A New 3D Structure Type, Consisting of Edge- and Vertex-Condensed Zr6 Octahedra Holger Kleinke and Hugo F. Franzen pp 5272 - 5277; DOI: 10.1021/ic960214a |
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A Novel Copper(I/II) Oxophosphate Chloride with a Quasi-One-Dimensional 4-Oxo-Bridged Copper(II) Chain. Crystal Structure and Magnetic Properties of [Na2CuII3(PO4)2][CuIOCl] Kristen M. S. Etheredge and and Shiou-Jyh Hwu pp 5278 - 5282; DOI: 10.1021/ic9516471 |
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Syntheses and Crystal Structures of New Ternary Selenides: Rb3Yb7Se12 and CsEr3Se5 Sung-Jin Kim and, So-Jung Park, Hoseop Yun, and Junghwan Do pp 5283 - 5289; DOI: 10.1021/ic960227o |
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Dinuclear Oxomolybdenum(V) Complexes Showing Strong Interactions across Diphenol Bridging Ligands: Syntheses, Structures, Electrochemical Properties, and EPR Spectroscopic Properties V  n Ân Ung, David A. Bardwell, John C. Jeffery, John P. Maher, Jon A. McCleverty, Michael D. Ward, and Andrew Williamsonpp 5290 - 5299; DOI: 10.1021/ic951634n |
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EPR, Electronic, and Vibrational Spectra of the CuCl64- Anion in [tris(2-aminoethyl)amineH4]2[CuCl6]Cl4·2H2O and Crystal Structure of the Complex Mingyi Wei, Roger D. Willett, and K. W. Hipps pp 5300 - 5303; DOI: 10.1021/ic960202p |
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Ligand Substitution Effect on Electronic Structure and Optical Properties of Nickel Porphyrazines Liqun Guo, D. E. Ellis, B. M. Hoffman, and Y. Ishikawa pp 5304 - 5312; DOI: 10.1021/ic960005q |
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Thermal Evolution of Chromium(III) Ions in Hydrotalcite-like Compounds F. M. Labajos and V. Rives pp 5313 - 5318; DOI: 10.1021/ic951648t |
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An Acetylacetonate-Based Semiconductor-Sensitizer Linkage Todd A. Heimer, Samuel T. D'Arcangelis, Fereshteh Farzad, Jeremy M. Stipkala, and Gerald J. Meyer pp 5319 - 5324; DOI: 10.1021/ic960419j |
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A Novel Bis(azatitanatrane) with a T-Shaped Nitrido Bridging Ligand: Synthesis and Structure of {[N(CH2CH2N-i-Pr)3Ti]2(3-N)Na(THF)} Zhibang Duan and John G. Verkade pp 5325 - 5327; DOI: 10.1021/ic9606385 |
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Unusual One-Dimensional Ladder Structures Containing Divalent Europium and the Tetracyanometalates Ni(CN)42- and Pt(CN)42- David W. Knoeppel and Sheldon G. Shore pp 5328 - 5334; DOI: 10.1021/ic960337v |
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One-Step Preparation of Dimethyl Sulfide Substituted Icosahedral Boranes: The Crystal and Molecular Structures of 1,7-(SMe2)2B12H10, 1,12-(SMe2)2B12H10, and [SMe3][B12H11(SMe2)]·MeCN Ewan J. M. Hamilton, Glenn T. Jordan IV, Edward A. Meyers, and Sheldon G. Shore pp 5335 - 5341; DOI: 10.1021/ic960433w |
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An Improved Synthesis of arachno-4-CB8H14 and Crystallographic and ab Initio/IGLO/NMR Investigations of the Solid State and Solution Structures of the arachno-4-CB8H13- Anion Andrew E. Wille, Jaromir Ple ek, Josef Holub, Bohumil tíbr, Patrick J. Carroll, and Larry G. Sneddonpp 5342 - 5346; DOI: 10.1021/ic9602409 |
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Polarized Optical Spectra, Transition Line Strengths, and the Electronic Energy-Level Structure of Eu(dpa)33- Complexes in Single Crystals of Hexagonal Na3[Yb0.95Eu0.05(dpa)3]·NaClO4·10H2O Todd A. Hopkins, James P. Bolender, David H. Metcalf, and F. S. Richardson pp 5347 - 5355; DOI: 10.1021/ic951524g |
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Polarized Optical Absorption and Emission Spectra and the Electronic Energy-Level Structure of Tb(dpa)33- Complexes in Na3[Yb0.95Tb0.05(dpa)3]·NaClO4·10H2O Todd A. Hopkins, James P. Bolender, David H. Metcalf, and F. S. Richardson pp 5356 - 5362; DOI: 10.1021/ic9515259 |
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Solid State Synthesis, Crystal Structure, Decomposition Reactions, and Optical Nonlinearity of a Twin-Nest-Shaped Cluster Compound, [Et4N]4[Mo2O2S6Cu6I6] Hongwei Hou, Deliang Long, Xinquan Xin, Xiaoxing Huang, Beisheng Kang, Ping Ge, Wei Ji, and Shu Shi pp 5363 - 5367; DOI: 10.1021/ic950991v |
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Oxygen Atom Transfer, Sulfur Atom Transfer, and Correlated Electron-Nucleophile Transfer Reactions of Oxo- and Thiomolybdenum(IV) Complexes: Synthesis of Oxothiomolybdenum(VI) and (Hydroxo)oxomolybdenum(V) Species Charles G. Young, Les J. Laughlin, Silvano Colmanet, and Sergio D. B. Scrofani pp 5368 - 5377; DOI: 10.1021/ic960403t |
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Strain Energies of Silicon Rings and Clusters Ming Zhao and Benjamin M. Gimarc pp 5378 - 5386; DOI: 10.1021/ic9512439 |
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A Density Functional Study of Trigold Oxonium Complexes and of Their Dimerization Sai-Cheong Chung, Sven Krüger, Hubert Schmidbaur, and Notker Rösch pp 5387 - 5392; DOI: 10.1021/ic960418r |
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A Hexanuclear Ruthenium Carbonyl Cluster Containing both 3-Nitrene and 5-Nitrido Ligands Kenneth Ka Hong Lee and Wing Tak Wong pp 5393 - 5395; DOI: 10.1021/ic960161x |
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Synthesis and Characterization of a New Binuclear Copper(II) Complex with an Oxygen Bridge and a B-N Bonded Ligand H. L. Shyu, H. H. Wei, G. H. Lee, and Yu Wang pp 5396 - 5398; DOI: 10.1021/ic960333q |
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Synthesis and X-ray Structure of the Monocarbon Rhodacarborane Complex [RhBr(PPh3)(5-7-NH2But-8-CH2CO2Et-7- CB10H9)] John C. Jeffery, Paul A. Jelliss, Vyacheslav N. Lebedev, and F. Gordon A. Stone pp 5399 - 5402; DOI: 10.1021/ic960450l |
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Reaction of 1,2-Bis(2-selenoxo-3-methyl-4-imidazolinyl)ethane (ebis) with TCNQ: Crystal Structure and Characterization of the Mixed-Valence Compound [2(ebis)2+·ebis]·2[(TCNQ)32-] Francesco Bigoli, Paola Deplano, Francesco A. Devillanova, Alberto Girlando, Vito Lippolis, Maria Laura Mercuri, Maria Angela Pellinghelli, and Emanuele F. Trogu pp 5403 - 5406; DOI: 10.1021/ic960141v |
Issue 19
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A Homoleptic Thioether Coordination Sphere That Supports Nickel(I) Pinghua Ge, Charles G. Riordan, Glenn P. A. Yap, and Arnold L. Rheingold pp 5408 - 5409; DOI: 10.1021/ic960515k |
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Synthesis and Characterization of a Copper Complex of [Et2N(N2O2)]- Stabilized with Respect to NO Release in Aqueous Solution Jamie L. Schneider, Victor G. Young, Jr., and William B. Tolman pp 5410 - 5411; DOI: 10.1021/ic960414m |
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Synthesis of Amine Derivatives of the Polyhedral Borane Anion [B20H18]4- Emil M. Georgiev, Kenneth Shelly, Debra A. Feakes, Jeremy Kuniyoshi, Solomon Romano, and M. Frederick Hawthorne pp 5412 - 5416; DOI: 10.1021/ic960171y |
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Carboracycles: Macrocyclic Compounds Composed of Carborane Icosahedra Linked by Organic Bridging Groups Wei Jiang, Igor T. Chizhevsky, Mark D. Mortimer, Weilin Chen, Carolyn B. Knobler, S. E. Johnson, F. A. Gomez, and M. Frederick Hawthorne pp 5417 - 5426; DOI: 10.1021/ic960354k |
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Reversible Insertion of Methyl Isothiocyanate into Copper(I) Aryloxides Christina Wycliff, Ashoka G. Samuelson, and Munirathinam Nethaji pp 5427 - 5434; DOI: 10.1021/ic9516424 |
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Utility of Arylamido Ligands in Yttrium and Lanthanide Chemistry William J. Evans, Mohammad A. Ansari, Joseph W. Ziller, and Saeed I. Khan pp 5435 - 5444; DOI: 10.1021/ic951499e |
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Diastereoselective Synthesis, Spectroscopy, and Electrochemistry of Ruthenium(II) Complexes of Substituted Pyrazolylpyridine Ligands Yue Luo, Pierre G. Potvin, Yu-Hong Tse, and A. B. P. Lever pp 5445 - 5452; DOI: 10.1021/ic950694q |
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Synthesis of Tungsten Carbonyl and Nitrosyl Complexes of Monodentate and Chelating Aryl-N-sulfonylphosphoramides, the First Members of a New Class of Electron-Withdrawing Phosphine Ligands. Comparative IR and 13C and 31P NMR Study of Related Phosphorus Complexes William H. Hersh, Ping Xu, Bing Wang, Jong Won Yom, and Cheslan K. Simpson pp 5453 - 5459; DOI: 10.1021/ic960256z |
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Nucleophilic Addition of CH, NH, and OH Bonds to the Phosphadiazonium Cation and Interpretation of 31P Chemical Shifts at Dicoordinate Phosphorus Centers Neil Burford, T. Stanley Cameron, Jason A. C. Clyburne, Klaus Eichele, Katherine N. Robertson, Sergey Sereda, Roderick E. Wasylishen, and W. Alex Whitla pp 5460 - 5467; DOI: 10.1021/ic960131u |
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Bonding Properties of a Novel Inorganometallic Complex, Ru(SnPh3)2(CO)2(iPr-DAB) (iPr-DAB = N,N'-Diisopropyl-1,4-diaza-1,3-butadiene), and its Stable Radical-Anion, Studied by UV-Vis, IR, and EPR Spectroscopy, (Spectro-) Electrochemistry, and Density Functional Calculations Maxim P. Aarnts, Maikel P. Wilms, Karin Peelen, Jan Fraanje, Kees Goubitz, Franti ek Hartl, Derk J. Stufkens, Evert Jan Baerends, and Antonín Vlek, Jr.pp 5468 - 5477; DOI: 10.1021/ic960042h |
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Syntheses, Spectra, and Structures of (Diphosphine)platinum(II) Carbonate Complexes Mark A. Andrews, George L. Gould, Wim T. Klooster, Kristina S. Koenig, and Eric J. Voss pp 5478 - 5483; DOI: 10.1021/ic9603159 |
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Reactions of the Dirhenium(II) Complexes Re2X4(dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 10.1 Synthesis and Characterization of the Complex [Re2Br3(-dppm)2(CO)2(CNXyl)]O3SCF3 and Several Isomeric Forms of [Re2Br3(-dppm)2(CO)(CNXyl)2]Y (Y = PF6, O3SCF3) Wengan Wu, Phillip E. Fanwick, and Richard A. Walton pp 5484 - 5491; DOI: 10.1021/ic960270b |
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Coordination Compounds of Schiff-Base Ligands Derived from Diaminomaleonitrile (DMN): Mononuclear, Dinuclear, and Macrocyclic Derivatives Mark J. MacLachlan, Murray K. Park, and Laurence K. Thompson pp 5492 - 5499; DOI: 10.1021/ic960237p |
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Synthesis, Structure, and Magnetic Properties of Transition Metal Complexes of the Nitroxide 2,5-Dihydro-4,5,5-trimethyl-2,2-bis(2-pyridyl)imidazole-1-oxyl Frank Hintermaier, Karlheinz Sünkel, Leonid B. Volodarsky, and Wolfgang Beck pp 5500 - 5503; DOI: 10.1021/ic951345z |
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Reactions of [Et4N]3[Sb{Fe(CO)4}4] with Alkyl Halides and Dihalides: Formation of the Alkyl- and the Dialkylantimony-Iron Carbonyl Complexes Minghuey Shieh, Chii-maw Sheu, Li-Fang Ho, Jiann-Jang Cherng, Li-Fing Jang, Chuen-Her Ueng, Shie-Ming Peng and, and Gene-Hsiang Lee pp 5504 - 5508; DOI: 10.1021/ic9513393 |
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A Search for / Equilibria in Chiral Rhenium Imine Complexes of the Formula [(5-C5H5)Re(NO)(PPh3)(N(H)=C(CF3)X)]+TfO-: Investigation of Electronic Effects upon the Binding Mode Gene A. Stark and J. A. Gladysz pp 5509 - 5513; DOI: 10.1021/ic960302v |
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Multinuclear NMR Study of the Structure and Intramolecular Dynamics of (2-Acetone phenylhydrazonato)tetrafluorooxotungsten(VI) Sergei G. Sakharov, Yuri A. Buslaev, and Ivan Tká pp 5514 - 5519; DOI: 10.1021/ic950330y |
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Electron Transfer in Frozen Media Pingyun Chen and Thomas J. Meyer pp 5520 - 5524; DOI: 10.1021/ic9512845 |
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Interconversion and Reactivity of Two Heterometallic Tin-Containing Cuboidal Clusters from [Mo3S4(H2O)9]4+: X-ray Structure of the Single Cube with an Mo3SnS4 Core Jane E. Varey, Gert J. Lamprecht, Vladimir P. Fedin, Alvin Holder, William Clegg, Mark R. J. Elsegood, and A. Geoffrey Sykes pp 5525 - 5530; DOI: 10.1021/ic951659m |
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Aqueous Solution Chemistry of the Mo3PdS4 Cube: Substitution Reactions and the Double to Single Cube Interconversion Induced by CO, Two Phosphines, Cl-, Br-, and NCS- David M. Saysell, Gert J. Lamprecht, James Darkwa, and A. Geoffrey Sykes pp 5531 - 5535; DOI: 10.1021/ic951595f |
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Preparation and Properties of the Corner-Shared Double Cube [Mo6BiS8(H2O)18]8+ as a Derivative of [Mo3S4(H2O)9]4+ in Aqueous Acidic Solutions David M Saysell and A. Geoffrey Sykes pp 5536 - 5539; DOI: 10.1021/ic960292y |
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CO2 Fixation by Novel Copper(II) and Zinc(II) Macrocyclic Complexes. A Solution and Solid State Study Carla Bazzicalupi, Alessandro Bencini, Andrea Bencini, Antonio Bianchi, Federica Corana, Vieri Fusi, Claudia Giorgi, Paola Paoli, Piero Paoletti, Barbara Valtancoli, and Claudia Zanchini pp 5540 - 5548; DOI: 10.1021/ic9603262 |
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Stereochemical Nonrigidity and Geometrical Isomerism in Six-Coordinate Trigonal Prismatic Complexes: The Case of Asymmetric Molybdenum and Tungsten Tris(dithiolenes) Dimitris Argyropoulos, Christine-Anne Mitsopoulou, and Dimitris Katakis pp 5549 - 5554; DOI: 10.1021/ic960398t |
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Ligand Structural Effects on the Electrochemistry of Chromium(III) Amino Carboxylate Complexes Mathias Hecht, Franklin A. Schultz, and Bernd Speiser pp 5555 - 5563; DOI: 10.1021/ic960152o |
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Synthesis and Electrochemistry of Tetraphenylporphyrins Containing an Antimony-Carbon -Bond Karl M. Kadish, Marie Autret, Zhongping Ou, Kin-ya Akiba, Shuji Masumoto, Ryosuke Wada, and Yohsuke Yamamoto pp 5564 - 5569; DOI: 10.1021/ic951538m |
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Electrochemistry and Spectral Characterization of Oxidized and Reduced (TPPBrx)FeCl Where TPPBrx Is the Dianion of -Brominated-Pyrrole Tetraphenylporphyrin and x Varies from 0 to 8 Pietro Tagliatesta, Jun Li, Marie Autret, Eric Van Caemelbecke, Anne Villard, Francis D'Souza, and Karl M. Kadish pp 5570 - 5576; DOI: 10.1021/ic960148c |
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Synthesis, Characterization, and Electrochemistry of -Bonded Cobalt Corroles in High Oxidation States Stefan Will, Johann Lex, Emanuel Vogel, Victor A. Adamian, Eric Van Caemelbecke, and Karl M. Kadish pp 5577 - 5583; DOI: 10.1021/ic960484t |
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Coordination Chemistry of Low-Valent Rhenium Polypyridyl Complexes: Synthesis, Reactivity, and Electrochemistry Lisa E. Helberg, Stephen D. Orth, Michal Sabat, and W. Dean Harman pp 5584 - 5594; DOI: 10.1021/ic960001l |
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Solid State Dynamics of Tricarbonyl(-1,5-cyclohexadienylium)iron Tetrafluoroborate and Tricarbonyl(-1,5-cycloheptadienylium)iron Tetrafluoroborate Dermot F. Brougham, Patrick J. Barrie, Geoffrey E. Hawkes, Isaac Abrahams, Majid Motevalli, David A. Brown, and Gary J. Long pp 5595 - 5602; DOI: 10.1021/ic951573t |
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Structural Variability of the Vanadium-Organodiphosphonate System: Hydrothermal Syntheses and Structural Characterizations of One-Dimensional, Two-Dimensional, and Three-Dimensional Phases Grant Bonavia, Robert C. Haushalter, C. J. O'Connor, and Jon Zubieta pp 5603 - 5612; DOI: 10.1021/ic960224b |
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Synthetic Strategies To Obtain V-P-O Open Frameworks Containing Organic Species as Structural Directing Agents. Crystal Structure of the V(IV)-Fe(III) Bimetallic Phosphate [H3N(CH2)2NH3]2[H3N(CH2)2NH2][FeIII(H2O)2(VIVO)8(OH)4(HPO4)4(PO4)4]·4H2O Manuel Roca, M. Dolores Marcos, Pedro Amorós, Aurelio Beltrán-Porter, A. J. Edwards, and Daniel Beltrán-Porter pp 5613 - 5621; DOI: 10.1021/ic960218f |
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NbxRu6-xTe8, New Chevrel-Type Clusters Containing Niobium and Ruthenium Jörg Neuhausen, E. Wolfgang Finckh, and Wolfgang Tremel pp 5622 - 5626; DOI: 10.1021/ic9508379 |
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A Comparative Study of Two New Structure Types. Synthesis and Structural and Electronic Characterization of K(RE)P2Se6 (RE = Y, La, Ce, Pr, Gd) John H. Chen, Peter K. Dorhout, and J. E. Ostenson pp 5627 - 5633; DOI: 10.1021/ic9516121 |
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Synthesis, Characterization, and Bonding of Two New Heteropolychalcogenides: -CsCu(SxSe4-x) and CsCu(SxSe6-x) Casey C. Raymond and Peter K. Dorhout pp 5634 - 5641; DOI: 10.1021/ic9516370 |
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Solvation of Copper(II) Ions in Liquid Ammonia M. Valli, S. Matsuo, H. Wakita, T. Yamaguchi, and M. Nomura pp 5642 - 5645; DOI: 10.1021/ic960475k |
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The Co-CH3 Bond in Imine/Oxime B12 Models. Influence of the Orientation and Donor Properties of the trans Ligand As Assessed by FT-Raman Spectroscopy Shun Hirota, Suzette M. Polson, James M. Puckett, Jr., Scott J. Moore, Mark B. Mitchell, and Luigi G. Marzilli pp 5646 - 5653; DOI: 10.1021/ic9602613 |
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Mercury(II) Site-Selective Binding to a DNA Hairpin. Relationship of Sequence-Dependent Intra- and Interstrand Cross-Linking to the Hairpin-Duplex Conformational Transition Zsuzsanna Kuklenyik and Luigi G. Marzilli pp 5654 - 5662; DOI: 10.1021/ic960260a |
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Nordesferriferrithiocin. Comparative Coordination Chemistry of a Prospective Therapeutic Iron Chelating Agent Klaus Langemann, Daniel Heineke, Stefan Rupprecht, and Kenneth N. Raymond pp 5663 - 5673; DOI: 10.1021/ic9601854 |
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Alkoxo Bound Monooxo- and Dioxovanadium(V) Complexes: Synthesis, Characterization, X-ray Crystal Structures, and Solution Reactivity Studies Gebray Asgedom, Alavattam Sreedhara, Jussi Kivikoski, Jussi Valkonen, Erkki Kolehmainen, and Chebrolu P. Rao pp 5674 - 5683; DOI: 10.1021/ic960061r |
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Multifunctional Ligands. Phosphinimine-Substituted Cyanofluoroaromatics Including X-ray Molecular Structures of Three Representative Ligands 4,6-(CN)2C6F2-1,3-(N=PPh3)2, 4,6-(CN)2C6F2-1,3-(N=PPh2Me)2 and 4,6-(CN)2C6F2-1-(N=PPh3)-3-(N=PPh2Me). Formation of Rhodium(I) Complexes Jin Li, A. Alan Pinkerton, Daniel C. Finnen, Mattias Kummer, Anthony Martin, Frank Wiesemann, and Ronald G. Cavell pp 5684 - 5692; DOI: 10.1021/ic951463m |
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Polyoxometalate Derivatives with Multiple Organic Groups. 3. Synthesis and Structure of Bis(phenyltin) Bis(decatungstosilicate), [(PhSnOH2)2(-SiW10O36)2]10- Feibo Xin and Michael T. Pope pp 5693 - 5695; DOI: 10.1021/ic960101r |
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Aluminum Amides Derived from Metalation of N,N'-Bis(trimethylsilyl)ethylenediamine Michael G. Gardiner, George A. Koutsantonis, Stacey M. Lawrence, and Colin L. Raston pp 5696 - 5702; DOI: 10.1021/ic9603161 |
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Complexation of LnIII and CaII Cations with 3,4-Dicarboxyinulin and Model Compounds: Methyl 3,4-Dicarboxy--D-fructofuranoside and 3,4-Dicarboxynystose, As Studied by Multinuclear Magnetic Resonance Spectroscopy and Potentiometry Louise Johnson, Dorine L. Verraest, Arie C. Besemer, Herman van Bekkum, and Joop A. Peters pp 5703 - 5710; DOI: 10.1021/ic960103b |
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Binding Patterns in Single-Ligand Complexes of NH3, H2O, OH-, and F- with First Series Transition Metals Eric Magnusson and Nigel W. Moriarty pp 5711 - 5719; DOI: 10.1021/ic960288m |
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A Density Functional Study of Active Site Models for Xanthine Oxidase Mark R. Bray and Robert J. Deeth pp 5720 - 5724; DOI: 10.1021/ic960135z |
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Photolysis of (Diamine)bis(2,2'-bipyridine)ruthenium(II) Complexes Using On-Line Electrospray Mass Spectrometry Ryuichi Arakawa, Shin-ichi Mimura, Gen-etsu Matsubayashi, and Takekiyo Matsuo pp 5725 - 5729; DOI: 10.1021/ic960193k |
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Single-Crystal Raman Spectroscopy of the Rubidium Alums RbMIII(SO4)2·12H2O (MIII = Al, Ga, In, Ti, V, Cr, Fe) between 275 and 1200 cm-1: Correlation between the Electronic Structure of the Tervalent Cation and Structural Abnormalities Philip L. W. Tregenna-Piggott and Stephen P. Best pp 5730 - 5736; DOI: 10.1021/ic9602759 |
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Formation of Mono- and Multimanganese Cationic Species. Crystal Structure of [Mn4(-Cl)6(THF)12][SnCl5(THF)]2 Zofia Janas, Tadeusz Lis, and Piotr Sobota pp 5737 - 5739; DOI: 10.1021/ic951236k |
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Evidence for Platinum(II) Oxo Intermediates in Reactions of (Diphosphine)platinum(II) Carbonate Complexes Mark A. Andrews, George L. Gould, and Eric J. Voss pp 5740 - 5742; DOI: 10.1021/ic9601448 |
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Effect of Peripheral Substitution and Extended Conjugation on the Redox Potentials of Nickel Porphycenes Francis D'Souza, Pierre L. Boulas, Michael Kisters, Louis Sambrotta, Ally M. Aukauloo, Roger Guilard, and Karl M. Kadish pp 5743 - 5746; DOI: 10.1021/ic951640j |
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Spectral and Electrochemical Investigations on the "Tail-On" and "Tail-Off" Mechanism in Pyridine Covalently Bound Zinc(II) Porphyrins Francis D'Souza, Yi-Ying Hsieh, and G. R. Deviprasad pp 5747 - 5749; DOI: 10.1021/ic960041p |
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Methylation of Boron Vertices of the Cobalt Dicarbollide Anion Mark D. Mortimer, Carolyn B. Knobler, and M. Frederick Hawthorne pp 5750 - 5751; DOI: 10.1021/ic960353s |
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Synthesis and Characterization of a Novel Green Cobalt Corrinoid Kenneth L. Brown, Shifa Cheng, Jeffrey D. Zubkowski, and Edward J. Valente pp 5752 - 5752; DOI: 10.1021/ic960895+ |
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Dioxomolybdenum(VI) Complexes of Tripodal Nitrogen-Donor Ligands: Syntheses and Spectroscopic, Structural, and Electrochemical Studies, Including the Generation of EPR-Active Molybdenum(V) Species in Solution Zhiguang Xiao, Michael A. Bruck, Colleen Doyle, John H. Enemark, Carina Grittini, Robert W. Gable, Anthony G. Wedd, and Charles G. Young pp 5752 - 5752; DOI: 10.1021/ic961983x |
Issue 20
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Bismuth Alkoxides. The First Structurally-Characterized Bismuth-Transition Metal Heterobimetallic Alkoxide: [BiCl3OV(OC2H4OCH3)3]2 J. W. Pell, W. C. Davis, and H. C. zur Loye pp 5754 - 5755; DOI: 10.1021/ic9604122 |
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Organic-Soluble Cyclic and Cage Alkylaluminophosphates: X-ray Crystal Structure of [(tBu)2Al(2-O)2P(OSiMe3)2]2 Mark R. Mason, R. Mark Matthews, Mark S. Mashuta, and John F. Richardson pp 5756 - 5757; DOI: 10.1021/ic960619v |
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Efficient Stereospecific Syntheses of Chiral Ruthenium Dimers Frederick M. MacDonnell and Swamy Bodige pp 5758 - 5759; DOI: 10.1021/ic9605682 |
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Intriguing Coordination Behaviors of Aquo and Amine Ligands Bound to the Organoruthenium(II) Cation [Ru(6-C6H6)(bpop)]2+ (bpop = 2,2-Bis[4(R)-phenyl-1,3-oxazolon-2-yl]propane) Hideo Asano, Kyoshige Katayama, and Hideo Kurosawa pp 5760 - 5761; DOI: 10.1021/ic960410h |
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Absorption of Tungsten Carbonyl Anions into the Lipid Bilayer Membrane of Mouse Myeloma Cells Katja Nielsen, Wolfdieter A. Schenk, Michael Kriegmeier, Vladimir L. Sukhorukov, and Ulrich Zimmermann pp 5762 - 5763; DOI: 10.1021/ic960641o |
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Preparation and Characterization of Bis[dihalo(-bis(diphenylphosphino)amine)molybdenum(II)] Complexes Deirdre I. Arnold, F. Albert Cotton, and Fritz E. Kühn pp 5764 - 5769; DOI: 10.1021/ic960325+ |
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Synthesis, Structure, and Reactivity of Three-Coordinate Vanadium(III) Chalcogenolates and Vanadium(V) Chalcogenide Chalcogenolates Christopher P. Gerlach and John Arnold pp 5770 - 5780; DOI: 10.1021/ic960439l |
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Crystal Structure and Magnetic Susceptibility Study of Pyrrolidinium Trichlorocuprate(II) Mingyi Wei, Roger D. Willett, Daniel Teske, Kala Subbaraman, and John E. Drumheller pp 5781 - 5785; DOI: 10.1021/ic960057f |
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Synthesis and Crystal Structure of Two Members of a New Type of Layered Compound: Copper(II) Hydroxyphosphonates Stéphanie Drumel, Pascal Janvier, Martine Bujoli-Doeuff, and Bruno Bujoli pp 5786 - 5790; DOI: 10.1021/ic960411+ |
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Stoichiometry of K+- and CO32--Containing Apatites Prepared by the Hydrolysis of Octacalcium Phosphate Ilse Y. Pieters, Erna A. P. De Maeyer, and Ronald M. H. Verbeeck pp 5791 - 5797; DOI: 10.1021/ic960213i |
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Relationship between the Skew Angle and Interplanar Distance in Four Bis(phthalocyaninato)lanthanide(III) Tetrabutylammonium Salts ([NBun4][LnIIIPc2]; Ln = Nd, Gd, Ho, Lu) Naoto Koike, Hidehiro Uekusa, Yuji Ohashi, Chokto Harnoode, Fusao Kitamura, Takeo Ohsaka, and Koichi Tokuda pp 5798 - 5804; DOI: 10.1021/ic960158d |
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Electronic Structure of Aryl- and Alkylphosphines S. T. Howard, J. P. Foreman, and P. G. Edwards pp 5805 - 5812; DOI: 10.1021/ic951553r |
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Synthesis, Structure, Luminescence, and Raman-Determined Excited State Distortions of a Trinuclear Gold(I) Phosphine Thiolate Complex Stephen D. Hanna, Saeed I. Khan, and Jeffrey I. Zink pp 5813 - 5819; DOI: 10.1021/ic951313b |
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Synthesis and Structural Characterization of Lithium Thiolates: Dependence of Association and Aggregation on Donor Hapticity and Ligand Size and Synthesis of the First Trimeric Lithium Thiolate [Li(THF)SR]3 and the Solvent-Separated Ion Pair [Li(12-crown-4)2][SR] (R = 2,4,6-tBu3C6H2) Karin Ruhlandt-Senge, Ulrich Englich, Mathias O. Senge, and Scott Chadwick pp 5820 - 5827; DOI: 10.1021/ic960375e |
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Synthesis and Characterization of the Mixed-Valence Diamagnetic Two-Electron-Reduced Isopolytungstate [W10O32]6-. Evidence for an Asymmetric d-Electron Distribution over the Tungsten Sites Dean C. Duncan and and Craig L. Hill pp 5828 - 5835; DOI: 10.1021/ic960226w |
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Intramolecular Chalcogen-Nitrogen Interactions: Molecular and Electronic Structures of Geometrical Isomers of the Diazenes RSN=C(R')N=NC(R')=NSR Tristram Chivers, Ian Krouse, Masood Parvez, Ignacio Vargas-Baca, Tom Ziegler, and Peter Zoricak pp 5836 - 5842; DOI: 10.1021/ic960465j |
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Triphenylcyanoborate Complexes of Rhodium. A Nitrogen-15 NMR Study of [Rh(NCBPh3)(PPh3)3] and [Rh(CNBPh3)(PPh3)3] and Their Derivatives Laurence Carlton and and Rosemarie Weber pp 5843 - 5850; DOI: 10.1021/ic9601293 |
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Synthesis of Novel Macrocyclic Polyamines with a Pendant Phenol Group and Properties and Structures of Their Copper(II) Complexes Shourong Zhu, Fuping Kou, Huakuan Lin, Chunchen Lin, Meirong Lin, and Yunti Chen pp 5851 - 5859; DOI: 10.1021/ic951250x |
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The Mo(CO)3 Fragment as an Organometallic Protection Group in the Synthesis of Functionalized Tripodal Phosphine Ligands Philipp Stössel, Hermann A. Mayer, Cäcilia Maichle-Mössmer, Riad Fawzi, and Manfred Steimann pp 5860 - 5867; DOI: 10.1021/ic9602512 |
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Synthesis and Characterization of Novel Acyclic, Macrocyclic, and Calix[4]arene Ruthenium(II) Bipyridyl Receptor Molecules That Recognize and Sense Anions Fridrich Szemes, Dusan Hesek, Zheng Chen, Simon W. Dent, Michael G. B. Drew, Alistair J. Goulden, Andrew R. Graydon, Alan Grieve, Roger J. Mortimer, Trevor Wear, John S. Weightman, and Paul D. Beer pp 5868 - 5879; DOI: 10.1021/ic960318l |
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Macrocyclic Rhodium(III) Hydrides and a Monomeric Rhodium(II) Complex Andreja Bakac and Leonard M. Thomas pp 5880 - 5884; DOI: 10.1021/ic960300a |
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Structural and Resonance Raman Studies of an Oxygen-Evolving Catalyst. Crystal Structure of [(bpy)2(H2O)RuIIIORuIV(OH)(bpy)2](ClO4)4 Jon R. Schoonover, JinFeng Ni, Lee Roecker, Peter S. White, and Thomas J. Meyer pp 5885 - 5892; DOI: 10.1021/ic960348o |
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Intramolecular Electron Transfer in Pentaammineruthenium(III)-Modified Cobaltocytochrome c Ji Sun, Chang Su, and James F. Wishart pp 5893 - 5901; DOI: 10.1021/ic960715w |
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The Rubredoxin from Clostridium pasteurianum: Mutation of the Conserved Glycine Residues 10 and 43 to Alanine and Valine Mustafa Ayhan, Zhiguang Xiao, Megan J. Lavery, Amanda M. Hamer, Kerry W. Nugent, Sergio D. B. Scrofani, Mitchell Guss, and Anthony G. Wedd pp 5902 - 5911; DOI: 10.1021/ic951653x |
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Adenosylcobinamide, the Base-Free Analog of Coenzyme B12 (Adenosylcobalamin). 1.1 Probing the Role of the Axial 5,6-Dimethylbenzimidazole Base in Coenzyme B12 via Exogenous Axial Base Kassociation, H, and S Measurements plus a Critical Review of the Relevant Biochemical Literature Cheryl D. Garr, Jeanne M. Sirovatka, and Richard G. Finke pp 5912 - 5922; DOI: 10.1021/ic951272j |
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Kinetics and Mechanism of Nucleophilic Substitutions on Coordinated Polyenes and Polyenyls. 1. Reactions of Tertiary Phosphines with [Ru(5-C5H5)(4-C5H4O)(L)]CF3SO3 (L = CH3CN, Benzonitrile, Thiourea, Pyridine) Walter Simanko, Thomas Vallant, Kurt Mereiter, Roland Schmid, Karl Kirchner, John Coddington, and Scot Wherland pp 5923 - 5930; DOI: 10.1021/ic960383v |
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The Complex of Co(2,2,6,6-tetramethyl-3,5-heptanedionate)2 with 2,2'-Bipyridine. Its Formation in the Gas Phase and in Solution Pascal Chassotand and Franzpeter Emmenegger pp 5931 - 5934; DOI: 10.1021/ic9605130 |
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Formation of Peroxynitrite from the Nitrosation of Hydrogen Peroxide by an Oxygenated Nitric Oxide Solution Sara Goldstein and and Gidon Czapski pp 5935 - 5940; DOI: 10.1021/ic960438t |
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Structure-Reactivity Correlations for Complex Formation Reactions between Square-Planar Metal Centers and Thioethers Tiesheng Shi and Lars I. Elding pp 5941 - 5947; DOI: 10.1021/ic9603518 |
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Stepwise Reactions of TiCl4 and Ti(OiPr)Cl3 with 2-Propanol. Variable-Temperature NMR Studies and Crystal Structures of [TiCl2(OiPr)(HOiPr)(-Cl)]2 and [TiCl2(OiPr)(HOiPr)(-OiPr)]2 Yaw-Ting Wu, Yuh-Chou Ho, Chu-Chieh Lin, and Han-Mou Gau pp 5948 - 5952; DOI: 10.1021/ic960147k |
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Dipyrido[4,3-b;5,6-b]acridine Derivatives and Their Ruthenium(II) Complexes Chi-Ying Hung, Tie-Lin Wang, Youngchan Jang, Won Y. Kim, Russell H. Schmehl, and Randolph P. Thummel pp 5953 - 5956; DOI: 10.1021/ic960409i |
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Autoionization of SmI3 in Tetrahydrofuran. X-ray Crystal Structure of the Ionic Complex [SmI2(THF)5][SmI4(THF)2] Zuowei Xie, Ka-yue Chiu, Bomu Wu, and Thomas C. W. Mak pp 5957 - 5958; DOI: 10.1021/ic9604526 |
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Propeller Isomerism in Bis(trimesitylphosphine)gold(I), -silver(I), and -copper(I) Tetrafluoroborates Angela Bayler, Graham A. Bowmaker, and Hubert Schmidbaur pp 5959 - 5960; DOI: 10.1021/ic960421a |
Issue 21
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Electropolymerization of Macromers Containing Ruthenium(II) Polypridyl Complexes Robert M. Leasure, Toru Kajita, and Thomas J. Meyer pp 5962 - 5963; DOI: 10.1021/ic951246l |
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Anomalous Magnetic Properties of [K{Mn(3-MeO-salen)}2{Mn(CN)6}]. A Metamagnet Exhibiting a Strong Negative Magnetization (3-MeOsalen = N,N'-Ethylenebis(3-methoxysalicylideneaminato) Nazzareno Re, Emma Gallo, Carlo Floriani, Hitoshi Miyasaka, and Naohide Matsumoto pp 5964 - 5965; DOI: 10.1021/ic9605480 |
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Helical Antiferromagnetic Copper(II) Chains with a Collagen Structural Motif Kausik K. Nanda, Anthony W. Addison, Ekkehard Sinn, and Laurence K. Thompson pp 5966 - 5967; DOI: 10.1021/ic9607090 |
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Synthesis, Structure, and Characterization of the Hydrogen-Substituted Imido Complex TiCl2(NH)(OPPh3)2 Peggy J. McKarns, Glenn P. A. Yap, Arnold L. Rheingold, and Charles H. Winter pp 5968 - 5969; DOI: 10.1021/ic960595s |
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Catalytic Properties of Layered Double Hydroxides and Their Calcined Derivatives W. Kagunya, Z. Hassan, and W. Jones pp 5970 - 5974; DOI: 10.1021/ic960047e |
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Chemoselective Reactions of the Phosphino Enolate Li[Ph2PCH Jacques Andrieu, Pierre Braunstein, Antonio Tiripicchio, and Franco Ugozzoli pp 5975 - 5985; DOI: 10.1021/ic951412p |
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Reactivity of -Phosphino Enolate Complexes of Nickel(II) and Palladium(II) toward Electrophilic Metal Centers. Synthesis and Crystal Structures of the Bimetallic Palladium(II)-Gold(I) Complex [(dmba)Pd{Ph2PCH(AuPPh3)C(O)Ph}](BF4) and of the Nickel(II)-Cobalt(II) Paramagnetic Complex cis-[Ni{Ph2PCH Jacques Andrieu, Pierre Braunstein, Marc Drillon, Yves Dusausoy, Florent Ingold, Pierre Rabu, Antonio Tiripicchio, and Franco Ugozzoli pp 5986 - 5994; DOI: 10.1021/ic9513494 |
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Formation of Carbon-Carbon-Bonded Dimers in the Reduction of [CoIIsalophen] [salophen = N,N'-o-Phenylenebis(salicylideneaminato)]: Their Reactivity with Electrophiles To Form Co-C Bonds Stefania De Angelis, Euro Solari, Emma Gallo, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli pp 5995 - 6003; DOI: 10.1021/ic951661d |
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Magnetic Properties of a One-Dimensional Ferromagnet Containing a Mn(III)-NC-Fe(III) Linkage: Synthesis and Crystal Structure of a Chainlike [Mn(acacen)Fe(CN)6]n2n- Polyanion Nazzareno Re, Emma Gallo, Carlo Floriani, Hitoshi Miyasaka, and Naohide Matsumoto pp 6004 - 6008; DOI: 10.1021/ic960556g |
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Pentafluorophenyl Complexes of Platinum Containing Intramolecular Pt···H Hydrogen Bridging Interactions. Crystal Structures of [NBu4][Pt(C6F5)3(8-hydroxyquinaldine)] and [NBu4][Pt(C6F5)3(8-methylquinoline)] José María Casas, Larry R. Falvello, Juan Forniés, Antonio Martín, and Alan J. Welch pp 6009 - 6014; DOI: 10.1021/ic960118+ |
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Oxo Ligand Reactivity and Bonding in the Dinuclear W-Re Oxo-Acetylide Complex (5-C5Me5)W(O)Re(CO)4(-H)(CCPh) Hsiao-Ling Wu, Guey-Lin Lu, Yun Chi, Louis J. Farrugia, Shie-Ming Peng, and Gene-Hsiang Lee pp 6015 - 6020; DOI: 10.1021/ic9601394 |
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Disproportionation of [(py)(NH3)4RuIII] at the N7 of Guanine Nucleosides: Severing the N-Glycosidic Bond K. J. LaChance-Galang, M. Zhao, and M. J. Clarke pp 6021 - 6026; DOI: 10.1021/ic960798g |
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Tetrahydroquinolinyl Amido and Indolinyl Amido Complexes of Tantalum as Models for Substrate-Catalyst Adducts in Hydrodenitrogenation Catalysis Peter A. Fox, Steven D. Gray, Michael A. Bruck, and David E. Wigley pp 6027 - 6036; DOI: 10.1021/ic960298n |
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Effects of Zero-Point Energy Difference on Intramolecular Electron Transfer in Asymmetric Polyethyl-Substituted Biferrocenium Triiodides Teng-Yuan Dong, Po-Ju Lin, and Kuan-Jiuh Lin pp 6037 - 6044; DOI: 10.1021/ic950953b |
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CO-Induced Reductive Elimination of P(t-Bu)2H from the Platinum(II) Dinuclear Derivative Pt2[-P(t-Bu)2]2(H)2[P(t-Bu)2H]2, Affording Mononuclear Platinum(0) or Triangulo Triplatinum(I,I,II) Derivatives Piero Leoni, Silvia Manetti, Marco Pasquali, and Alberto Albinati pp 6045 - 6052; DOI: 10.1021/ic9602308 |
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Coordination Dynamics and Reactivity of Palladium(II) Complexes Containing the N-Thienylidene-L/D-methionine Methyl Ester Ligand Hubertus A. Ankersmit, Peter T. Witte, Huub Kooijman, Miles T. Lakin, Anthony L. Spek, Kees Goubitz, Kees Vrieze, and Gerard van Koten pp 6053 - 6063; DOI: 10.1021/ic951076c |
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Synthesis and Structures of (2,2-cis)-Dirhodium(II) Tetrakis[methyl 1-acyl-2-oxoimidazolidine-4(S)-carboxylates]. Chiral Catalysts for Highly Stereoselective Metal Carbene Transformations Michael P. Doyle, Qi-Lin Zhou, Conrad E. Raab, Gregory H. P. Roos, Stanley H. Simonsen, and Vincent Lynch pp 6064 - 6073; DOI: 10.1021/ic960249a |
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Synthesis and Characterization of Lithium, Zirconium, and Hafnium Derivatives of N-Isopropyl-2-(isopropylamino)troponiminate H. V. Rasika Dias, Wiechang Jin, and Ziyun Wang pp 6074 - 6079; DOI: 10.1021/ic9603823 |
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Synthesis of Layered MoOPO4·2H2O and Investigation of Its Intercalation Chemistry K. Kasthuri Rangan and J. Gopalakrishnan pp 6080 - 6085; DOI: 10.1021/ic960027c |
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[Cr(bipy)(C2O4)2]-: A Versatile Building Block for the Design of Heteropolymetallic Systems. Crystal Structures of [BaCr2(bipy)2(C2O4)4(H2O)]n·nH2O, [MnCr2(bipy)2(-C2O4)4]n, and [CoCr2(bipy)2(-C2O4)2(C2O4)2(H2O)2]·H2O Fernande D. Rochon, Robert Melanson, and Marius Andruh pp 6086 - 6092; DOI: 10.1021/ic951089q |
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Structures, Bonding, and Reactivity of M-S-M' (M and M' = Rh, W, and Cu) Groups in Higher-Nuclearity Heterometallic Sulfide Clusters Seiji Ogo, Takayoshi Suzuki, Yoshiki Ozawa, and Kiyoshi Isobe pp 6093 - 6101; DOI: 10.1021/ic9601807 |
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Photoelectron Spectra and Structures of Proazaphosphatranes László Nyulászi, Tamás Veszprémi, Bosco A. D'Sa, and John Verkade pp 6102 - 6107; DOI: 10.1021/ic960532+ |
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Intercalation Reactions of Layered Vanadyl Organophosphonates with Alkylamines P. Gendraud, M. E. de Roy, and J. P. Besse pp 6108 - 6112; DOI: 10.1021/ic960238h |
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Superacid Anions: Crystal and Molecular Structures of Oxonium Undecafluorodiantimonate(V), [H3O][Sb2F11], Cesium Fluorosulfate, CsSO3F, Cesium Hydrogen Bis(fluorosulfate), Cs[H(SO3F)2], Cesium Tetrakis(fluorosulfato)aurate(III), Cs[Au(SO3F)4], Cesium Hexakis(fluorosulfato)platinate(IV), Cs2[Pt(SO3F)6], and Cesium Hexakis(fluorosulfato)antimonate(V), Cs[Sb(SO3F)6] Dingliang Zhang, Steven J. Rettig, James Trotter, and Friedhelm Aubke pp 6113 - 6130; DOI: 10.1021/ic960525l |
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Structural Studies on the Ion-Exchanged Phases of a Porous Titanosilicate, Na2Ti2O3SiO4·2H2O Damodara M. Poojary, Anatoly I. Bortun, Lyudmila N. Bortun, and Abraham Clearfield pp 6131 - 6139; DOI: 10.1021/ic960378r |
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Structure, Stability, and Reactivity of Cationic Hydrogen Trioxides and Thermochemistry of their Neutral Analogs. A Fourier-Transform Ion Cyclotron Resonance Study Maurizio Speranza pp 6140 - 6151; DOI: 10.1021/ic960549s |
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Structures and Conformations of (Trifluoromethyl)thioacetic Acid, CF3C(O)SH, and Derivatives CF3C(O)SCH3 and CF3C(O)SCl Karina I. Gobbato, Carlos O. Della Védova, Hans-Georg Mack, and Heinz Oberhammer pp 6152 - 6157; DOI: 10.1021/ic960536e |
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Stable Analogs of the Uranyl Ion Containing the -N=U=N- Group Dean R. Brown and Robert G. Denning pp 6158 - 6163; DOI: 10.1021/ic951386v |
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Synthesis of Tin Oxide Precursors and Related Germanium and Lead Compounds Seigi Suh and David M. Hoffman pp 6164 - 6169; DOI: 10.1021/ic960293q |
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Existence of C,3-Me2-closo-1,2-C2B3H3 Refuted by the Ab Initio/IGLO, GIAO-MP2/NMR Method. Attempted Repetition of the Synthesis Matthias Hofmann, Mark A. Fox, Robert Greatrex, Paul von Ragué Schleyer, Joseph W. Bausch, and Robert E. Williams pp 6170 - 6178; DOI: 10.1021/ic960360g |
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Synthesis and Structures of Intramolecularly Base-Coordinated Aryl Group 15 Compounds Smuruthi Kamepalli, Claire J. Carmalt, Robert D. Culp, Alan H. Cowley, Richard A. Jones, and Nicholas C. Norman pp 6179 - 6183; DOI: 10.1021/ic960516c |
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Structural Evaluation and Solution Integrity of Alkali Metal Salt Complexes of the Manganese 12-Metallacrown-4 (12-MC-4) Structural Type Brian R. Gibney, Hsin Wang, Jeff W. Kampf, and Vincent L. Pecoraro pp 6184 - 6193; DOI: 10.1021/ic960371+ |
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Reduction of [Re(X)(CO)3(R'-DAB)] (X = Otf-, Br-; DAB = Diazabutadiene; R' = iPr, pTol, pAn) and [Re(R)(CO)3(iPr-DAB)] (R = Me, Et, Bz) Complexes: A Comparative (Spectro)electrochemical Study at Variable Temperatures Brenda D. Rossenaar, Franti ek Hartl, and Derk J. Stufkenspp 6194 - 6203; DOI: 10.1021/ic9600947 |
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Comparative Reactivity of the (Trimethylsilyl)phosphines (Me3Si)3-nPHn (n = 1,2) in Radical Reactions David M. Schubert, Paul F. Brandt, and Arlan D. Norman pp 6204 - 6209; DOI: 10.1021/ic9602916 |
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Stereochemistry of Boron-Functionalized (Dioximato)iron(II) Complexes. Control of Nonbonded Interactions on Soft Conformational Surfaces Isak Vernik and Dennis V. Stynes pp 6210 - 6220; DOI: 10.1021/ic9602761 |
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Uncommon Anionic Dioxorhenium(V) and Neutral Monooxorhenium(V) Mixed-Ligand Complexes Containing Heterofunctionalized Phosphine Ligands: Syntheses and Structural Characterization Cristina Bolzati, Francesco Tisato, Fiorenzo Refosco, Giuliano Bandoli, and Alessandro Dolmella pp 6221 - 6229; DOI: 10.1021/ic960404l |
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Synthesis, Structures, and Spectroscopic, Magnetic, and Electrochemical Properties of (-Alkoxo)bis(-carboxylato)diruthenium Complexes, M[Ru2(dhpta)(-O2CR)2] (M = Na and K, dhptaH5 = 1,3-Diamino-2-hydroxypropanetetraacetic Acid) Tomoaki Tanase, Yasuko Yamada, Keiko Tanaka, Tomoko Miyazu, Masako Kato, Keomil Lee, Yoshikazu Sugihara, Wasuke Mori, Akio Ichimura, Isamu Kinoshita, Yasuhiro Yamamoto, Masaaki Haga, Yoichi Sasaki, and Shigenobu Yano pp 6230 - 6239; DOI: 10.1021/ic960435g |
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Cyclization of Tetra-L-alanine Induced by Complexation of Technetium G. Bormans, O. M. Peeters, H. Vanbilloen, N. Blaton, and A. Verbruggen pp 6240 - 6244; DOI: 10.1021/ic951030j |
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Binuclear Iron and Ruthenium Complexes with Bis(diazene) or Bis(diazenido) Bridging Ligands: Synthesis, Characterization, X-ray Crystal Structure, and Electrochemical Studies Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Emilio Bordignon, Giancarlo Pelizzi, and Paolo Ugo pp 6245 - 6253; DOI: 10.1021/ic960138b |
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Structure and Dynamics of CO-Iron(II) Protoporphyrin IX in Dimethyl Sulfoxide Randy W. Larsen, Jim Murphy, and Eric W. Findsen pp 6254 - 6260; DOI: 10.1021/ic950998c |
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Emission Spectroscopic Properties of the Red Form of Dichloro(2,2'-bipyridine)platinum(II). Role of Intermolecular Stacking Interactions William B. Connick, Lawrence M. Henling, Richard E. Marsh, and Harry B. Gray pp 6261 - 6265; DOI: 10.1021/ic960511f |
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Reaction Chemistry of Alkynyl-Functionalized Titanocenes. X-ray Structure Analyses of (5-C5H4SiMe3)2Ti(Cl)(CH2SiMe3) and [(5-C5H4SiMe3)2Ti(Cl)(CCSiMe3)]CuBr H. Lang, W. Frosch, I. Y. Wu, S. Blau, and B. Nuber pp 6266 - 6272; DOI: 10.1021/ic960115x |
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[FeIII(PMA)]2+: A Mononuclear Non-Heme Iron Complex That Catalyzes Alkane Oxidation Cattien Nguyen, Richard J. Guajardo, and Pradip K. Mascharak pp 6273 - 6281; DOI: 10.1021/ic960400g |
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Synthesis, Properties, and Structure of a Stable Cobalt(III) Alkyl Peroxide Complex and Its Role in the Oxidation of Cyclohexane Ferman A. Chavez, Cattien V. Nguyen, Marilyn M. Olmstead, and Pradip K. Mascharak pp 6282 - 6291; DOI: 10.1021/ic960500m |
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Nonrandom Double Strand Cleavage of DNA by a Monofunctional Metal Complex: Mechanistic Studies Charles A. Detmer, III, Filomena V. Pamatong, and Jeffrey R. Bocarsly pp 6292 - 6298; DOI: 10.1021/ic960519p |
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Synthesis and Characterization of Amide-Derivatized, Polypyridyl-Based Metallopolymers Laurence M. Dupray and Thomas J. Meyer pp 6299 - 6307; DOI: 10.1021/ic9516222 |
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Structural and Dynamic Information on Double-Decker Yb3+ and Dy3+ Porphyrin Complexes in Solution through 1H NMR Ivano Bertini, Athanassios Coutsolelos, Alexander Dikiy, Claudio Luchinat, Georgios A. Spyroulias, and Anastassios Troganis pp 6308 - 6315; DOI: 10.1021/ic960339f |
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Ionic Isomerism. 3. Estimation of Enthalpies of Formation of the Gaseous Tetrachlorophosphonium Ion, fH(PCl4+,g), and of the Gaseous Hexachlorophosphate Ion, fH(PCl6-,g). Lattice Enthalpy Calculations for Bis(tetrachlorophosphonium) Hexachlorophosphate Halides, [PCl4]2[PCl6]X, Where X = Cl or Br. Bond Enthalpies of Phosphorus(V) Chloro Compounds Harry Donald Brooke Jenkins, Lorraine Sharman, Arthur Finch, and Peter N. Gates pp 6316 - 6326; DOI: 10.1021/ic9514410 |
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Synthesis and Electronic Structure of Pentacyanoosmate(II) Complexes with N-Heterocyclic Ligands Leonardo D. Slep, Luis M. Baraldo, and José A. Olabe pp 6327 - 6333; DOI: 10.1021/ic960377z |
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X-ray Crystallographic Structure of (meso-Tetraphenylporphinato)bis(phenylphosphinic methyl ester)iron(III) Perchlorate: A New High-Spin Six-Coordinate Ferric Porphyrin Maud Guillemot, Loïc Toupet, and Gérard Simonneaux pp 6334 - 6336; DOI: 10.1021/ic960338n |
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Synthesis and Structure of Adamantane-Containing Phosphazenes Wendy E. Krause, Masood Parvez, Karyn B. Visscher, and Harry R. Allcock pp 6337 - 6338; DOI: 10.1021/ic960721s |
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Independent Synthesis and Structural Characterization of a Mononuclear Copper-Hydroxide Complex Previously Assigned as a Copper-Superoxide Species Lisa M. Berreau, Samiran Mahapatra, Jason A. Halfen, Victor G. Young, Jr., and William B. Tolman pp 6339 - 6342; DOI: 10.1021/ic960340e |
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Preparation of the Novel Chelating Agent N-(2-Aminoethyl)-trans-1,2-diaminocyclohexane- N,N',N''-pentaacetic Acid (H5CyDTPA), a Preorganized Analogue of Diethylenetriaminepentaacetic Acid (H5DTPA), and the Structures of BiIII(CyDTPA)2- and BiIII(H2DTPA) Complexes Martin W. Brechbiel, Otto A. Gansow, C. Greg Pippin, Robin D. Rogers, and Roy P. Planalp pp 6343 - 6348; DOI: 10.1021/ic951326p |
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Binding of Oxovanadium(IV) to Guanosine 5'-Monophosphate Giovanni Micera, Alessandro Dessì, and Daniele Sanna pp 6349 - 6352; DOI: 10.1021/ic9514152 |
Issue 22
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2-Bonded Hydrotris(3,5-dimethylpyrazolyl)borate in [Rh(HB(Me2pz)3)(CO)(PMe3)]. X-ray Crystal Structure and Dynamic Exchange in Solution V. Chauby, C. Serra Le Berre, Ph. Kalck, J.-C. Daran, and G. Commenges pp 6354 - 6355; DOI: 10.1021/ic9602198 |
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Modeling the Claus Reaction: Preparation of trans-Pt(PPh3)2(phthalimido)S(O)2SR Alan Shaver, Hélène Boily, and Anne-Marie Lebuis pp 6356 - 6357; DOI: 10.1021/ic960617a |
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Na4Mn0.5P0.5O5: Synthesis of a Novel Mixed-Metal Manganese(VII)/Phosphorus(V) Oxide via Hydroxide Flux Kristen M. S. Etheredge, Anna S. Gardberg, and Shiou-Jyh Hwu pp 6358 - 6361; DOI: 10.1021/ic960752n |
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Preparation and Study of Decavanadate-Pillared Hydrotalcite-like Anionic Clays Containing Cobalt and Chromium M. del Arco, M. V. G. Galiano, V. Rives, R. Trujillano, and P. Malet pp 6362 - 6372; DOI: 10.1021/ic9601551 |
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Synthesis and Crystal Structures of Two Novel Anionic Aluminophosphates: A One-Dimensional Chain, UT-7 ([Al3P5O20H]5-[C7H13NH3+]5), and a Layer Containing Two Cyclic Amines, UT-8 ([Al3P4O16]3-[C4H7NH3+]2[C5H10NH2+]) Scott Oliver, Alex Kuperman, Alan Lough, and Geoffrey A. Ozin pp 6373 - 6380; DOI: 10.1021/ic960458v |
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Synthesis, Crystal Structure, and EPR Studies of the Five-Coordinate [CuCl3(H2O)2]- Complex in (dabcoH2)2Cl3[CuCl3(H2O)2]·H2O Mingyi Wei and Roger D. Willett pp 6381 - 6385; DOI: 10.1021/ic9602862 |
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Synthesis and Structural Characterization of [Mn(ethyl isonicotinate)2(N3)2]n, a Two-Dimensional Alternating Ferromagnetic-Antiferromagnetic Compound. Magnetostructural Correlations for the End-to-End Pseudohalide-Manganese System Albert Escuer, Ramon Vicente, Mohamed A. S. Goher, and Franz A. Mautner pp 6386 - 6391; DOI: 10.1021/ic9603464 |
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Hydrothermal Synthesis, Structure, and Solid State 19F NMR Study of ULM-17: (H3O)2[V4(HPO4)(PO4)3O6F]2[NC7H14]6 Didier Riou, Francis Taulelle, and Gérard Férey pp 6392 - 6395; DOI: 10.1021/ic960081t |
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Electronic Band Structure and Madelung Potential Study of the Nickelates La2NiO4, La3Ni2O7, and La4Ni3O10 D.-K. Seo, W. Liang, M.-H. Whangbo, Z. Zhang, and M. Greenblatt pp 6396 - 6400; DOI: 10.1021/ic960379j |
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Theoretical Evaluation of Steric Effects in [ReH5(PR3)2(SiR3)2] Complexes with the IMOMM Method Guada Barea, Feliu Maseras, Yves Jean, and Agustí Lledós pp 6401 - 6405; DOI: 10.1021/ic960440k |
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Photodriven Electron and Energy Transfer from Copper Phenanthroline Excited States Mark Ruthkosky, Felix N. Castellano, and Gerald J. Meyer pp 6406 - 6412; DOI: 10.1021/ic960503z |
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Photophysical and ab Initio Studies of Mononuclear Copper(I) Complexes Jerald A. Simon, William E. Palke, and Peter C. Ford pp 6413 - 6421; DOI: 10.1021/ic960367y |
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Linear Free Energy Relationships in Dinuclear Compounds. 2. Inductive Redox Tuning via Remote Substituents in Quadruply Bonded Dimolybdenum Compounds Chun Lin, John D. Protasiewicz, Eugene T. Smith, and Tong Ren pp 6422 - 6428; DOI: 10.1021/ic960555o |
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Coordination Chemistry of the Carboxylate Type Siderophore Rhizoferrin: The Iron(III) Complex and Its Metal Analogs Carl J. Carrano, Hartmut Drechsel, Dietmar Kaiser, Günther Jung, Berthold Matzanke, Günther Winkelmann, Natacha Rochel, and Anne Marie Albrecht-Gary pp 6429 - 6436; DOI: 10.1021/ic960526d |
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Tetranuclear and Octanuclear Manganese Carboxylate Clusters: Preparation and Reactivity of (NBun4)[Mn4O2(O2CPh)9(H2O)] and Synthesis of (NBun4)2[Mn8O4(O2CPh)12(Et2mal)2(H2O)2] with a "Linked-Butterfly" Structure Michael W. Wemple, Hui-Lien Tsai, Sheyi Wang, Juan Pablo Claude, William E. Streib, John C. Huffman, David N. Hendrickson, and George Christou pp 6437 - 6449; DOI: 10.1021/ic9603013 |
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Tetranuclear and Pentanuclear Vanadium(IV/V) Carboxylate Complexes: [V4O8(NO3)(O2CR)4]2- and [V5O9X(O2CR)4]2- (X = Cl-, Br-) Salts Gail B. Karet, Ziming Sun, Dwight D. Heinrich, James K. McCusker, Kirsten Folting, William E. Streib, John C. Huffman, David N. Hendrickson, and George Christou pp 6450 - 6460; DOI: 10.1021/ic9605938 |
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Synthesis, Structure, and Characterization of a Novel Manganese(IV) Monomer, [MnIV(Me3TACN)(OMe)3](PF6) (Me3TACN = N,N',N''-Trimethyl-1,4,7-triazacyclononane), and Its Activity toward Olefin Oxidation with Hydrogen Peroxide Vikki Chin Quee-Smith, Lisa DelPizzo, Sharon H. Jureller, Judith L. Kerschner, and Ronald Hage pp 6461 - 6465; DOI: 10.1021/ic951522w |
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Model for the Reduced Schiff Base Intermediate between Amino Acids and Pyridoxal: Copper(II) Complexes of N-(2-Hydroxybenzyl)amino Acids with Nonpolar Side Chains and the Crystal Structures of [Cu(N-(2-hydroxybenzyl)-D,L-alanine)(phen)]·H2O and [Cu(N-(2-hydroxybenzyl)-D,L-alanine)(imidazole)] Lip Lin Koh, John O. Ranford, Ward T. Robinson, Jan O. Svensson, Agnes Lay Choo Tan, and Daqing Wu pp 6466 - 6472; DOI: 10.1021/ic9606441 |
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Structure and Properties of [Fe4S4{2,6-bis(acylamino)benzenethiolato-S}4]2- and [Fe2S2{2,6-bis(acylamino)benzenethiolato-S}4]2-: Protection of the Fe-S Bond by Double NH···S Hydrogen Bonds Norikazu Ueyama, Yusuke Yamada, Taka-aki Okamura, Shuuji Kimura, and Akira Nakamura pp 6473 - 6484; DOI: 10.1021/ic9604324 |
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Four- and Five-Coordinate Oxovanadium(V) Alkoxides: Do Steric Effects or Electronic Properties Dictate the Geometry? Jean Yves Kempf, Bernard Maigret, and Debbie C. Crans pp 6485 - 6494; DOI: 10.1021/ic9601706 |
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Structural and Spectroscopic Characterization of Iron(III) Dioxoporphodimethene Complexes and Their Autoreduction to an Iron(II) Complex in Pyridine Alan L. Balch, Bruce C. Noll, Marilyn M. Olmstead, and Shane L. Phillips pp 6495 - 6506; DOI: 10.1021/ic960423v |
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Characterization of the Potent Insulin Mimetic Agent Bis(maltolato)oxovanadium(IV) (BMOV) in Solution by EPR Spectroscopy Graeme R. Hanson, Yan Sun, and Chris Orvig pp 6507 - 6512; DOI: 10.1021/ic960490p |
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Complexes of Zn2+, Cd2+, and Hg2+ with 2-(-Hydroxybenzyl)thiamine Monophosphate Chloride Katerina Dodi, Ioannis P. Gerothanassis, Nick Hadjiliadis, Andre Schreiber, Robert Bau, Ian S. Butler, and Patrick J. Barrie pp 6513 - 6519; DOI: 10.1021/ic950758x |
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Sulfur K-Edge EXAFS Studies of Cadmium-, Zinc-, Copper-, and Silver-Rabbit Liver Metallothioneins Ziqi Gui, Anna Rae Green, Masoud Kasrai, G. Michael Bancroft, and Martin J. Stillman pp 6520 - 6529; DOI: 10.1021/ic951624m |
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Synthesis, Characterization, and Spectroelectrochemistry of Cobalt Porphyrins Containing Axially Bound Nitric Oxide George B. Richter-Addo, Shelly J. Hodge, Geun-Bae Yi, Masood A. Khan, Tianshu Ma, Eric Van Caemelbecke, Ning Guo, and Karl M. Kadish pp 6530 - 6538; DOI: 10.1021/ic960031o |
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Interaction of Derivatized Capped Iron(II) Porphyrin Complexes with CO and O2 Hang Tang and David Dolphin pp 6539 - 6545; DOI: 10.1021/ic9600745 |
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N-Methyl-2-(methylamino)troponiminate Complexes of Tin(II), Gallium(III), and Indium(III). Syntheses of [(Me)2ATI]2GaI and [(Me)2ATI]2InCl Using the Tin(II) Reagent [(Me)2ATI]2Sn H. V. Rasika Dias and and Wiechang Jin pp 6546 - 6551; DOI: 10.1021/ic9606800 |
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Axial Site Occupancy by the Least Electronegative Ligands in Trigonal Bipyramidal Tetraoxyphosphoranes Natalya V. Timosheva, A. Chandrasekaran, T. K. Prakasha, Roberta O. Day, and Robert R. Holmes pp 6552 - 6560; DOI: 10.1021/ic960538z |
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Reaction of nido-7,8-C2B9H13 with Dicobalt Octacarbonyl: Crystal Structures of the Complexes [Co2(CO)2(5-7,8-C2B9H11)2], [Co2(CO)(PMe2Ph)(5-7,8-C2B9H11)2], and [CoCl(PMe2Ph)2(5-7,8-C2B9H11)] Shelley L. Hendershot, John C. Jeffery, Paul A. Jelliss, Donald F. Mullica, Eric L. Sappenfield, and F. Gordon A. Stone pp 6561 - 6570; DOI: 10.1021/ic960560s |
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Small Molecule Chemistry of the Pyrazolylborate-Zinc Unit TpCum,MeZn Michael Ruf and Heinrich Vahrenkamp pp 6571 - 6578; DOI: 10.1021/ic960335a |
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Small Heteroborane Cluster Systems. 6. Mössbauer Effect Study of Iron Substituted Small Metallaborane Clusters Bruce H. Goodreau, Lianna R. Orlando, Gary J. Long, and James T. Spencer pp 6579 - 6585; DOI: 10.1021/ic9605478 |
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Vinylmercury Hydrides: Synthesis and Spectroscopic Characterization Jean-Claude Guillemin, Nathalie Bellec, Sándor Kis Szétsi, László Nyulászi, and Tamás Veszprémi pp 6586 - 6591; DOI: 10.1021/ic960211y |
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Platinum-Assisted Addition of Carbonyl-Stabilized Phosphorus Ylides to Pentafluorobenzonitrile and Acetonitrile To Give Platinum(II) Complexes Containing Iminophosphorane and/or N-Bonded -Imino Phosphorus Ylide Ligands. Crystal and Molecular Structures of trans-[PtCl2{E-NH=C(C6F5)C(=PPh3)C(O)Me}2] and trans-[PtCl2{E-N(=PPh3)C(C6F5)=CHCO2Et}{E-NH=C(C6F5)C(=PPh3)CO2Et}] José Vicente, María Teresa Chicote, Michael A. Beswick, and M. Carmen Ramirez de Arellano pp 6592 - 6598; DOI: 10.1021/ic951666a |
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Synthesis, Properties, and Crystal Structures of Benzene-1,2-dithiolato Complexes of Thallium(I) and -(III) Boris E. Bosch, Martin Eisenhawer, Berthold Kersting, Kristin Kirschbaum, Bernt Krebs, and Dean M. Giolando pp 6599 - 6605; DOI: 10.1021/ic951411x |
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Resonance Raman Spectra of [M6X8Y6]2- Cluster Complexes (M = Mo, W; X, Y = Cl, Br, I) Jon R. Schoonover, Thomas C. Zietlow, David L. Clark, Joseph A. Heppert, Malcolm H. Chisholm, Harry B. Gray, Alfred P. Sattelberger, and William H. Woodruff pp 6606 - 6613; DOI: 10.1021/ic960184b |
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Ion-Bearing Propellers: Alkali Metal Complexes of Tris(2-alkoxyphenyl)amine Ionophores Scott J. Stoudt, Prakash Gopalan, Alexei Bakulin, Bart Kahr, and James E. Jackson pp 6614 - 6621; DOI: 10.1021/ic951129q |
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Iso- and Homeostructuralism of Analogous Ph4E and Ph3E-E'R3 Compounds (E = C, Si, Ge, Sn, Pb; E' = Si, Ge, Sn; R = Me, Ph): Crystal Structure of 1,1,1-Trimethyltriphenyldistannane László Párkányi, Alajos Kálmán, Keith H. Pannell, Francisco Cervantes-Lee, and Ramesh N. Kapoor pp 6622 - 6624; DOI: 10.1021/ic960791z |
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Organometallic Selenolates. 3.1 Oxidation of (Cyclopentadienyl)tungsten Selenolates and Crystal Structure of [(cp)W(CO)3]2Se3 Peter G. Jones and Carsten Thöne pp 6625 - 6626; DOI: 10.1021/ic951394b |
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First Structural Study of a Stable Arsorane Containing 1,3,2-Dioxarsenane Rings and an NAs Donor-Acceptor Bond: Arsenic vs Phosphorus Chemical Behavior Musa A. Said, K. C. Kumara Swamy, M. Veith, and V. Huch pp 6627 - 6630; DOI: 10.1021/ic951621+ |
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Synthesis, Tuning of the Stereochemistry, and Physical Properties of Cobalt(II) Tropocoronand Complexes B. Scott Jaynes, Linda H. Doerrer, Shuncheng Liu, and Stephen J. Lippard pp 6630 - 6630; DOI: 10.1021/ic961041s |
Issue 23
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Nickel Complexes as Antioxidants. Inhibition of Aldehyde Autoxidation by Nickel(II) Tetraazamacrocycles Wonwoo Nam, Seung Joong Baek, Kyoung Ah Lee, Byung Tae Ahn, James G. Muller, Cynthia J. Burrows, and Joan Selverstone Valentine pp 6632 - 6633; DOI: 10.1021/ic9513651 |
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Multielectron Redox Process of Vanadium Complexes in Oxidation of Low-Coordinate Vanadium(III) to Oxovanadium(V) with Dioxygen Kenichi Oyaizu, Kimihisa Yamamoto, Kotaro Yoneda, and Eishun Tsuchida pp 6634 - 6635; DOI: 10.1021/ic960198h |
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Synthesis and Characterization of a Tripyrrane-Copper(II) Complex Jonathan L. Sessler, Andreas Gebauer, Vladimír Král, and Vincent Lynch pp 6636 - 6637; DOI: 10.1021/ic9606789 |
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Synthesis, Characterization, and Reactivity of Monomeric Strontium and Barium Triphenylsiloxide Compounds: Molecular Structure and Reactivity of M(OSiPh3)2(15-crown-5)THF, M = Sr (1) and Ba (2) William A. Wojtczak, Mark J. Hampden-Smith, and Eileen N. Duesler pp 6638 - 6639; DOI: 10.1021/ic960723c |
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Supercubane Mixed-Valence Tridecanuclear Manganese Complex Ziming Sun, Peter K. Gantzel, and David N. Hendrickson pp 6640 - 6641; DOI: 10.1021/ic9607200 |
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Syntheses, Crystal Structures, and Properties of Unsymmetrical (-Oxo)diiron(III) Complexes Containing Polyimidazole Ligands Jianping Wang, Mark S. Mashuta, Ziming Sun, John F. Richardson, David N. Hendrickson, and Robert M. Buchanan pp 6642 - 6643; DOI: 10.1021/ic9607494 |
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Synthesis and Structure of the First Stable Iminoarsane Jens-Thomas Ahlemann, Antje Künzel, Herbert W. Roesky, Mathias Noltemeyer, Leonid Markovskii, and Hans-Georg Schmidt pp 6644 - 6645; DOI: 10.1021/ic960756s |
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Novel Organo-Substituted Cyclophosphazenes via Reaction of a Monohydro Cyclophosphazene and Acetyl Chloride G. Bosscher, A. Meetsma, and J. C. van de Grampel pp 6646 - 6650; DOI: 10.1021/ic960466b |
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Ring Systems Containing Anionic and Cationic Gallium Centers: Structural and Bonding Considerations Jason A. C. Clyburne, Robert D. Culp, Smuruthi Kamepalli, Alan H. Cowley, and Andreas Decken pp 6651 - 6655; DOI: 10.1021/ic960647d |
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Gallium and Indium Complexes of Bis(amino thiol) (N2S2) Ligands Yong Yong Zheng, Sunita Saluja, Glenn P. A. Yap, Michael Blumenstein, Arnold L. Rheingold, and Lynn C. Francesconi pp 6656 - 6666; DOI: 10.1021/ic951535+ |
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Dehydrochlorination of -Chlorophosphines, a Simple and General Route to Phosphaalkenes Annie-Claude Gaumont, Bruno Pellerin, Jean-Luc Cabioch, Xavier Morise, Mickaël Lesvier, Philippe Savignac, Pierre Guenot, and Jean-Marc Denis pp 6667 - 6675; DOI: 10.1021/ic960417z |
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Insertion of Fluoroalkenes into Activated C-H Bonds for the Preparation of Polyfluorinated Sulfanes, Alcohols, and Acyclic and Cyclic Ethers Jianguo Chen, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 6676 - 6681; DOI: 10.1021/ic960541i |
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Preparation and Structures of the 2.2.2-Cryptand(1+) Salts of the [Sb2Se4]2-, [As2S4]2-, [As10S3]2-, and [As4Se6]2- Anions Donna M. Smith, Chang-Woo Park, and James A. Ibers pp 6682 - 6687; DOI: 10.1021/ic960602c |
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Synthesis and Characterization of Water-Soluble 1,2-Bis(bis(hydroxyalkyl)phosphino)ethane Ligands and Their Nickel(II), Ruthenium(III), and Rhodium(I) Complexes Gregory T. Baxley, Warren K. Miller, David K. Lyon, Brian E. Miller, Gregory F. Nieckarz, Timothy J. R. Weakley, and David R. Tyler pp 6688 - 6693; DOI: 10.1021/ic960766t |
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Synthesis and Characterization of Sterically Encumbered Derivatives of Aluminum Hydrides and Halides: Assessment of Steric Properties of Bulky Terphenyl Ligands Rudolf J. Wehmschulte, Warren J. Grigsby, Berthold Schiemenz, Ruth A. Bartlett, and Philip P. Power pp 6694 - 6702; DOI: 10.1021/ic960486d |
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"Recapitation" of nido-Metallacarboranes as a Synthetic Tool: Preparation of Apically Substituted CoC2B4 Clusters via Boron Insertion Michael A. Curtis, Michal Sabat, and Russell N. Grimes pp 6703 - 6707; DOI: 10.1021/ic960691t |
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Metal Complexes of Mesitylphosphine: Synthesis, Structure, and Spectroscopy Igor V. Kourkine, Stanislav V. Maslennikov, Robert Ditchfield, David S. Glueck, Glenn P. A. Yap, Louise M. Liable-Sands, and Arnold L. Rheingold pp 6708 - 6716; DOI: 10.1021/ic960529q |
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Synthesis and Characterization of Palladium(II) and Platinum(II) Complexes Containing Water-Soluble Hybrid Phosphine-Phosphonate Ligands Terence L. Schull, James C. Fettinger, and D. Andrew Knight pp 6717 - 6723; DOI: 10.1021/ic960506b |
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Oxo-Centered Mixed-Ligand Triruthenium Complexes Having Redox-Active N-Methyl-4,4'-bipyridinium Ions (mbpy+). Reversible Multistep Electrochemical Properties of [RuIII2RuII(3-O)(-CH3CO2)6(mbpy+)2(CO)]2+ and [RuIII3(3-O)(-CH3CO2)6(mbpy+)2(L)]3+ (L = H2O and N-Heterocyclic Ligands) Masaaki Abe, Yoichi Sasaki, Yasuko Yamada, Keiichi Tsukahara, Shigenobu Yano, Tadashi Yamaguchi, Masato Tominaga, Isao Taniguchi, and Tasuku Ito pp 6724 - 6734; DOI: 10.1021/ic960430j |
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Structural Aspects of Lithium Arenethiolate Complexes with Intramolecular Coordinating Amine Donors Maurits D. Janssen, Evelien Rijnberg, Corine A. de Wolf, Marinus P. Hogerheide, Dennis Kruis, Huub Kooijman, Anthony L. Spek, David M. Grove, and Gerard van Koten pp 6735 - 6741; DOI: 10.1021/ic960075x |
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Octahedral Group 4 Metal Complexes That Contain Amine, Amido, and Aminopyridinato Ligands: Synthesis, Structure, and Application in -Olefin Oligo- and Polymerization Hans Fuhrmann, Simon Brenner, Perdita Arndt, and Rhett Kempe pp 6742 - 6745; DOI: 10.1021/ic960182r |
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Catalytic Activation of H2 and C-H Bonds by Electron-Deficient Ruthenium(II) Porphyrins James P. Collman, H. T. Fish, Paul S. Wagenknecht, David A. Tyvoll, Leng-Leng Chng, Todd A. Eberspacher, John I. Brauman, Jeffrey W. Bacon, and Louis H. Pignolet pp 6746 - 6754; DOI: 10.1021/ic951495+ |
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Kinetic Investigation of Homogeneous H2-D2 Equilibration Catalyzed by Pt-Au Cluster Compounds. Characterization of the Cluster [(H)Pt(AuPPh3)9](NO3)2 Leon I. Rubinstein and Louis H. Pignolet pp 6755 - 6762; DOI: 10.1021/ic9515160 |
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Synthesis and Characterization of a Series of Triethylphosphine-Ligated Pt-Au Cluster Compounds. X-ray Crystal and Molecular Structure of [Pt(AuPEt3)9](NO3)3 Don A. Krogstad, Wayde V. Konze, and Louis H. Pignolet pp 6763 - 6771; DOI: 10.1021/ic960586j |
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Intramolecular Hydrogen Site Exchange in an HRu(SiHPh2) Moiety Dmitry G. Gusev, T. Timothy Nadasdi, and Kenneth G. Caulton pp 6772 - 6774; DOI: 10.1021/ic960584z |
Structure and H2-Loss Energies of OsHX(H2)(CO)L2 Complexes (L = P(t-Bu)2Me, P(i-Pr)3; X = Cl, I, H): Attempted Correlation of 1J(H-D), T1min, and G Dmitry G. Gusev, Roger L. Kuhlman, Kenton B. Renkema, Odile Eisenstein, and Kenneth G. Caulton pp 6775 - 6783; DOI: 10.1021/ic960693d |
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Reactions of the Dirhenium(II) Complexes Re2X4(-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 11.1 A Triply Bonded Dirhenium Complex Containing a Labile Acetonitrile Ligand. Synthesis, Structural Characterization, and Reactivity of [(XylNC)(CH3CN)ClRe(-dppm)2ReCl2(CO)]O3SCF3 Wengan Wu, J. Anand Subramony, Phillip E. Fanwick, and Richard A. Walton pp 6784 - 6788; DOI: 10.1021/ic9604831 |
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X-ray Crystallographic Study of the Ruthenium Blue Complexes [Ru2Cl3(tacn)2](PF6)2·4H2O, [Ru2Br3(tacn)2](PF6)2·2H2O, and [Ru2I3(tacn)2](PF6)2: Steric Interactions and the Ru-Ru "Bond Length" Wendy A. Clucas, Robert S. Armstrong, Irmi E. Buys, Trevor W. Hambley, and Kerry W. Nugent pp 6789 - 6794; DOI: 10.1021/ic9605377 |
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Kinetics and Mechanism of the Ferrate Oxidation of Thiosulfate and Other Sulfur-Containing Species Michael D. Johnson and John F. Read pp 6795 - 6799; DOI: 10.1021/ic960480o |
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Ion-Pair Charge Transfer Photochemistry in Rhenium(I) Borate Salts Bruce H. McCosar and Kirk S. Schanze pp 6800 - 6808; DOI: 10.1021/ic9605074 |
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Structural and Electrochemical Comparison of Copper(II) Complexes with Tripodal Ligands Hirotaka Nagao, Nobutoshi Komeda, Masao Mukaida, Masatatsu Suzuki, and Koji Tanaka pp 6809 - 6815; DOI: 10.1021/ic960303n |
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Luminescence Properties of Platinum(II) Dithiooxamide Compounds Giuseppe Rosace, Gaetano Giuffrida, Marcello Saitta, Giovanni Guglielmo, Sebastiano Campagna, and Santo Lanza pp 6816 - 6822; DOI: 10.1021/ic9514004 |
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Comparison of Physical and Photophysical Properties of Monometallic and Bimetallic Ruthenium(II) Complexes Containing Structurally Altered Diimine Ligands Ariel Macatangay, Greg Y. Zheng, D. Paul Rillema, Donald C. Jackman, and Jon W. Merkert pp 6823 - 6831; DOI: 10.1021/ic9513447 |
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Structure and Bonding in Pentacyano(L)ferrate(II) and Pentacyano(L)ruthenate(II) Complexes (L = Pyridine, Pyrazine, and N-Methylpyrazinium): A Density Functional Study Darío A. Estrin, O. Yasmine Hamra, Luca Paglieri, Leonardo D. Slep, and José A. Olabe pp 6832 - 6837; DOI: 10.1021/ic960534u |
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Valence-Dependent Metal-Metal Bonding and Optical Spectra in Confacial Bioctahedral [Re2Cl9]z- (z = 1, 2, 3). Crystallographic and Computational Characterization of [Re2Cl9]- and [Re2Cl9]2- Graham A. Heath, John E. McGrady, Raphael G. Raptis, and Anthony C. Willis pp 6838 - 6843; DOI: 10.1021/ic951604k |
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Magnetochemical Properties and Reactions of Vanadium(III) Thiolate Complexes: Preparation of (NEt4)3[V3Cl6(edt)3] and Mixed-Valence (NEt4)[V2(edt)4] (edt = Ethane-1,2-dithiolate) Joe R. Rambo, Stephanie L. Castro, Kirsten Folting, Stuart L. Bartley, Robert A. Heintz, and George Christou pp 6844 - 6852; DOI: 10.1021/ic9606901 |
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Layered Double Hydroxides Intercalated by Polyoxometalate Anions with Keggin (-H2W12O406-), Dawson (-P2W18O626-), and Finke (Co4(H2O)2(PW9O34)210-) Structures Sang Kyeong Yun and Thomas J. Pinnavaia pp 6853 - 6860; DOI: 10.1021/ic960287u |
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NMR Investigation of -Substituted High-Spin and Low-Spin Iron(III) Tetraphenylporphyrins Jacek Wojaczy ski, Lechosaw Latos-Grayski, Witold Hrycyk, Ewa Pacholska, Krystyna Rachlewicz, and Ludmia Szterenbergpp 6861 - 6872; DOI: 10.1021/ic960772p |
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Molecular Recognition of Amino Acids by Copper(II) Complexes of 6A,6X-Diamino-6A,6X-dideoxy--cyclodextrin (X = B, C, D) Raffaele P. Bonomo, Sonia Pedotti, Graziella Vecchio, and Enrico Rizzarelli pp 6873 - 6877; DOI: 10.1021/ic951447p |
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Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear FeIII-CN-CuII Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase Matthew T. Gardner, Geurt Deinum, Younkyoo Kim, G. T. Babcock, Michael J. Scott, and R. H. Holm pp 6878 - 6884; DOI: 10.1021/ic960575q |
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Characterization of N-Acetylated Heme Undecapeptide and Some of Its Derivatives in Aqueous Media: Monomeric Model Systems for Hemoproteins Angela D. Carraway, Michael G. McCollum, and Jim Peterson pp 6885 - 6891; DOI: 10.1021/ic960434o |
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A Carboxylate-Bridged Non-Heme Diiron Dinitrosyl Complex Andrew L. Feig, Maria T. Bautista, and Stephen J. Lippard pp 6892 - 6898; DOI: 10.1021/ic960552b |
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Unique Intramolecular Interaction in Cyclotriphosphazene Molecule. Synthesis, Structure, and Properties of 1,1-Bis(pyridyl-2-thio)-3,3,5,5-tetrachlorocyclotriphosphazene Ok-Sang Jung, Sung Ho Park, Young-A Lee, Yangha Cho, Kwan Mook Kim, Sang-gi Lee, Hee Kwon Chae, and Youn Soo Sohn pp 6899 - 6901; DOI: 10.1021/ic9604730 |
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Self-Assembly and X-ray Structure of a Dimetalloparacyclophane Incorporating a - Stacked Subunit Chris M. Hartshorn and Peter J. Steel pp 6902 - 6903; DOI: 10.1021/ic960425f |
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Spectroelectrochemical Characterization of Substituted Cobalt Nitrosyl Porphyrins Abhay D. Kini, John Washington, Clifford P. Kubiak, and Bruce H. Morimoto pp 6904 - 6906; DOI: 10.1021/ic9604223 |
Issue 24
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Localized 3MLCT Excitations of [Ru(bpy)3-x(bpy-6,6'-d2)x]2+ (x = 0-3) in [Zn(bpy)3](ClO4)2 (bpy = 2,2'-Bipyridine) Hans Riesen, Lynne Wallace, and Elmars Krausz pp 6908 - 6909; DOI: 10.1021/ic960590v |
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Co5BP3O14: The First Borophosphate with Planar BO3 Groups Connected to PO4 Tetrahedra Ranko P. Bontchev and Slavi C. Sevov pp 6910 - 6911; DOI: 10.1021/ic960808d |
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Comparison of Zinc and Cadmium Coordination Environments in Synthetic Analogues of Carbonic Anhydrase: Synthesis and Structure of {[PimPri,But]Cd(OH2)(OClO3)}(ClO4) Clare Kimblin and Gerard Parkin pp 6912 - 6913; DOI: 10.1021/ic961007d |
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Fluorination of B10H102- with an N-Fluoro Reagent. A New Way To Transform B-H Bonds into B-F Bonds Sergei V. Ivanov, Svetlana M. Ivanova, Susie M. Miller, Oren P. Anderson, Konstantin A. Solntsev, and Steven H. Strauss pp 6914 - 6915; DOI: 10.1021/ic961043c |
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Temperature Dependence of the Electron Transfer in a MnIIMnIII(-OH) Mixed-Valence Manganese Complex Alex Darovsky, Vladimir Kezerashvili, Philip Coppens, T. Weyhermüller, H. Hummel, and K. Wieghardt pp 6916 - 6917; DOI: 10.1021/ic9610391 |
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Assignment of Nonclassical [Cu(CO)n]+ (n = 1, 2) Complex Ions in Zeolite Cages Masakazu Iwamoto and Yasuyuki Hoshino pp 6918 - 6921; DOI: 10.1021/ic960429k |
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The Four-Connected Net in the CeCu2 Structure and Its Ternary Derivatives. Its Electronic and Structural Properties Gerhard Nuspl, Kurt Polborn, Jürgen Evers, Gregory A. Landrum, and Roald Hoffmann pp 6922 - 6932; DOI: 10.1021/ic9602557 |
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Experimental and Theoretical Studies of ScS under Pressure Suhithi M. Peiris, Michael T. Green, Dion L. Heinz, and Jeremy K. Burdett pp 6933 - 6936; DOI: 10.1021/ic9605027 |
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Three 18-Electron Tantalum(I) Compounds, TaCl(CO)2(dppe)2, [TaCl(CO)2(dppe)2]2x, and TaCl(CO)4(dppe) (dppe = 1,2-Bis(diphenylphosphino)ethane), Which Exhibit Low Levels of Paramagnetism Mary Ann D. Koeslag, Brian K. Hunter, Joseph H. MacNeil, Aleksander W. Roszak, and Michael C. Baird pp 6937 - 6943; DOI: 10.1021/ic960456a |
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Copper and Bismuth Complexes Containing Dipyridyl gem-Diolato Ligands: BiIII2[(2-Py)2CO(OH)]2(O2CCF3)4(THF)2 , CuII[(2-Py)2CO(OH)]2(HO2CCH3)2, and CuII4[(2-Py)2CO(OH)]2(O2CCH3)6(H2O)2, a Ferromagnetically Coupled Tetranuclear Copper(II) Chain Steven R. Breeze, Suning Wang, John E. Greedan, and N. P. Raju pp 6944 - 6951; DOI: 10.1021/ic9602310 |
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Molecular Structures of Methyldifluoroarsine, CH3AsF2, and Dimethylfluoroarsine, (CH3)2AsF, in the Gas Phase As Determined by Electron Diffraction and ab Initio Calculations Anthony J. Downs, Tim M. Greene, G. Sean McGrady, Neil Townson, Paul T. Brain, Colin R. Pulham, David W. H. Rankin, Heather E. Robertson, Bruce A. Smart, and Ian L. Alberts pp 6952 - 6958; DOI: 10.1021/ic960732l |
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Synthesis and Structure of Ba2Sn3Sb6, a Zintl Phase Containing Channels and Chains Robert Lam and Arthur Mar pp 6959 - 6963; DOI: 10.1021/ic960716o |
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Structural Chemistry of Poly(ethylene glycol) Complexes of Lead(II) Nitrate and Lead(II) Bromide Robin D. Rogers, Andrew H. Bond, and Debra M. Roden pp 6964 - 6973; DOI: 10.1021/ic960587b |
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Bipyrimidine-Bridged Mixed-Metal Trimetallic Complexes of Ruthenium(II) with Rhodium(III) or Iridium(III), {[(bpy)2Ru(bpm)]2MCl2}5+ Girlie Naomi A. Nallas, Sumner W. Jones, and Karen J. Brewer pp 6974 - 6980; DOI: 10.1021/ic960792r |
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Syntheses, Characterization, and Molecular Mechanics Calculations of Optically Active Silatrane Derivatives Motoyuki Tasaka, Masakazu Hirotsu, Masaaki Kojima, Shunji Utsuno, and Yuzo Yoshikawa pp 6981 - 6986; DOI: 10.1021/ic960349g |
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New Zr6MTe2 (M = Mn, Fe, Co, Ni, Ru, Pt), Zr6Fe0.6Se2.4, and Zr6Fe0.57S2.43 Intermetallics: Structural Links between Binary (Zr,Hf)3M Alloys and Porous Metal-Rich Tellurides Chwanchin Wang and Timothy Hughbanks pp 6987 - 6994; DOI: 10.1021/ic960610t |
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Synthesis and Characterization of Polyether Adducts of Barium and Strontium Carboxylates and Their Use in the Formation of MTiO3 Films William A. Wojtczak, Paolina Atanassova, Mark J. Hampden-Smith, and Eileen Duesler pp 6995 - 7000; DOI: 10.1021/ic960660y |
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Multifrequency ESEEM Spectroscopy of Sulfite Oxidase in Phosphate Buffer: Direct Evidence for Coordinated Phosphate Andrew Pacheco, Partha Basu, Petr Borbat, Arnold M. Raitsimring, and John H. Enemark pp 7001 - 7008; DOI: 10.1021/ic9607806 |
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Synthesis and Structure of Two New Strontium Germanium Nitrides: Sr3Ge2N2 and Sr2GeN2 S. J. Clarke, G. R. Kowach, and F. J. DiSalvo pp 7009 - 7012; DOI: 10.1021/ic960518x |
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Molecular Mechanics Investigation of Gadolinium(III) Complexes David E. Reichert, Robert D. Hancock, and Michael J. Welch pp 7013 - 7020; DOI: 10.1021/ic960495m |
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X-ray Diffraction Analysis of Geometry Changes upon Excitation: The Ground-State and Metastable-State Structures of K2[Ru(NO2)4(OH)(NO)] Dmitry V. Fomitchev and Philip Coppens pp 7021 - 7026; DOI: 10.1021/ic9607144 |
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Organotransition-Metal Metallacarboranes. 46. Multidecker Sandwiches of the Cobalt Group Metals David A. Franz, Eric J. Houser, Michal Sabat, and Russell N. Grimes pp 7027 - 7034; DOI: 10.1021/ic9606587 |
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Reactivity of RuCl2(CO)(PtBu2Me)2 toward H2 and Brnsted Acids: Aggregation Triggered by Protonation and Phosphine Loss Dejian Huang, Kirsten Folting, and Kenneth G. Caulton pp 7035 - 7040; DOI: 10.1021/ic9605837 |
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Synthesis and Liquid-Crystalline Properties of Diazabutadiene Complexes of Rhenium(I) Stefania Morrone, Daniel Guillon, and Duncan W. Bruce pp 7041 - 7048; DOI: 10.1021/ic960478x |
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Substrate and Solvent Influence on the Photochemical C-H Bond Activation Reactivity of (HBPz'3)Rh(CO)2 (Pz' = 3,5-Dimethylpyrazolyl) Agus A. Purwoko, Stephen D. Tibensky, and Alistair J. Lees pp 7049 - 7055; DOI: 10.1021/ic960479p |
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Oligomeric Rare-Earth-Metal Halide Clusters. Three Structures Built of (Y16Z4)Br36 Units (Z = Ru, Ir) Sharon J. Steinwand and John D. Corbett pp 7056 - 7067; DOI: 10.1021/ic960650x |
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Formation and X-ray Structures of PCP Ligand Based Platinum(II) and Palladium(II) Macrocycles Milko E. van der Boom, Michael Gozin, Yehoshoa Ben-David, Linda J. W. Shimon, Felix Frolow, Heinz-Bernard Kraatz, and David Milstein pp 7068 - 7073; DOI: 10.1021/ic960285+ |
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Complex Formation in the Ternary System Tl(III)-CN--Cl- in Aqueous Solution. A 205Tl NMR Study Katja E. Berg, Johan Blixt, and Julius Glaser pp 7074 - 7081; DOI: 10.1021/ic950772+ |
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Preparation, Structure, and Properties of Bis(-oxo)dirhenium(III,IV) and -dirhenium(IV) Complexes of Tris(2-pyridylmethyl)amine and Its (6-Methyl-2-pyridyl)methyl Derivatives Hideki Sugimoto, Masaki Kamei, Keisuke Umakoshi, Yoichi Sasaki, and Masatatsu Suzuki pp 7082 - 7088; DOI: 10.1021/ic960445h |
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Interactions of Aluminum(III) with Phosphates Károly Atkári, Tamás Kiss, Roberta Bertani, and R. Bruce Martin pp 7089 - 7094; DOI: 10.1021/ic960329e |
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Poly(2-thienyl)borates: An Investigation into the Coordination of Thiophene and Its Derivatives Andrew L. Sargent, Emily P. Titus, Charles G. Riordan, Arnold L. Rheingold, and Pinghua Ge pp 7095 - 7101; DOI: 10.1021/ic960703a |
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Photooxidation of Diimine Dithiolate Platinium(II) Complexes Induced by Charge Transfer to Diimine Excitation Yin Zhang, Kevin D. Ley, and Kirk S. Schanze pp 7102 - 7110; DOI: 10.1021/ic960685x |
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113Cd Shielding Tensors of Monomeric Cadmium Compounds Containing Nitrogen Donor Atoms. 3. CP/MAS Studies on Five-Coordinate Cadmium Complexes Having N3X2 (X = H, N, O, and S) Donor Atoms Andrew S. Lipton, Scott S. Mason, Sheila M. Myers, Daniel L. Reger, and Paul D. Ellis pp 7111 - 7117; DOI: 10.1021/ic951528l |
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Acid-Base Properties of the Ground and Excited States of Ruthenium(II) Bis(2,2'-bipyridine) 3-Carboxyl-2,2'-bipyridine Greg Y. Zheng, Y. Wang, and D. Paul Rillema pp 7118 - 7123; DOI: 10.1021/ic960677g |
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Besides N2, What Is the Most Stable Molecule Composed Only of Nitrogen Atoms? Mikhail N. Glukhovtsev, Haijun Jiao, and Paul von Ragué Schleyer pp 7124 - 7133; DOI: 10.1021/ic9606237 |
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Photoinduced Ligand Redistribution Chemistry of Quadruply Bonded Mo2Cl2(6-mhp)2(PR3)2 Complexes Ann M. Macintosh and Daniel G. Nocera pp 7134 - 7139; DOI: 10.1021/ic960252u |
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Iron Sulfido Derivatives of the Fullerenes C60 and C70 Mark D. Westmeyer, Thomas B. Rauchfuss, and Atul K. Verma pp 7140 - 7147; DOI: 10.1021/ic960728+ |
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Structures and Stabilities of Ternary Copper(II) Complexes with 3,5-Diiodo-L-tyrosinate. Weak Interactions Involving Iodo Groups Feng Zhang, Akira Odani, Hideki Masuda, and Osamu Yamauchi pp 7148 - 7155; DOI: 10.1021/ic960599x |
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Voltammetry of Plastocyanin at a Graphite Electrode: Effects of Structure, Charge, and Electrolyte Dharmini D. Niles McLeod, Hans C. Freeman, Ian Harvey, Peter A. Lay, and Alan M. Bond pp 7156 - 7165; DOI: 10.1021/ic960620u |
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Rhenium Polyhydride Complexes Containing PhP(CH2CH2CH2PCy2)2 (Cyttp): Protonation, Insertion, and Ligand Substitution Reactions of ReH5(Cyttp) and Structural Characterization of ReH5(Cyttp) and [ReH4(2-H2)(Cyttp)]SbF6 Youhyuk Kim, Haibin Deng, Judith C. Gallucci, and Andrew Wojcicki pp 7166 - 7173; DOI: 10.1021/ic9602714 |
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Iodination of -Phosphino Enolate Complexes of Palladium(II) and Platinum(II). Synthesis and Crystal Structures of [(dmba)Pd{Ph2PC(I) Jacques Andrieu, Pierre Braunstein, Yves Dusausoy, and Nour Edine Ghermani pp 7174 - 7180; DOI: 10.1021/ic951507r |
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Organometallic Fluorides of Zirconium and Hafnium in the Synthesis of Carboxylate Complexes: Molecular Structures of [{(5-C5Me5)ZrF(OCOCF3)2}2] and [(5-C5Me5)2Zr(OCOCF3)2] Hendrik Dorn, Syed A. A. Shah, Emilio Parisini, Mathias Noltemeyer, Hans-Georg Schmidt, and Herbert W. Roesky pp 7181 - 7184; DOI: 10.1021/ic9604977 |
Issue 25
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Silicon Insertion into Boranes: A Rational Synthetic Route to Silicon-Containing Heteroboranes Joel A. Dopke, Adam N. Bridges, Matthew R. Schmidt, and Donald F. Gaines pp 7186 - 7187; DOI: 10.1021/ic960474s |
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A One-Dimensional Metallopolymer of 2,5-Dimethyl-N,N'-Dicyanoquinone Diimine (2,5-DM-DCNQI) Xiang Ouyang, Charles Campana, and Kim R. Dunbar pp 7188 - 7189; DOI: 10.1021/ic960713b |
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Heteroleptic Lanthanide Complexes with Aryloxide Ligands. Synthesis and Structural Characterization of Divalent and Trivalent Samarium Aryloxide/Halide and Aryloxide/Cyclopentadienide Complexes Zhaomin Hou, Akira Fujita, Takashi Yoshimura, Aldo Jesorka, Yugen Zhang, Hiroshi Yamazaki, and Yasuo Wakatsuki pp 7190 - 7195; DOI: 10.1021/ic960683c |
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Occurrence of Neighboring Group Participation Reactions in Amide-N and Amidine Complexes Derived from Pentaammine(dinitrile)cobalt(III) Ions Patricia M. Angus and W. Gregory Jackson pp 7196 - 7204; DOI: 10.1021/ic960032g |
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Complexation of Thorium(IV) and Uranium(IV) by a Hexaacetic Hexaaza Macrocycle: Kinetic and Thermodynamic Topomers of Actinide Chelates with a Large Cavity Ligand Vincent Jacques and Jean F. Desreux pp 7205 - 7210; DOI: 10.1021/ic9606439 |
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Stepwise Oxidation of Thiophene and Its Derivatives by Hydrogen Peroxide Catalyzed by Methyltrioxorhenium(VII) Kylie N. Brown and James H. Espenson pp 7211 - 7216; DOI: 10.1021/ic960607+ |
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Ru3(CO)12 in Acidic Media. Intermediates of the Acid-Cocatalyzed Water-Gas Shift Reaction (WGSR) Giuseppe Fachinetti, Tiziana Funaioli, Lorenzo Lecci, and Fabio Marchetti pp 7217 - 7224; DOI: 10.1021/ic960630v |
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Acid-Catalyzed Amine-Borane Reduction of Nitrite Kevin E. Bell and Henry C. Kelly pp 7225 - 7228; DOI: 10.1021/ic9601549 |
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Synthesis and Properties of 5-Chloro-8-hydroxyquinoline-Substituted Azacrown Ethers: A New Family of Highly Metal Ion-Selective Lariat Ethers Andrei V. Bordunov, Jerald S. Bradshaw, Xian Xin Zhang, N. Kent Dalley, Xiaolan Kou, and Reed M. Izatt pp 7229 - 7240; DOI: 10.1021/ic9610290 |
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cis-Bis(bipyridine)ruthenium Imidazole Derivatives: A Spectroscopic, Kinetic, and Structural Study K. Bal Reddy, Myung-ok P. Cho, James F. Wishart, Thomas J. Emge, and Stephan S. Isied pp 7241 - 7245; DOI: 10.1021/ic951434b |
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Host-Guest Interactions of Inorganic Phosphates with the Copper(II) Complexes of the Hexaaza Macrocyclic Ligand 3,6,9,17,20,23-Hexaazatricyclo[23.3.1.111,15]triaconta-1(29),11(30),12,14,25,27-hexaene David A. Nation, Arthur E. Martell, Richard I. Carroll, and Abraham Clearfield pp 7246 - 7252; DOI: 10.1021/ic960661q |
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Enhancement of the Catalytic Activity of a Macrocyclic Cobalt(II) Complex for the Electroreduction of O2 by Adsorption on Graphite Iqbal Bhugun and Fred C. Anson pp 7253 - 7259; DOI: 10.1021/ic9608399 |
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One-Pot Synthesis of Dihalo(porphyrinato)osmium(IV) Complexes. Evidence for Monohalo(carbonyl)osmium(III) Intermediates Zeev Gross and and Atif Mahammed pp 7260 - 7263; DOI: 10.1021/ic960363t |
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Donor-Free Alkali Metal Thiolates: Synthesis and Structure of Dimeric, Trimeric, and Tetrameric Complexes with Sterically Encumbered Terphenyl Substituents Mark Niemeyer and Philip P. Power pp 7264 - 7272; DOI: 10.1021/ic960570t |
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Group 9 Chalcogenometalates Thomas E. Albrecht-Schmitt and James A. Ibers pp 7273 - 7278; DOI: 10.1021/ic960589w |
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Synthesis and Characterization by 19F and 125Te NMR and Raman Spectroscopy of cis-ReO2(OTeF5)3 and cis-ReO2(OTeF5)4-, and X-ray Crystal Structure of [N(CH3)4+][cis-ReO2(OTeF5)4-] William J. Casteel Jr., Dianne M. MacLeod, Hélène P. A. Mercier, and Gary J. Schrobilgen pp 7279 - 7288; DOI: 10.1021/ic960597c |
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Clusters as Ligands. 4. Synthesis, Structure, and Characterization of the Tungsten(II)-Tungsten(III) Cluster Carboxylate {[Na][W2{OOCCCo3(CO)9}2(OOCCF3)4(THF)2]}2 Victor Calvo-Perez, Thomas P. Fehlner, and Arnold L. Rheingold pp 7289 - 7294; DOI: 10.1021/ic9609113 |
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Synthesis and Spectroscopic Characterization of Novel Heterotermetallic Isopropoxides: X-ray Crystal Structures of ICd{M2(OPri)9} and [{Cd(OPri)3}Ba{M2(OPri)9}]2 (M = Ti, Hf) Michael Veith, Sanjay Mathur, and Volker Huch pp 7295 - 7303; DOI: 10.1021/ic960116p |
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Characterization of Five-Coordinate Ruthenium(II) Phosphine Complexes by X-ray Diffraction and Solid-State 31P CP/MAS NMR Studies and Their Reactivity with Sulfoxides and Thioethers Kenneth S. MacFarlane, Ajey M. Joshi, Steven J. Rettig, and Brian R. James pp 7304 - 7310; DOI: 10.1021/ic960860+ |
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Reactions of 1,2-Dehydro-o-carborane with Thiophenes. Cycloadditions and an Easy Synthesis of "Benzo-o-carboranes" Lisa Barnett-Thamattoor, Guo-xiu Zheng, Douglas M. Ho, Maitland Jones, Jr., and James E. Jackson pp 7311 - 7315; DOI: 10.1021/ic960284h |
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Synthesis, NMR Study, and Reactivity of Isomeric Early-Late Heterobimetallic Dihydrides. X-ray Crystal Structure of (PPh3)HRu(-H)(-PMe2C5Me4)2(-Cl)ZrCl Vladimir I. Bakhmutov, Marc Visseaux, Denise Baudry, Alain Dormond, and Philippe Richard pp 7316 - 7324; DOI: 10.1021/ic960073c |
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Investigation of the Scope of Heterogeneous and Homogeneous Procedures for Preparing Magnesium Chelates of Porphyrins, Hydroporphyrins, and Phthalocyanines Donal F. O'Shea, Mark A. Miller, Hiroko Matsueda, and Jonathan S. Lindsey pp 7325 - 7338; DOI: 10.1021/ic960812p |
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Pyridineselenolate Complexes of Copper and Indium: Precursors to CuSex and In2Se3 Y. Cheng, T. J. Emge, and J. G. Brennan pp 7339 - 7344; DOI: 10.1021/ic9603969 |
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Synthesis and Reactivity of (Pentafluorophenyl)platinate(II) Complexes with Bridging 1,8-Naphthyridine (napy) and X Ligands (X = C6F5, OH, Cl, Br, I, SPh). Crystal Structure of [NBu4][Pt2(-napy)(-OH)(C6F5)4]·CHCl3 Irene Ara, José M. Casas, Juan Forniés, and Angel J. Rueda pp 7345 - 7349; DOI: 10.1021/ic960092m |
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Metal-Metal Multiply Bonded Complexes of Technetium. 5.1 Tris and Tetrakis(formamidinato) Complexes of Ditechnetium F. Albert Cotton, Steven C. Haefner, and Alfred P. Sattelberger pp 7350 - 7357; DOI: 10.1021/ic960535m |
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Preparation, Molecular and Electronic Structures, and Magnetic Properties of Face-Sharing Bioctahedral Titanium(III) Compounds: [PPh4][Ti2(-Cl)3Cl4(PR3)2] Linfeng Chen, F. Albert Cotton, Kim R. Dunbar, Xuejun Feng, Robert A. Heintz, and Calvin Uzelmeir pp 7358 - 7363; DOI: 10.1021/ic960636k |
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Synthesis, Structure, and Reactivity of [Zr6Cl18H5]2-, the First Paramagnetic Species of Its Class Linfeng Chen and F. Albert Cotton pp 7364 - 7369; DOI: 10.1021/ic960454q |
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Electronic and Geometric Structure of Bimetallic Clusters: Density Functional Calculations on [M4{Fe(CO)4}4]4- (M = Cu, Ag, Au) and [Ag13{Fe(CO)4}8]n- (n = 0-5) Katrin Albert, Konstantin M. Neyman, Gianfranco Pacchioni, and Notker Rösch pp 7370 - 7376; DOI: 10.1021/ic960274g |
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Syn-Anti Isomerism in a Mixed-Ligand Oxorhenium Complex, ReO[SN(R)S][S] M. S. Papadopoulos, I. C. Pirmettis, M. Pelecanou, C. P. Raptopoulou, A. Terzis, C. I. Stassinopoulou, and E. Chiotellis pp 7377 - 7383; DOI: 10.1021/ic9604167 |
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Crystal Structures and Magnetic Properties of Novel [LnIIICuII4] (Ln = Gd, Dy, Ho) Pentanuclear Complexes. Topology and Ferromagnetic Interaction in the LnIII-CuII Pair José Luis Sanz, Rafael Ruiz, Alain Gleizes, Francesc Lloret, Juan Faus, Miguel Julve, Juan José Borrás-Almenar, and Yves Journaux pp 7384 - 7393; DOI: 10.1021/ic960524t |
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K(VO)(SeO3)2H: A New One-Dimensional Compound with Strong Hydrogen Bonding Yoon Hyun Kim, Kyu-Seok Lee, Young-Uk Kwon, and Oc Hee Han pp 7394 - 7398; DOI: 10.1021/ic960624z |
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Boundary Structures in a Series of Lanthanoid Hexacyanocobaltate(III) n-Hydrates and Their Raman Spectra Yasuhiko Yukawa and, Satoshi Igarashi, Tomohiro Kawaura, and Hiroshi Miyamoto pp 7399 - 7403; DOI: 10.1021/ic9602355 |
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Anionic Halomolybdate(III) Chemistry. Tetrahydrofuran Loss from [MoX3Y(THF)2]- (X, Y = Cl, Br, I), Preparation and Properties of [Mo3X12]3- (X = Br, I), and Crystal Structure of the Edge-Sharing Trioctahedral [PPh4]3[Mo3I12] James C. Fettinger, John C. Gordon, Sundeep P. Mattamana, Charles J. O'Connor, Rinaldo Poli, and Ghadi Salem pp 7404 - 7412; DOI: 10.1021/ic9607301 |
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Ferromagnetic Mn(II)···Cu(II) Exchange in the New Bimetallic Quasi-2-D Compound Cu(op)2MnCl4 (op = 1,4-Diazacycloheptane) B. Chiari, A. Cinti, L. David, F. Ferraro, D. Gatteschi, O. Piovesana, and P. F. Zanazzi pp 7413 - 7418; DOI: 10.1021/ic960373u |
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Temperature Dependence of the Crystal Structure and EPR Spectrum of Bis(1,3,5-Trihydroxycyclohexane)copper(II) Tosylate. A Unified Interpretation Using a Model of Dynamic Vibronic Coupling Joachim Bebendorf, Hans-Beat Bürgi, Eduard Gamp, Michael A. Hitchman, Angela Murphy, Dirk Reinen, Mark J. Riley, and Horst Stratemeier pp 7419 - 7429; DOI: 10.1021/ic960343r |
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Allopurinol- and Hypoxanthine-Copper(II) Compounds. Spectral and Magnetic Studies of Novel Dinuclear Coordination Compounds with Bridging Hypoxanthine Rodolfo Acevedo-Chávez, María Eugenia Costas, and Roberto Escudero pp 7430 - 7439; DOI: 10.1021/ic9602005 |
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Rb2[Ga4(HPO4)(PO4)4]·0.5H2O: A New Gallium Phosphate Containing Four-, Five, and Six-Coordinated Gallium Atoms Kwang-Hwa Lii pp 7440 - 7442; DOI: 10.1021/ic960488y |
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Molecular Structure of [CpFe(CO)2]2AlAr (Ar = 2-[(Dimethylamino)methyl]phenyl): An Alanediyl Complex with Two Fe-Al Bonds Holger Braunschweig, Jens Müller, and Beate Ganter pp 7443 - 7444; DOI: 10.1021/ic960471f |
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The Heterobimetallic Polymeric Zigzag Chain [(W4S16Ag4)4-]n Derived from the Linear Chain [(WS4Ag)-]n: Synthesis, Characterization, and Structure of [W4S16Ag4·2Ca(DMSO)6]n (DMSO = Dimethyl Sulfoxide) Qun Huang, Xintao Wu, and Jiaxi Lu pp 7445 - 7447; DOI: 10.1021/ic9606791 |
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Structure of ReOFCl2(PPh3)2, a Crystallographic Pitfall Céline Pearson, Michèle Dartiguenave, and André L. Beauchamp pp 7448 - 7449; DOI: 10.1021/ic9608206 |
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Calculated Structure and Optical Properties of Tl2Pt(CN)4 Michael Dolg, Pekka Pyykkö, and Nino Runeberg pp 7450 - 7451; DOI: 10.1021/ic951049m |
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Synthesis and Crystal Structure of Tetrakis(2-pyridinecarboxylato)niobium(IV)- 2-Ethanol, an Octacoordinate Dodecahedral d1 M(A-B)4 System Bee-Lean Ooi, Genta Sakane, and Takashi Shibahara pp 7452 - 7454; DOI: 10.1021/ic960803g |
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Electronic Tuning Using Remote Substituents in Tetrakis(-N,N'-diarylformamidinato)dinickel. Linear Free Energy Relationships in Dinuclear Compounds. 3 Chun Lin, John D. Protasiewicz, and Tong Ren pp 7455 - 7458; DOI: 10.1021/ic960842s |
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Synthesis of Triamidoamine Complexes of Niobium Joel S. Freundlich and Richard R. Schrock pp 7459 - 7461; DOI: 10.1021/ic9607088 |
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Copper(II) Complexes of the Hexaaza Macrocyclic Ligand 3,6,9,16,19,22-Hexaaza-27,28-dioxatricyclo [ 22.2.1.111,14 ] octacosa-1 (26) ,11 ,13 ,24 - tetraene and Their Interaction with Oxalate, Malonate, and Pyrophosphate Anions Qin Lu, Joseph H. Reibenspies, Arthur E. Martell, and Ramunas J. Motekaitis pp 7462 - 7462; DOI: 10.1021/ic960914f |
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Helical Antiferromagnetic Copper(II) Chains with a Collagen Structural Motif Kausik K. Nanda, Anthony W. Addison, Ekkehard Sinn, and Laurence K. Thompson pp 7462 - 7462; DOI: 10.1021/ic961985h |
Issue 26
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Sir Geoffrey Wilkinson 1921-1996 IN MEMORIAM E. Abel pp 7463 - 7464; DOI: 10.1021/ic961299i |
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Restoration of Catalytic Activity by Replacement of a Coordinated Amide Group: Synthesis and Laser-Induced Luminescence Studies of the Phosphate Diester Transesterification Catalyst [Eu(NBAC)]3+ Shahid Amin, David A. Voss, Jr., William DeW. Horrocks, Jr., and Janet R. Morrow pp 7466 - 7467; DOI: 10.1021/ic9516469 |
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Unexpected Coexistence of Isomeric Forms and Unusual Structures of Ru(CO)2L3 Masamichi Ogasawara, Feliu Maseras, Nuria Gallego-Planas, William E. Streib, Odile Eisenstein, and Kenneth G. Caulton pp 7468 - 7469; DOI: 10.1021/ic960742m |
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Novel Strategy for Assigning Hyperfine Shifts Using Pulsed-Field Gradient Heteronuclear Multiple-Bond Correlation Spectroscopy Ken Skidmore and Ursula Simonis pp 7470 - 7471; DOI: 10.1021/ic960797o |
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Structure and Reactivity of a Dinuclear Cobalt(III) Complex with a Bridging Phosphate Monoester Jin Seog Seo, Nack-Do Sung, Rosemary C. Hynes, and Jik Chin pp 7472 - 7473; DOI: 10.1021/ic9603924 |
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Copper(II) Macrocycles Cleave Single-Stranded and Double-Stranded DNA under Both Aerobic and Anaerobic Conditions Eric L. Hegg and Judith N. Burstyn pp 7474 - 7481; DOI: 10.1021/ic960384n |
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Cobalt(II) Substituted Derivatives of Carcinus maenas Hemocyanin: Magnetic Characterization, Magnetooptic, and Kinetic Studies Regarding the Geometry of the Active Site Martina Hüber, Luigi Bubacco, Mariano Beltramini, Benedetto Salvato, Horst Elias, Jack Peisach, Erik Larsen, Sven E. Harnung, and Wolfgang Haase pp 7482 - 7492; DOI: 10.1021/ic951587z |
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Synthesis, Crystal Structure, and Magnetic Properties of a Ferromagnetically Coupled Difluoro-Bridged Dinuclear Chromium(III) Complex with a Substituted Tetrahydrosalen Derivative as Ligand Ralf Sanzenbacher, Arnd Böttcher, Horst Elias, Martina Hüber, Wolfgang Haase, Jørgen Glerup, Thomas B. Jensen, Markus Neuburger , Margareta Zehnder, Johan Springborg, and Carl Erik Olsen pp 7493 - 7499; DOI: 10.1021/ic960342z |
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Metalloporphyrin Mixed-Valence -Cation Radicals: Solid-State Structures W. Robert Scheidt, Kristin E. Brancato-Buentello, Hungsun Song, K. Venugopal Reddy, and Beisong Cheng pp 7500 - 7507; DOI: 10.1021/ic9610748 |
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A Catalytic Cycle Related to Molybdenum Enzymes Containing [MoVIO2]2+ Oxidized Active Sites Zhiguang Xiao, Michael A. Bruck, John H. Enemark, Charles G. Young, and Anthony G. Wedd pp 7508 - 7515; DOI: 10.1021/ic961065z |
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Functional Modeling of Tyrosinase. Mechanism of Phenol ortho-Hydroxylation by Dinuclear Copper Complexes Luigi Casella and, Enrico Monzani, Michele Gullotti, Daniela Cavagnino, Gianluca Cerina, Laura Santagostini, and Renato Ugo pp 7516 - 7525; DOI: 10.1021/ic9601100 |
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Synthesis and Photochemistry of Amido-Linked, Peripherally-Molybdenated Tetraphenylporphyrins Natalie M. Rowley, Stefan S. Kurek, Peter R. Ashton, Tom A. Hamor, Christopher J. Jones, Neil Spencer, Jon A. McCleverty, Godfrey S. Beddard, Timothy M. Feehan, Nigel T. H. White, Eric J. L. McInnes, Nicholas N. Payne, and Lesley J. Yellowlees pp 7526 - 7534; DOI: 10.1021/ic9509342 |
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A Platinum(II) Diamino--cyclodextrin Complex: A Crystallographic and Solution Study. Synthesis and Structural Characterization of a Platinum(II) Complex of 6A,6B-Diamino-6A,6B-dideoxycyclomaltoheptaose Vincenzo Cucinotta, Giulia Grasso, Sonia Pedotti, Enrico Rizzarelli, Graziella Vecchio, Benedetto Di Blasio, Carla Isernia, Michele Saviano, and Carlo Pedone pp 7535 - 7540; DOI: 10.1021/ic9607651 |
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NMR Evidence for Sequence-Specific DNA Minor Groove Binding by Bis(ethylenediamine)platinum(II) Craig A. Franklin, John V. Fry, and J. Grant Collins pp 7541 - 7545; DOI: 10.1021/ic9604775 |
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Rhodium(III) Complexes with Acyclic Tetrathioether Ligands. Effects of Backbone Chain Length on the Conformation of the Rh(III) Complex Niranjan Goswami, Roger Alberto, Charles L. Barnes, and Silvia Jurisson pp 7546 - 7555; DOI: 10.1021/ic960952z |
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Kinetics and Mechanism of the Complexation of trans-Diamminediaquaplatinum(II) with the 6-Oxopurine Nucleosides Inosine and 1-Methylinosine in Aqueous Solution as a Function of the pH Marjaana Mikola and Jorma Arpalahti pp 7556 - 7562; DOI: 10.1021/ic960828f |
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A Route to Bis(benzimidazole) Ligands with Built-In Asymmetry: Potential Models of Protein Binding Sites Having Histidines of Different Basicity Craig J. Matthews, Troy A. Leese, William Clegg, Mark R. J. Elsegood, Lynne Horsburgh, and Joyce C. Lockhart pp 7563 - 7571; DOI: 10.1021/ic960777m |
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Ferric Ion Complexes of a DOPA-Containing Adhesive Protein from Mytilus edulis Steven W. Taylor, D. Bruce Chase, Mark H. Emptage, Mark J. Nelson, and J. Herbert Waite pp 7572 - 7577; DOI: 10.1021/ic960514s |
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Modeling the Photosynthetic Water Oxidation Center: Chloride/Bromide Incorporation and Reversible Redox Processes in the Complexes Mn4O3X(OAc)3(dbm)3 (X = Cl, Br) and (pyH)3[Mn4O3Cl7(OAc)3] Sheyi Wang, Hui-Lien Tsai, Eduardo Libby, Kirsten Folting, William E. Streib, David N. Hendrickson, and George Christou pp 7578 - 7589; DOI: 10.1021/ic9601347 |
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Carboxylate- and Phosphate Ester-Bridged Dimagnesium(II), Dizinc(II), and Dicalcium(II) Complexes. Models for Intermediates in Biological Phosphate Ester Hydrolysis Joanne W. Yun, Tomoaki Tanase, and Stephen J. Lippard pp 7590 - 7600; DOI: 10.1021/ic960894h |
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Intermetal Oxygen Atom Transfer Reactions of Titanium Porphyrins: Complete vs Incomplete Atom Transfer. X-ray Structure of (-Oxo)bis[(meso-tetra-p-tolylporphyrinato)titanium(III)] J. Alan Hays, Catherine L. Day, Victor G. Young, Jr., and L. Keith Woo pp 7601 - 7607; DOI: 10.1021/ic960863m |
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Synthesis and Structure of Two New Layered Ternary Nitrides, SrZrN2 and SrHfN2 D. H. Gregory, M. G. Barker, P. P. Edwards, and D. J. Siddons pp 7608 - 7613; DOI: 10.1021/ic9607649 |
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Synthesis and Crystal Structure of the Alkylbismuth Diiodides: A Family of Extended One-Dimensional Organometallic Compounds David B. Mitzi pp 7614 - 7619; DOI: 10.1021/ic961083g |
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Synthesis and Characterization of [Yb(NH3)8][Cu(S4)2]·NH3, [Yb(NH3)8][Ag(S4)2]·2NH3, and [La(NH3)9][Cu(S4)2] in Supercritical Ammonia: Metal Sulfide Salts of the First Homoleptic Lanthanide Ammine Complexes Dianna M. Young, George L. Schimek, and Joseph W. Kolis pp 7620 - 7625; DOI: 10.1021/ic9601403 |
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Preparation and Solid State Characterization of Isostructural Bifunctional 1,2,3,5-Dithiadiazolyls with Benzene, Bithiophene, and Piperazine Spacers A. W. Cordes, R. C. Haddon, C. D. MacKinnon, R. T. Oakley, G. W. Patenaude, R. W. Reed, T. Rietveld, and K. E. Vajda pp 7626 - 7632; DOI: 10.1021/ic960659z |
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Synthesis, Crystal Structures, and Magnetostructural Correlations in Two New One-Dimensional Nickel(II) Complexes with Azido as Bridging Ligand. Effect of Temperature Montserrat Monfort, Joan Ribas, Xavier Solans, and Mercé Font-Bardía pp 7633 - 7638; DOI: 10.1021/ic960733d |
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Molecular Structure of SbI3 and BiI3 from Combined Electron Diffraction and Vibrational Spectroscopic Studies Judit Molnár, Mária Kolonits, Magdolna Hargittai, R. J. M. Konings, and A. S. Booij pp 7639 - 7642; DOI: 10.1021/ic960601k |
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Structure and Magnetism of Dibridged Vanadium(IV) Hydrotris(pyrazolyl)borate Dimers Norman S. Dean, Marcus R. Bond, C. J. O'Connor, and Carl J. Carrano pp 7643 - 7648; DOI: 10.1021/ic9607705 |
MAxTe2 Phases (M = Nb, Ta; A = Si, Ge; 1/3  x 1/2): An Electronic Band Structure Calculation AnalysisFlorent Boucher, Vladlen Zhukov, and Michel Evain pp 7649 - 7654; DOI: 10.1021/ic960564x |
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A Two-Dimensional Manganese(II) Carboxylato Polymer. Structure, Magnetism, and EPR Study Vasilis Tangoulis, George Psomas, Catherine Dendrinou-Samara, Catherine P. Raptopoulou, Aris Terzis, and Dimitris P. Kessissoglou pp 7655 - 7660; DOI: 10.1021/ic9608051 |
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Interconversion between Polymeric and Monomeric Forms of Oxovanadium(IV) Complexes with Tetradentate Schiff Base Ligands Derived from (R,R)-2,4-Pentanediamine Ryuichi Kasahara, Masanobu Tsuchimoto, Shigeru Ohba, Kiyohiko Nakajima, Hiroyuki Ishida, and Masaaki Kojima pp 7661 - 7665; DOI: 10.1021/ic960531h |
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Synthesis, X-ray Structure, and Magnetic Properties of Ferromagnetically Coupled Binuclear Copper(II) Complexes Having a (-Hydroxo/methoxo)bis(-benzoato)dicopper(II) Core Kannappan Geetha, Munirathinam Nethaji, Akhil R. Chakravarty, and Nagasampagi Y. Vasanthacharya pp 7666 - 7670; DOI: 10.1021/ic9607550 |
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Millimeter-Wave Spectra, ab Initio Calculations, and Structures of Fluorophosphane and Chlorophosphane P. Dréan, M. Paplewski, J. Demaison, J. Breidung, W. Thiel, H. Beckers, and H. Bürger pp 7671 - 7678; DOI: 10.1021/ic960546f |
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Multinuclear Magnetic Resonance Study on the Structure and Dynamics of Lanthanide(III) Complexes of Cyclic DTPA Derivatives in Aqueous Solution Emrin Bovens, Mattheus A. Hoefnagel, Edwin Boers, Hendrik Lammers, Herman van Bekkum, and Joop A. Peters pp 7679 - 7683; DOI: 10.1021/ic960540q |
Cyclic Voltammetry of Palladium(II) Complexes with Tridentate Arsine Ligands. Separation of the Two Single-Electron Transfer Steps of the Pd(II)  Pd(0) Interconversion Based on Thermodynamic and Kinetic DiscriminationAlison J. Downard, Alan M. Bond, Andrew J. Clayton, Lyall R. Hanton, and David A. McMorran pp 7684 - 7690; DOI: 10.1021/ic960642g |
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trans-Chloromethylbis(dimethyl sulfoxide)platinum(II): X-ray Structure, Mechanism of Isomerization, and Its Use as a Precursor to Organoamine Complexes of Variable Geometrical Configurations Raffaello Romeo, Luigi Monsù Scolaro, Nicola Nastasi, Brian Ernest Mann, Giuseppe Bruno, and Francesco Nicolò pp 7691 - 7698; DOI: 10.1021/ic960428s |
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Coupled Two-Electron/Halide Transfer Reactions of Ruthenoceniums and Osmoceniums Timothy M. Shea, Samitha P. Deraniyagala, Daniel B. Studebaker, and T. David Westmoreland pp 7699 - 7703; DOI: 10.1021/ic961000w |
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Electrochemical and IR Spectroelectrochemical Studies of the Electrocatalytic Reduction of Carbon Dioxide by [Ir2(dimen)4]2+ (dimen = 1,8-Diisocyanomenthane) Stephen C. Cheng, Christine A. Blaine, Michael G. Hill, and Kent R. Mann pp 7704 - 7708; DOI: 10.1021/ic9512385 |
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Kinetics and Mechanism of Chromium(VI) Reduction to Chromium(III) by L-Cysteine in Neutral Aqueous Solutions Peter A. Lay and and Aviva Levina pp 7709 - 7717; DOI: 10.1021/ic960663a |
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Mixed-Valence Cyanopyridine-Bridged Complexes of Pentacyanoferrate and Pentaammineruthenium: Electronic Structure, Stability, and Redox Reactivity Alejandra E. Almaraz, Luis A. Gentil, Luis M. Baraldo, and José A. Olabe pp 7718 - 7727; DOI: 10.1021/ic960489q |
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Reactivity of a Regiospecific Ion Pair. Comparisons of Cl- and H2O Entry into the Five-Coordinate Intermediate Generated from p-[Co(tren)(NH3)OH2]3+·Cl- Nicola E. Brasch, David A. Buckingham, Charles R. Clark, and Jim Simpson pp 7728 - 7734; DOI: 10.1021/ic960653+ |
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Formation of Peroxynitrite from the Oxidation of Hydrogen Peroxide by Nitrosonium Ion (NO+): A Pulse Radiolysis Study Sara Goldstein and and Gidon Czapski pp 7735 - 7740; DOI: 10.1021/ic960233k |
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Influence of Remote Ligand Lone Pairs on the Electronic Structure and Spectrum of Bis(bipyridine)ruthenium(II) 3,4-Diamino-3',4'-diimino-3',4'-dihydrobiphenyl. Tuning by External Donors and Acceptors Robert A. Metcalfe, Elaine S. Dodsworth, Scott S. Fielder, Derk J. Stufkens, A. B. P. Lever, and William J. Pietro pp 7741 - 7750; DOI: 10.1021/ic960232s |
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Oxygen-Transfer Reactions of Methylrhenium Oxides Mahdi M. Abu-Omar, Evan H. Appelman, and James H. Espenson pp 7751 - 7757; DOI: 10.1021/ic960701q |
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Electronic Structural Contributions to g Values and Molybdenum Hyperfine Coupling Constants in Oxyhalide Anions of Molybdenum(V) C. Balagopalakrishna, John T. Kimbrough, and T. David Westmoreland pp 7758 - 7768; DOI: 10.1021/ic951142a |
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Photophysics of Tungsten and Molybdenum Arylcarbyne Complexes. Observation of the Lowest Excited State by Laser Flash Photolysis Thomas K. Schoch, Andrea D. Main, Richard D. Burton, Lucian A. Lucia, Edward A. Robinson, Kirk S. Schanze, and Lisa McElwee-White pp 7769 - 7775; DOI: 10.1021/ic951043x |
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Electronic Structure, Heisenberg Coupling Constants, and Metal-Metal Bond in Dimeric Iron(II) Organometallics with the Metal Centers at Variable Distances: A Density Functional Approach Paola Belanzoni, Nazzareno Re, Marzio Rosi, Antonio Sgamellotti, Evert Jan Baerends, and Carlo Floriani pp 7776 - 7785; DOI: 10.1021/ic9507676 |
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Spectroscopic Investigation of the Photochemistry of Uranyl-Doped Sol-Gel Glasses Immersed in Ethanol Sheng Dai, D. H. Metcalf, G. D. Del Cul, and L. M. Toth pp 7786 - 7790; DOI: 10.1021/ic9604066 |
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Communication between Porphyrin Rings in the Butadiyne-Bridged Dimer Ni(OEP)(-C4)Ni(OEP): A Density Functional Study Robert Stranger, John E. McGrady, Dennis P. Arnold, Ian Lane, and Graham A. Heath pp 7791 - 7797; DOI: 10.1021/ic961016m |
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Geometric Factors in the Structural and Thermodynamic Properties of Copper(II) Complexes with Tripodal Tetraamines Andreas M. Dittler-Klingemann, Chris Orvig, F. Ekkehardt Hahn, Florian Thaler, Colin D. Hubbard, Rudi van Eldik, Siegfried Schindler, and István Fábián pp 7798 - 7803; DOI: 10.1021/ic960585r |
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A New Tripodal Tetradentate Ligand and Its Iron(III) Complex, as a Model for Mononuclear Non-Heme Iron Active Sites. Reactivity Studies toward Dioxygen and Superoxide Marie-Carmen Rodriguez, Irène Morgenstern-Badarau, Michèle Cesario, Jean Guilhem, Bineta Keita, and Louis Nadjo pp 7804 - 7810; DOI: 10.1021/ic951060m |
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Quantum Mechanical Exchange Coupling in Trihydridoosmium Complexes Containing Azole Ligands Miguel A. Esteruelas, Fernando J. Lahoz, Ana M. López, Enrique Oñate, Luis A. Oro, Natividad Ruiz, Eduardo Sola, and José I. Tolosa pp 7811 - 7817; DOI: 10.1021/ic960446+ |
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Aryldiazenido Complexes: Syntheses of Diiridium Complexes with Mono- and Dibridging Aryldiazenido Ligands and X-ray Structures of [(5-C5Me5)IrI]2(-2-p-N2C6H4OMe)(-1-p-N2C6H4OMe) and [{(5-C5Me5)Ir(CO)}2(-2-p-N2C6H4OMe)][BF4] Xiaoqian Yan, Raymond J. Batchelor, Frederick W. B. Einstein, and Derek Sutton pp 7818 - 7828; DOI: 10.1021/ic960551j |
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Binuclear Platinum(II) Triazolopyrimidine Bridged Complexes. Preparation, Crystal Structure, NMR Spectroscopy, and ab Initio MO Investigation on the Bonding Nature of the Pt(II)···Pt(II) Interaction in the Model Compound {Pt2[NHCHN(C(CH2)(CH3))]4} Jorge A. R. Navarro, M. Angustias Romero, Juan M. Salas, Miguel Quirós, Jaouad El Bahraoui, and José Molina pp 7829 - 7835; DOI: 10.1021/ic960496e |
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Preparation and Protonation Studies of trans-Dioxorhenium(V) Complexes with Imidazoles Suzanne Bélanger and André L. Beauchamp pp 7836 - 7844; DOI: 10.1021/ic960451d |
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Syntheses, Structures, and Reactivity of Diruthenium Phosphine Carbonyl Complexes of Nitrites and Nitrates Kom-Bei Shiu, Luh-Tin Yang, Shih-Wei Jean, Chien-Hsing Li, Ru-Rong Wu, Ju-Chun Wang, Lin-Shu Liou, and Michael Y. Chiang pp 7845 - 7849; DOI: 10.1021/ic960530p |
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Synthesis and Reactivity of New Aminopentaboranes Robert W. McGaff and Donald F. Gaines pp 7850 - 7856; DOI: 10.1021/ic960192s |
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Syntheses, Characterization, and Structures of Tri- and Tetraruthenium Clusters Containing Sulfido, Phenylimido, and (Phenylimino)thio Ligands Wen-Yann Yeh, Charlotte Stern, and Duward F. Shriver pp 7857 - 7862; DOI: 10.1021/ic960697i |
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(1-Ferrocenyl-6-borabenzene)(5-cyclopentadienyl)cobalt(1+): A New Heterobimetallic Basic NLO Chromophore Ute Hagenau, Jürgen Heck, Eric Hendrickx, André Persoons, Thomas Schuld, and Hans Wong pp 7863 - 7866; DOI: 10.1021/ic960443x |
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Direct Ag-Pt2 Interactions in Pentafluorophenyl A-Frame Complexes Containing Halide or OH- and Bis(diphenylphosphino)methane (dppm) as Bridging Ligands. Crystal Structures of [(C6F5)2Pt(-OH)(-dppm){Ag(PPh3)}Pt(C6F5)2]·C7H8 and [(C6F5)2Pt(-SC4H8)(-dppm)Pt(C6F5)2]·1/2C6H14 José María Casas, Larry R. Falvello, Juan Forniés, and Antonio Martín pp 7867 - 7872; DOI: 10.1021/ic9605332 |
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Exchange Coupling in Niobocene Trihydrides, Nb(C5H3RR')2H3, and Their Adducts with Copper Triad Cations, [{Nb(C5H3RR')2H3}2M]+ (R = R' = H; R = H, R'= SiMe3; R = R' = SiMe3; M = Cu, Ag, Au) Antonio Antiñolo, Fernando Carrillo-Hermosilla, Bruno Chaudret, Mariano Fajardo, Juan Fernández-Baeza, Maurizio Lanfranchi, Hans-Heinrich Limbach, Markus Maurer, Antonio Otero, and Maria Angela Pellinghelli pp 7873 - 7881; DOI: 10.1021/ic960582e |
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Reactions of CB9H10- with Electrophiles, Including the Regioselective Mono- and Dihalogenation of the Lower Belt Sergei V. Ivanov, Juston J. Rockwell, Susie M. Miller, Oren P. Anderson, Konstantin A. Solntsev, and Steven H. Strauss pp 7882 - 7891; DOI: 10.1021/ic960859a |
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Electron Transfer. 132. Oxidations with Peroxynitrite Ahmad M. Al-Ajlouni and Edwin S. Gould pp 7892 - 7896; DOI: 10.1021/ic960504r |
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Reaction of AgOCN with NO, NO2, ClNO2, ClNO, and BrNO: Evidence of the Formation of OCN-NO2 and OCN-NO Thomas M. Klapötke and Axel Schulz pp 7897 - 7904; DOI: 10.1021/ic960707f |
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Polyoxometalate Catalyst Precursors. Improved Synthesis, H+-Titration Procedure, and Evidence for 31P NMR as a Highly Sensitive Support-Site Indicator for the Prototype Polyoxoanion-Organometallic-Support System [(n-C4H9)4N]9P2W15Nb3O62 Heiko Weiner, John D. Aiken, III, and Richard G. Finke pp 7905 - 7913; DOI: 10.1021/ic960681s |
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Steric Parameters for Metal Binding Sites on Nucleobases Elizabeth Yuriev and John D. Orbell pp 7914 - 7915; DOI: 10.1021/ic9610896 |
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Synthesis and Solution Spectral Properties of Antimony(III) Phthalocyanine and Dihydroxoantimony(V) Phthalocyanine Complexes Günther Knör pp 7916 - 7918; DOI: 10.1021/ic961013+ |
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Ba3CuBr3(P2O7): The First Copper(I) Halide Pyrophosphate Kristen M. S. Etheredge, Richard Mackay, George L. Schimek, and Shiou-Jyh Hwu pp 7919 - 7921; DOI: 10.1021/ic960461e |
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A Bis-Capped Cofacial Metallodiporphyrin: Synthesis and Electrochemistry of a Molecule Containing Two Coaxial Metal-Metal Multiple Bonds in Close Proximity James P. Collman and and H. T. Fish pp 7922 - 7923; DOI: 10.1021/ic950940y |
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Microwave Irradiation Synthesis of Mo(W)/Tl/S Linear Chains and Their Nonlinear Optical Properties in Solution Jianping Lang, Kazuyuki Tatsumi, Hiroyuki Kawaguchi, Jianmei Lu, P. Ge, W. Ji, and Shu Shi pp 7924 - 7927; DOI: 10.1021/ic9610905 |
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Cobalt meso-Tetrakis(N-methyl-4-pyridiniumyl)porphyrin Becomes a Catalyst for the Electroreduction of O2 by Four Electrons When [(NH3)5Os]n+ (n = 2, 3) Groups Are Coordinated to the Porphyrin Ring Chunnian Shi and Fred C. Anson pp 7928 - 7931; DOI: 10.1021/ic9607189 |
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A Square Pyramidal Coordination Cap: The Co(III) Complex of a Novel Tetrapodal Pentadentate Ligand with an NN4 Donor Set Andreas Grohmann and and Falk Knoch pp 7932 - 7934; DOI: 10.1021/ic9606082 |
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Evidence for Porphyrin ()-Chlorine (p) Orbital Overlap in the -Cation Radicals of Zinc(II) and Magnesium(II) Tetrakis(o-dichlorophenyl)porphyrin William A. Kalsbeck, Jyoti Seth, and David F. Bocian pp 7935 - 7937; DOI: 10.1021/ic9608354 |
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Synthesis, Characterization, and Reactivity of Monomeric Strontium and Barium Triphenylsiloxide Compounds: Molecular Structure and Reactivity of M(OSiPh3)2(15-crown-5)THF, M = Sr (1) and Ba (2) William A. Wojtczak, Mark J. Hampden-Smith, and Eileen N. Duesler pp 7938 - 7938; DOI: 10.1021/ic961373x |